Transient bioelectronics: Electronic properties of silver microparticle‐based circuits on polymeric substrates subjected to mechanical load

Transient soft bioelectronics are capable of forming conformal contacts with curvilinear surfaces of biological host tissues and organs. Such systems are often subject to continuous static and dynamic loads from the biological host. In this article, we present investigation of electronic attributes of transient soft bioelectronic circuits subjected to mechanical force and influence of substrate's transiency on the transiency of the whole device; also, characterize and quantify loss of functionality in triggered devices. Variations in the electrical conductivity of circuits as a function of applied mechanical load was used as a means to deduce electronic characteristics under stress. The experimental results suggest that there exists a correlation between electronic properties of circuits and applied mechanical strain; no clear correlation was, however, observed between electronic properties of circuits and frequency of the applied dynamic load. Control over transiency rate of identical circuits utilizing the transiency characteristics of the poly(vinyl alcohol)l‐based substrates is also studied and demonstrated. © 2015 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2015 , 53, 1603–1610     

Highly efficient oxidative cleavage of alkenes and cyanosilylation of aldehydes catalysed by magnetically recoverable MIL‐101

The catalytic activity of magnetically recoverable MIL‐101 was investigated in the oxidation of alkenes to carboxylic acids and cyanosilylation of aldehydes. MIL‐101 was treated with Fe₃O₄ and the prepared catalyst was characterized using Fourier transform infrared spectroscopy, X‐ray diffraction, N₂ adsorption measurements, field emission scanning electron microscopy, energy‐dispersive X‐ray spectroscopy and inductively coupled plasma analysis. The catalytic active sites in this heterogeneous catalyst are Cr³⁺ nodes of the MIL‐101 framework. This heterogeneous catalyst has the advantages of excellent yields, short reaction times and reusability several times without significant decrease in its initial activity and stability in both oxidation and cyanosilylation reactions. Its magnetic property allows its easy separation using an external magnetic field.     

Highly efficient protection of alcohols and phenols catalysed by tin porphyrin supported on MIL‐101

The catalytic activity of 5,10,15,20‐tetrakis(4‐aminophenyl)porphyrinatotin(IV) trifluoromethanesulfonate, [Sn^IV(TNH₂PP)(OTf)₂], supported on chloromethylated MIL‐101, was investigated in the trimethylsilylation of alcohols and phenols with hexamethyldisilazane (HMDS) and also their tetrahydropyranylation with 3,4‐dihydro‐2H‐pyran. Excellent yields, mild reaction conditions, short reaction times and reusability of the catalyst without significant decrease in its initial activity are noteworthy advantages of this supported catalyst. Copyright © 2015 John Wiley & Sons, Ltd.     

The Dynamic Nature of CO Adlayers on Pt(111) Electrodes

CO adlayers on Pt(111) electrode surfaces are an important electrochemical system and of great relevance to electrocatalysis. The potential‐dependent structure and dynamics of these adlayers are complex and still controversial, especially in the CO pre‐oxidation regime. We here employ in situ high‐speed scanning tunneling microscopy for studying the surface phase behavior in CO‐saturated 0.1 m H₂SO₄ on the millisecond time scale. At potentials near the onset of CO pre‐oxidation local fluctuations in the (2×2)‐CO adlayer are observed, which increase towards more positive potentials. Above 0.20 V (vs. Ag/AgCl), this leads to an adlayer where CO_ad apparently reside on every top site, but still exhibit a (2×2) superstructure modulation. We interpret this observation as a dynamic effect, caused by a small number of highly mobile point defects in the (2×2)‐CO adlayer. As shown by density functional theory calculations, the CO lattice near such defects relaxes into a local (1×1) arrangement, which can rapidly propagate across the surface. This scenario, where a static (2×2) CO_ad sublattice coexists with a highly dynamic sublattice of partially occupied top sites, explains the pronounced CO_ad surface mobility during electrooxidation.     

[Cu(bpdo)2·2H2O]2+-supported SBA-15 nanocatalyst for efficient one-pot synthesis of benzoxanthenone and benzochromene derivatives

A novel [Cu(bpdo)₂·2H₂O]²⁺-supported SBA-15 catalyst (bpdo = 2,2′-bipyridine,1,1′-dioxide) was prepared by the impregnation method. The catalyst was characterized by XRD, TEM, and BET nitrogen adsorption–desorption method, FT-IR, UV–vis, and chemical analysis. XRD patterns and TEM analysis of [Cu(bpdo)₂·2H₂O]²⁺/SBA-15 showed highly ordered hexagonal mesoporous silica, even after immobilization. Also, nitrogen adsorption–desorption isotherms exhibited type-IV isotherms and H1 hysteresis loops according to the IUPAC classification of mesoporous materials. This green support was tested for the synthesis of benzoxanthenone and benzochromene derivatives under solvent-free conditions, with high yield of products via a simple experimental and work-up procedure.     

Design and synthesis of new imidazo[1,2-b]pyrazole derivatives,in vitro α-glucosidase inhibition,kinetic and docking studies

Molecular Diversity - A new series of imidazo[1,2-b]pyrazole derivatives 4a–o was designed, synthesized, and screened for in vitro α-glucosidase inhibitory activity. All compounds showed...     

Attack on Han et al.’s ID-based confirmer (undeniable) signature at ACM-EC’03

In ACM conference on electronic commerce (EC’03), Han et al. [Identity-based confirmer signatures from pairings over elliptic curves, in: Proceedings of ACM Conference on Electronic Commerce Citation 2003, San Diego, CA, USA, June 09–12, 2003, pp. 262–263] proposed an ID-based confirmer signature scheme using pairings (the scheme is in fact an ID-based undeniable signature scheme). In this paper, we show that this signature scheme is not secure and the signer can deny any signature, even if it is a valid signature, and any one can forge a valid confirmer signature of a signer with identity ID on an arbitrary message and confirm this signature to the verifier.     

Experiments with an interactive paired comparison simplex method for molp problems

In this paper, an interactive paired comparison simplex based method formultiple objective linear programming (MOLP) problems is developed and compared to other interactive MOLP methods. The decision maker (DM)’s utility function is assumed to be unknown, but is an additive function of his known linearized objective functions. A test for ‘utility efficiency’ for MOLP problems is developed to reduce the number of efficient extreme points generated and the number of questions posed to the DM. The notion of ‘strength of preference ’ is developed for the assessment of the DM’s unknown utility function where he can express his preference for a pair of extreme points as ‘strong ’, ‘weak ’, or ‘almost indifferent ’. The problem of ‘inconsistency of the DM’ is formalized and its resolution is discussed. An example of the method and detailed computational results comparing it with other interactive MOLP methods are presented. Several performance measures for comparative evaluations of interactive multiple objective programming methods are also discussed. All rights reserved. This study, or parts thereof, may not be reproduced in any form without written permission of the authors.     

Reaction between isocyanides and dialkyl acetylenedicarboxylates in the presence of strong CH-acids: one-pot synthesis of highly functionalized annulated 4H-pyrans

The highly reactive 1:1 adduct, produced from the reaction between dialkyl acetylenedicarboxylates and alkyl isocyanides, was trapped by strong cyclic CH-acids such as 4-hydroxy-6-methyl-2H-pyran-2-one or 4-hydroxycoumarin to yield dialkyl 2-(alkylamino)-5-oxo-4H,5H-pyrano[3,2-c]chromene-3,4-dicarboxylates or dialkyl 7-methyl-2-(alkylamino)-5-oxo-4H,5H-pyrano[4,3-b]pyran-3,4-dicarboxylates in good yields at room temperature.