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91.
92.
Carolin Blum Lothar Opilik Joanna M. Atkin Kai Braun Stefan B. Kmmer Vasily Kravtsov Naresh Kumar Sergey Lemeshko Jian‐Feng Li Karol Luszcz Teimour Maleki Alfred J. Meixner Steve Minne Markus B. Raschke Bin Ren Jan Rogalski Debdulal Roy Bruno Stephanidis Xiang Wang Dai Zhang Jin‐Hui Zhong Renato Zenobi 《Journal of Raman spectroscopy : JRS》2014,45(1):22-31
Since its first experimental realization, tip‐enhanced Raman spectroscopy (TERS) has emerged as a potentially powerful nanochemical analysis tool. However, questions about the comparability and reproducibility of TERS data have emerged. This interlaboratory comparison study addresses these issues by bringing together different TERS groups to perform TERS measurements on nominally identical samples. Based on the spectra obtained, the absolute and relative peak positions, number of bands, peak intensity ratios, and comparability to reference Raman and surface‐enhanced Raman spectroscopy (SERS) data are discussed. Our general findings are that all research groups obtained similar spectral patterns, irrespective of the setup or tip that was used. The TERS (and SERS) spectra consistently showed fewer bands than the conventional Raman spectrum. When comparing these three methods, the spectral pattern match and substance identification is readily possible. Absolute and relative peak positions of the three major signals of thiophenol scattered by 19 and 9 cm−1, respectively, which can probably be attributed to different spectrometer calibrations. However, within the same group (but between different tips), the signals only scattered by 3 cm−1 on average. This study demonstrated the suitability of TERS as an analytical tool and brings TERS a big step forward to becoming a routine technique. Copyright © 2014 John Wiley & Sons, Ltd. 相似文献
93.
Hojat Veisi Zahra Vafajoo Behrooz Maleki Malek Taher Maghsoodlou 《Phosphorus, sulfur, and silicon and the related elements》2013,188(6):672-677
Abstract An electrochemically induced catalytic crossed Aldol condensation of one equivalent of rhodanine with various aromatic aldehydes and ketones in ethanol in an undivided cell in the presence of sodium bromide as an electrolyte results in the formation of the corresponding 5-arylalkylidenerhodanines in 80–96% yield with reactions in 40 min. Supplemental materials are available for this article. Go to the publisher's online edition of Phosphorus, Sulfur, and Silicon and the Related Elements to view the free supplemental file. 相似文献
94.
Synthesis of Imidazo[1,2‐a]pyridines Using Fe3O4@SiO2 as an Efficient Nanomagnetic Catalyst via a One‐Pot Multicomponent Reaction
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Ali Maleki 《Helvetica chimica acta》2014,97(4):587-593
A one‐pot multicomponent synthesis of imidazo[1,2‐a]pyridine derivatives by using pyridin‐2‐amines, aldehydes, and terminal alkynes in the presence of a catalytic amount of silica‐supported iron oxide (Fe3O4@SiO2) nanoparticles in refluxing EtOH in good‐to‐excellent yields is reported. 相似文献
95.
Somayeh Motavallizadeh Asal Fallah-Tafti Saeedeh Maleki Amir Nasrolahi Shirazi Mahboobeh Pordeli Maliheh Safavi Sussan Kabudanian Ardestani Shaaban Asd Rakesh Tiwari Donghoon Oh Abbas Shafiee Alireza Foroumadi Keykavous Parang Tahmineh Akbarzadeh 《Tetrahedron letters》2014
Several novel N-(9-oxo-9H-xanthen-4-yl)benzenesulfonamide derivatives were prepared as potential antiproliferative agents. The in vitro antiproliferative activity of the synthesized compounds was investigated against a panel of tumor cell lines including breast cancer cell lines (MDA-MB-231, T-47D) and neuroblastoma cell line (SK-N-MC) using MTT colorimetric assay. Etoposide, a well-known anticancer drug, was used as a positive standard drug. Among synthesized compounds, 4-methoxy-N-(9-oxo-9H-xanthen-4-yl)benzenesulfonamide (5i) showed the highest antiproliferative activity against MDA-MB-231, T-47D, and SK-N-MC cells. Furthermore, pentafluoro derivatives 5a and 6a exhibited higher antiproliferative activity than doxorubicin against human leukemia cell line (CCRF-CEM) and breast adenocarcinoma (MDA-MB-468) cells. Structure–activity relationship studies revealed that xanthone benzenesulfonamide hybrid compounds can be used for the development of new lead anticancer agents. 相似文献
96.
In recent years, there is a high demand on utilizing heterogeneous nanocatalysts in organic synthetic routes because of their green approach, facile purification of the products, and reusability of the catalyst. Herein, we introduced trihydrazinotriazine (THDT)-coated Fe3O4@SiO2 as a novel amino-functionalized magnetic nanocompostie. We fully characterized the nanocatalyst and proved the morphology and magnetic property of the nanoparticles by using essential analyses. The basic attribute of the amino-rich porous surface of the nanocomposite provides a desirable environment for enhancing various reaction conditions. To examine the applicability of the nanocatalyst in organic reactions, we synthesized several benzoxanthenes using Fe3O4@SiO2-THDT nanocatalysts. The nanocomposite successfully improved the reaction conditions and provided the benzoxanthenes in an environmentally friendly procedure, which afforded product in excellent yields (80–96%) and reduced time. The nanomagnetic catalyst was easily recovered after each trial by using an external magnet. After six successive runs, the loss of catalytic activity of the nanocomposite was negligible. Finally, we propounded a plausible mechanism for the preparation of the benzoxanthenes derivatives using the THDT-functionalized core-shell magnetic nanocatalyst. 相似文献
97.
Mahdiar Khakinejad Samaneh Ghassabi Kondalaji Hossein Maleki James R. Arndt Gregory C. Donohoe Stephen J. Valentine 《Journal of the American Society for Mass Spectrometry》2014,25(12):2103-2115
The gas-phase conformations of electrosprayed ions of the model peptide KKDDDDIIKIIK have been examined by ion mobility spectrometry (IMS) and hydrogen deuterium exchange (HDX)-tandem mass spectrometry (MS/MS) techniques. [M+4H]4+ ions exhibit two conformers with collision cross sections of 418 Å2 and 471 Å2. [M+3H]3+ ions exhibit a predominant conformer with a collision cross section of 340 Å2 as well as an unresolved conformer (shoulder) with a collision cross section of ~367 Å2. Maximum HDX levels for the more compact [M+4H]4+ ions and the compact and partially-folded [M+3H]3+ ions are ~12.9, ~15.5, and ~14.9, respectively. Ion structures obtained from molecular dynamics simulations (MDS) suggest that this ordering of HDX level results from increased charge-site/exchange-site density for the more compact ions of lower charge. Additionally, a new model that includes two distance calculations (charge site to carbonyl group and carbonyl group to exchange site) for the computer-generated structures is shown to better correlate to the experimentally determined per-residue deuterium uptake. Future comparisons of IMS-HDX-MS data with structures obtained from MDS are discussed with respect to novel experiments that will reveal the HDX rates of individual residues. Graphical Abstract
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98.
p‐Toluenesulfonic acid catalyzed the one‐pot, three‐component synthesis of 3‐aminoimidazo[1,2‐a]pyridines and pyrazines through a condensation reaction of a 2‐aminoazine, an aldehyde, and an isocyanide at room temperature. This methodology affords a number of 3‐aminoimidazo[1,2‐a]pyridines in reasonable yields and short reaction times without any significant optimization of the reaction conditions. 相似文献
99.
Abstract Bismuth(III) nitrate pentahydrate, Bi(NO3)3?·?5H2O, has been used as a mild, efficient, and inexpensive oxidant for the oxidative aromatization of several 1,3,5‐trisubstituted 2‐pyrazolines to pyrazoles in acetic acid under microwave irradiation with good to excellent yields. 相似文献
100.
Behrooz Maleki Saba Hemmati Reza Tayebee Sirous Salemi Yasaman Farokhzad Mehdi Baghayeri Farrokhzad Mohammadi Zonoz Elahe Akbarzadeh Rohollah Moradi Azam Entezari Mohammad Reza Abdi Samaneh Sedigh Ashrafi Fereshteh Taimazi Majid Hashemi 《Helvetica chimica acta》2013,96(11):2147-2151
A convenient synthesis of sulfonamides and sulfonyl azides from thiols is described. In situ preparation of sulfonyl chlorides from thiols was accomplished by oxidation with chloramine‐T (=N‐chlorotosylamide=N‐chloro‐4‐methylbenzenesulfonamide), tetrabutylammonium chloride (Bu4NCl), and H2O. The sulfonyl chlorides were then further allowed to react with excess amine or NaN3 in the same pot. 相似文献