Clotrimazole-triiodide ion association as an ion exchanger for a triiodide ion-selective electrode.

A novel triiodide ion-selective electrode based on a clotrimazole-triiodide ion pair as a membrane carrier was prepared. It has a linear response to triiodide from 8 x 10(-6) to 5 x 10(-3) M with a slope of -68.9 mV per decade and a detection limit of 5 x 10(-6) M. The electrode response is independent of the pH of the solution in the pH range 2-9. It has a very short response time and can be used for at least 3 months without any considerable divergence in the potentials. The proposed sensor revealed very good selectivities for I3- over a variety of other anions. It was used as an indicator electrode in the potentiometric titration of triiodide ions and in an indirect potentiometric determination of clotrimazole in pharmaceutical preparations.     

Ionic liquid promoted one-pot synthesis of 3-aminoimidazo[1,2-a]pyridines

3-Aminoimidazo[1,2-a]pyridines have been synthesized in good to excellent yields in the presence of the ionic liquid 1-butyl-3-methylimidazolium bromide [bmim]Br, the reaction workup is simple and the ionic liquid can be easily separated from the product and reused.     

Silica‐supported synthesis of some 1,3,5‐trisubstituted 2‐pyrazolines under solvent‐free and microwave irradiation conditions

A simple method for the synthesis of 2‐pyrazolines is described which occurs on silica surface under solvent‐free conditions within 110‐180 sec using microwave irradiation. The results obtained indicate that the use of silica gel as a support in pyrazoline formation reactions can have a profound effect on reaction rates and yields and cause cleaner reaction conditions.     

Fuzzy number linear programming: A probabilistic approach (3)

In the real world there are many linear programming problems where all decision parameters are fuzzy numbers. Several approaches exist which use different ranking functions for solving these problems. Unfortunately when there exist alternative optimal solutions, usually with different fuzzy value of the objective function for these solutions, these methods can not specify a clear approach for choosing a solution. In this paper we propose a method to remove the above shortcoming in solving fuzzy number linear programming problems using the concept of expectation and variance as ranking functions.     

Microcavity‐Stabilized Quantum Cascade Laser

Narrow‐linewidth lasers are key elements in optical metrology and spectroscopy. Spectral purity of these lasers determines accuracy of the measurements and quality of collected data. Solid state and fiber lasers are stabilized to relatively large and complex external optical cavities or narrow atomic and molecular transitions to improve their spectral purity. While this stabilization technique is rather generic, its complexity increases tremendously moving to longer wavelenghts, to the infrared (IR) range. Inherent increase of losses of optical materials at longer wavelengths hinders realization of compact, room temperature, high finesse IR cavities suitable for laser stabilization. In this paper, we report on demonstration of quantum cascade lasers stabilized to high‐Q crystalline mid‐IR microcavities. The lasers operating at room temperature in the 4.3‐4.6 μm region have a linewidth approaching 10 kHz and are promising for on‐chip mid‐IR and IR spectrometers.

     

Transesterification of canola oil over Li/Ca-La mixed oxide catalyst: Kinetics and calcination temperature investigations

In this research, a solid 1%Li/Ca-La mixed oxide catalyst was prepared using co-precipitation method followed by wet impregnation. The prepared catalyst was used in the transesterification reaction of canola oil and methanol for biodiesel synthesis. The effects of calcination and reaction temperatures were investigated on the activity of the catalyst. In addition, rate of the reaction was studied through a kinetic model for which parameters were determined. Surface properties and structure of the catalyst were characterized through the powder X-ray diffraction (XRD), thermogravimetry/derivative thermogravimetry (TG/DTG), and Fourier transform infrared spectroscopy analysis. All these emphasized that the performance of the catalyst corresponded to the generation of the active sites and their thermal activation.     

Co3O4 nanoparticles prepared by oxidative precipitation method: an efficient and reusable heterogeneous catalyst for N-formylation of amines

Research on Chemical Intermediates - N-formylation of different amines was carried out with formic acid in the presence of the Co3O4 nanoparticles as an efficient, stable heterogeneous catalyst to...     

A new method to detect periodically correlated structure

In this paper, we introduce a new method to test whether a discrete-time periodically correlated model explains an observed time series. The proposed method is based on the estimation of the support of spectral measure. Comparisons between our procedure and the methods which were proposed by Broszkiewicz-Suwaj et al. (Phys A 336:196–205, 2004) show that our testing procedure is more powerful. We investigate the performance of the proposed method by using real and simulated datasets.