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11.
A model of two interacting (chemically different) linear polymer chains is solved exactly using the real-space renormalization
group transformation on a family of Sierpinski gasket type fractals and on a truncated 4-simplex lattice. The members of the
family of the Sierpinski gasket-type fractals are characterized by an integer scale factorb which runs from 2 to ∞. The Hausdorff dimensiond
F of these fractals tends to 2 from below asb → ∞. We calculate the contact exponenty for the transition from the State of segregation to a State in which the two chains are entangled forb = 2-5. Using arguments based on the finite-size scaling theory, we show that forb→∞, y = 2 - v(b) d
F, wherev is the end-toend distance exponent of a chain. For a truncated 4-simplex lattice it is shown that the system of two chains
either remains in a State in which these chains are intermingled in such a way that they cannot be told apart, in the sense
that the chemical difference between the polymer chains completely drop out of the thermodynamics of the system, or in a State
in which they are either zipped or entangled. We show the region of existence of these different phases separated by tricritical
lines. The value of the contact exponenty is calculated at the tricritical points. 相似文献
12.
Applying tight-binding approximation and spin pairing of like charge carriers in a pair of excitons created in a lattice, the possibility of forming a bound exciton-exciton state is studied. It is found that, provided there exists strong exciton-lattice interaction, such a bound state may be formed and its energy may lie within the valence band deforming the material into a crystalline solid with no energy gap. Lowering of the energy is calculated in naphthalene and anthracene crystals where some experimental results are known. The excess energy released after the formation of such bound state can be adequate, depending on the material, to desorb neutral atoms or eject of electrons from surfaces. 相似文献
13.
14.
Synchronized whistlers recorded at Varanasi 总被引:1,自引:0,他引:1
Some interesting events of synchronized whistlers recorded at low latitude station Varanasi during magnetic storm period of
the year 1977 are presented. The dynamic spectrum analysis shows that the component whistlers are Eckersley whistlers having
dispersion 10 s1/2 and 30 s1/2. An attempt has been made to explain the dynamic spectra using lightning discharge generated from magnetospheric sources 相似文献
15.
The occurrence of charge on recoil56Mn produced by the (n,γ) reaction in polycrystalline potassium permanganate has been examined using the ‘charge plate technique’.
From considerations of capture gamma ray decay schemes and internal conversion it appears that, in a condensed medium, the
recoil atom develops charge after losing much of its initial kinetic energy which allows collection on charged electrodes.
Preliminary findings were presented at the International Symposium on Radiochemistry and Radiation Chemistry, RC-41 BARC,
Bombay, Feb. 4–6 (1991). 相似文献
16.
Praveen K. Tandon Gayatri Sumita Sahgal Manish Srivastava Santosh B. Singh 《应用有机金属化学》2007,21(3):135-138
Catalytic activities of three transition metals, as iridium (III) chloride, rhodium (III) chloride and palladium (II) chloride, were compared in the oxidation of six aromatic aldehydes (benzaldehyde, p‐chloro benzaldehyde, p‐nitro benzaldehyde, m‐nitro benzaldehyde, p‐methoxy benzaldehyde and cinnamaldehyde), two hydrocarbons (viz. (anthracene and phenanthrene)) and one aromatic and one cyclic alcohol (cyclohexanol and benzyl alcohol) by 50% H2O2. The presence of traces (substrate: catalyst ratio equal to 1:62500 to 1:1961) of the chlorides of iridium(III), rhodium(III) and palladium(II) catalyze these oxidations, resulting in good to excellent yields. It was observed that in most of the cases palladium(II) chloride is the most efficient catalyst. