Friedel–Crafts acyl rearrangements in the fluoranthene series

Structural Chemistry - Friedel–Crafts monoacylation and diacylation of fluoranthene (FT) gave 3-acetyl-, 8-acetyl-, 3-benzoyl-, 8-benzoyl-, 3-(4-fluorobenzoyl)-, 8-(4-fluorobenzoyl)-,...     

Yields of Hydrogen and Hydrogen Peroxide from Argon–Water Vapor in Dielectric Barrier Discharge

Controlled chemical transformation of water vapor in dielectric barrier discharge (DBD) of argon into hydrogen and hydrogen peroxide for its usability as in situ or ex situ H₂ and H₂O₂ source are reported. Online analysis of the product gas mixture by conventional wet-chemical colorimetric method using buffered KI absorber solution revealed typical H₂O₂ G-value = 6.4 × 10^?3 µmol J^?1 (G-value defines as the number of molecules produced/consumed per 100 eV of energy; in SI unit G-value is expressed in µmol J^?1) in the absence of ozone. On the other hand, H₂ in product mixture analyzed in gas chromatograph-thermal conductivity detector (GC-TCD) with argon carrier revealed its G-value = 0.134 µmol J^?1. Enhancements in products’ yields were explored by varying gas residence time inside the plasma zone, and applied voltage and frequency on the dielectric surfaces. Employing a double-DBD reactor, at applied high voltage ~2.5 kV mm^?1 @50 Hz and gas residence time ~20 s resulted in the highest yields of H₂O₂. However, the H₂ yield increased continuously with increase in gas residence time. On the other hand, the single-dielectric barrier surface reactors were more efficient for high and exclusive generation of ex situ H₂ (e.g. maximum 1260 ppm; G-value typically 0.498 µmol J^?1).     

Unsteady compressible boundary layer flow in the stagnation region of a sphere with a magnetic field

Summary An analysis is performed to study the unsteady compressible laminar boundary layer flow in the forward stagnation-point region of a sphere with a magnetic field applied normal to the surface. We have considered the case where there is an initial steady state that is perturbed by the step change in the total enthalpy at the wall. The nonlinear coupled parabolic partial differential equations governing the flow and heat transfer have been solved numerically using a finite-difference scheme. The numerical results are presented, which show the temporal development of the boundary layer. The magnetic field in the presence of variable electrical conductivity causes an overshoot in the velocity profile. Also, when the total enthalpy at the wall is suddenly increased, there is a change in the direction of transfer of heat in a small interval of time. Received 15 January 1996; accepted for publication 21 November 1996     

Simultaneous heat and mass transfer under unsteady mixed convection along a vertical slender cylinder embedded in a porous medium

Unsteady laminar mixed convection flow (combined free and forced convection flow) along a vertical slender cylinder embedded in a porous medium under the combined buoyancy effect of thermal and species diffusion has been studied. The effect of the permeability of the medium as well as the magnetic field has been included in the analysis. The partial differential equations with three independent variables governing the flow have been solved numerically using a implicit finite difference scheme in combination with the quasilinearization technique. Computations have been carried out for accelerating, decelerating and oscillatory free stream velocity distributions. The effects of the permeability of the medium, buoyancy forces, transverse curvature and magnetic field on skin friction, heat transfer and mass transfer have been studied. It is found that the effect of free stream velocity distribution is more pronounced on the skin friction than on the heat and mass transfer. The permeability and magnetic parameters increase the skin friction, but reduce the heat and mass transfer. The skin friction, heat transfer and mass transfer are enhanced due to the buoyancy forces and curvature parameter. The heat transfer is strongly dependent on the viscous dissipation parameter and the Prandtl number, and the mass transfer on the Schmidt number.     

Unsteady free convection flow under the influence of a magnetic field

Summary The unsteady free convection boundary layer at the stagnation point of a two-dimensional body and an axisymmetric body with prescribed surface heat flux or temperature has been studied. The magnetic field is applied parallel to the surface and the effect of induced magnetic field has been considered. It is found that for certain powerlaw distribution of surface heat flux or temperature and magnetic field with time, the governing boundary layer equations admit a self-similar solution locally. The resulting nonlinear ordinary differential equations have been solved using a finite element method and a shooting method with Newton's corrections for missing initial conditions. The results show that the skin friction and heat transfer coefficients, andx-component of the induced magnetic field on the surface increase with the applied magnetic field. In general, the skin friction, heat transfer andx-component of the induced magnetic field for axisymmetric case are more than those of the two-dimensional case. Also they change more when the surface heat flux or temperature decreases with time than when it increases with time. The skin friction, heat transfer andx-component of the induced magnetic field are significantly affected by the magnetic Prandtl number and they increase as the magnetic Prandtl number decreases. The skin friction andx-component of the magnetic field increase with the dissipation parameter, but heat transfer decreases.

