全文获取类型
收费全文 | 217篇 |
免费 | 3篇 |
专业分类
化学 | 129篇 |
力学 | 5篇 |
数学 | 24篇 |
物理学 | 62篇 |
出版年
2016年 | 3篇 |
2015年 | 2篇 |
2014年 | 3篇 |
2013年 | 40篇 |
2012年 | 2篇 |
2011年 | 3篇 |
2010年 | 2篇 |
2009年 | 4篇 |
2008年 | 3篇 |
2007年 | 9篇 |
2005年 | 4篇 |
2003年 | 5篇 |
2002年 | 7篇 |
2001年 | 2篇 |
2000年 | 4篇 |
1999年 | 4篇 |
1997年 | 2篇 |
1996年 | 12篇 |
1995年 | 4篇 |
1994年 | 4篇 |
1993年 | 5篇 |
1992年 | 2篇 |
1991年 | 4篇 |
1989年 | 4篇 |
1987年 | 3篇 |
1986年 | 7篇 |
1982年 | 3篇 |
1981年 | 3篇 |
1980年 | 4篇 |
1979年 | 3篇 |
1977年 | 4篇 |
1976年 | 4篇 |
1973年 | 2篇 |
1972年 | 3篇 |
1971年 | 2篇 |
1970年 | 6篇 |
1969年 | 5篇 |
1968年 | 6篇 |
1967年 | 3篇 |
1965年 | 2篇 |
1962年 | 1篇 |
1961年 | 1篇 |
1951年 | 1篇 |
1941年 | 1篇 |
1940年 | 2篇 |
1937年 | 2篇 |
1936年 | 4篇 |
1933年 | 2篇 |
1932年 | 1篇 |
1928年 | 1篇 |
排序方式: 共有220条查询结果,搜索用时 15 毫秒
71.
Ohne Zusammenfassung 相似文献
72.
73.
74.
Majer J. 《Colloid and polymer science》1962,184(1):90
Ohne Zusammenfassung 相似文献
75.
Schmid DG Majer F Kupke T Jung G 《Rapid communications in mass spectrometry : RCM》2002,16(18):1779-1784
The microbial flavoenzyme EpiD catalyzes the oxidative decarboxylation of peptidyl-cysteines to peptidyl-aminoenethiols. These unusual C-terminally modified peptides are intermediates in the biosynthesis of the tetracyclic peptide antibiotic epidermin, which belongs to the lantibiotics family. The peptide SFNSYCC represents the C-terminal partial sequence of the natural precursor peptide EpiA. EpiA is posttranslationally modified to form finally the lantibiotic epidermin. The substrate specificity of EpiD was investigated using high-resolution mass spectrometry and the heptapeptide library SFNSXCC. The enzymatic conversion of particular peptides can be observed by a mass loss of m/z 46. In contrast to the previously used triple quadrupole instrument, electrospray ionization Fourier transform ion cyclotron resonance mass spectrometry (ESI-FTICR-MS) was able to resolve and detect all precursor and converted peptides with identical nominal masses in a single measurement, avoiding the necessity to investigate single peptides. Furthermore, a new substrate SFNSCCC of the enzyme EpiD was detected within the reaction mixture. 相似文献
76.
John J. Morelli Somayajula K. Viswanadham Andrew. G. Sharkey JR. David M. Hercules 《International journal of environmental analytical chemistry》2013,93(2-4):295-323
Abstract Laser mass spectra obtained for 20 organophosphorus (OP) compounds were systematically evaluated for groups containing analogous structural features. Variations in fragmentation can be understood based on simple organic reactions. While detailed mechanistic interpretations of the laser mass spectra (LMS) were not possible, the qualitative features in the LMS obtained from five compounds, not in the original set, could be predicted based on the characteristics of the other OP compounds studied. The success of the prediction lends credence to the qualitative models developed for rationalizing the LMS. A specific feature in the LMS of aromatic thionophosphates is a thiono-thiolo rearrangement. Detailed investigation into the phenomena involved comparison of LMS obtained from aromatic thionophosphates with spectra from electron impact, chemical ionization, field desorption, and secondary ion mass spectrometry. These results led to the conclusion that the rearrangement in laser mass spectrometry must occur during volatilization while the molecule/ion is in the “cloud” present immediately above the laser impact area. 相似文献
77.
We demonstrate a new approach for the asymmetric synthesis of bissetone. The key reaction is the highly enantioselective hetero-Diels–Alder cycloaddition of triene 3 with ethyl glyoxylate catalyzed by readily available BINOL–Ti complexes. The HDA cycloadduct 4 was then transformed in five steps into O-protected bissetone (8) and its C5-epimer in good yield. 相似文献
78.
Several low molecular weight alkanes have been polymerized (polycondensed) over HSO3 F-SbF5 to yield a highly branched oily oligomer with a molecular weight range from the molecular weight of the monomer to around 700. The order of reactivity for butane and lower molecular alkanes is isobutane > n-butane > propane > ethane > methane. The reactivity is explained by the ease of attack of an acid proton derived from the acid on the alkane sigma bonds as well as the relative stability of the resulting cation formed. A cationic mechanism for this reaction is proposed. 相似文献
79.
80.
S. A. Liebman D. H. Ahlstrom W. H. Starnes JR. F. C. Schilling 《高分子科学杂志,A辑:纯化学与应用化学》2013,50(6):935-950
This study compares the use of pyrolysis hydrogenation gas chromatography (PHGC) and 13C Fourier transform nuclear magnetic resonance (FTNMR) methods for the analysis of reference polyethylene (PE) samples, ethylene-α-olefin copolymers, and specially prepared poly(vinyl chloride) (PVC) samples which were reduced to their PE skeletal structures. The nature and relative quantities of the short branches along the polymer chains were determined using both techniques. Improved high-resolution PHGC data, obtained with a fused silica capillary separation column, gave results which were in satisfactory agreement with the 13C FTNMR data. This approach confirms that detailed microstructural information can be obtained with these methods by using carefully controlled experimental conditions and appropriate reference systems. 相似文献