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Instationäre freie Konvektionsströmung unter dem Einfluß eines magnetischen Feldes

Übersicht Untersucht wurde die instationäre freie Konvektionsgrenzschicht am Ruhepunkt eines zweidimensionalen und achsensymmetrischen umströmten Körpers bei vorgegebenem Wärmefluß bzw. bei vorgegebener Temperatur an der Oberfläche. Das magnetische Feld wird parallel zur Oberfläche angelegt, und der Einfluß des induzierten magnetischen Feldes wurde berücksichtigt. Es stellt sich heraus, daß bei bestimmter, zeitlicher Potenzgesetzverteilung des Wärmeflusses bzw. der Temperatur und des magnetischen Feldes an der Oberfläche die geltenden Grenzschichtgleichungen örtlich eine selbstähnliche Lösung erlauben. Die sich ergebenden nichtlinearen gewöhnlichen Differentialgleichungen wurden mittels einer Finite-Element-Methode und einer Shooting-Methode mit Newtonschen Korrekturen für fehlende Anfangsbedingungen gelöst. Die Ergebnisse zeigen, daß die Oberflächenreibung und die Wärmeübergangskoeffizienten sowie diex-Komponente des induzierten magnetischen Feldes an der Oberfläche mit dem angelegten magnetischen Feld zunehmen. Im allgemeinen sind die Oberflächenreibung, der Wärmeübergang und diex-Komponente des induzierten magnetischen Feldes im achsensymmetrischen Fall größer als die entsprechenden Werte im zweidimensionalen Fall. Außerdem verändern sich diese Werte beim zeitlichen Abfallen des Wärmeflusses an der Oberfläche bzw. der Temperatur in höherem Maße als bei der zeitlichen Zunahme dieser Werte. Die Oberflächenreibung, der Wärmeübergang und diex-Komponente des induzierten magnetischen Feldes werden durch die magnetische Prandtl-Zahl erheblich beeinflußt; sie nehmen mit abfallender magnetischer Prandtl-Zahl zu. Die Oberflächenreibung und diex-Komponente des magnetischen Feldes nehmen mit dem Wärmeableitungsparameter zu, der Wärmeübergang jedoch fällt ab.

     

Non-darcy natural convection on a vertical cylinder in a saturated porous medium

The steady free convection boundary layer flow of non-Darcy fluid along an isothermal vertical cylinder embedded in a saturated porous medium using the Ergun model has been studied. The partial differential equations governing the flow have been solved numerically using an implicit finite-difference scheme developed by Keller. It is found that the heat transfer is strongly affected by the modified Grashof number which characterizes the non-Darcy fluid, and the curvature parameter. Also the heat transfer is found to be more than that of the flat plate.     

Unsteady free convection flow over an infinite vertical porous plate due to the combined effects of thermal and mass diffusion,magnetic field and Hall currents

The unsteady free convection flow over an infinite vertical porous plate, which moves with time-dependent velocity in an ambient fluid, has been studied. The effects of the magnetic field and Hall current are included in the analysis. The buoyancy forces arise due to both the thermal and mass diffusion. The partial differential equations governing the flow have been solved numerically using both the implicit finite difference scheme and the difference-differential method. For the steady case, analytical solutions have also been obtained. The effect of time variation on the skin friction, heat transfer and mass transfer is very significant. Suction increases the skin friction coefficient in the primary flow, and also the Nusselt and Sherwood numbers, but the skin friction coefficient in the secondary flow is reduced. The effect of injection is opposite to that of suction. The buoyancy force, injection and the Hall parameter induce an overshoot in the velocity profiles in the primary flow which changes the velocity gradient from a negative to a positive value, but the magnetic field and suction reduce this velocity overshoot.     

Study of complexation of an ionic liquid inside into crown ethers in aqueous environments by physicochemical techniques

Inclusion complexation between crown ethers (CEs) (viz., 15-crown-5, 18-crown-6) and an ionic liquid (IL) (viz., 1-ethyl-3-methylimidazolium tosylate) in aqueous medium have been demonstrated by conductivity, surface tension and ¹Proton Nuclear Magnetic Resonance (H NMR) study. The results show the formation of 1:1 complexes between CEs and the IL through electron-deficient imidazolium cation and electron pairs of oxygen atoms of the CEs. Hydrogen bonding is the key factor responsible for complexation, while, the ion–dipole interactions also contribute towards the complex formation. The formation constants have been derived from conductivity study and the complexes have been analysed by ¹H NMR study.     

Efficient synthesis of acridinediones in aqueous media

An efficient synthesis of acridinediones in two steps have been achieved using water as a reaction media without chromatographic purification. First step involves the reaction of dimedone with ammonium acetate to yield enaminone in water which on further reaction with various aldehydes yields acridinedione in aqueous media. The reaction merits the use of water as solvent, no additive catalyst and provides high yield of products with good purity.     

Synthesis,characterization, and applications with the manifestation of antifungal activity and seed germination properties of nickel doped zinc oxide nano platform by biochemical contrivance

In the recent era, nanotechnology, a rapidly emerging field, has been explored as the most studied field worldwide. The goal of this study is to use neem leaves extract as an effective ‘reducing agent’ and ‘stabilizing agent’ in the green synthesis of bio-medically important Zn_1-XNi_XO (X = 0.00, 0.04, 0.08, 0.12) nanoparticles. The molar concentrations of nickel nitrate and zinc nitrate are varied to produce nickel-doped ZnO nanoparticles. Color change is the first indicator of nanoparticle formation during this biosynthesis. The hexagonal wurtzite structure with good crystallinity is confirmed by X-ray diffraction. FTIR analysis reveals the fact that the Zn–O stretching vibration shifts with the introduction of impurities into the ZnO matrix. UV–Vis spectra show the typical surface plasma resonance around 370 nm and the hydrodynamic diameter is larger than the size calculated from the XRD value, according to DLS. The main finding of this study is that Ni_0.12Zn_0.88O has a strong antifungal activity against and a significant growth rate after treating wheat seeds with biologically synthesized Ni_0.12Zn_0.88O nanoparticles.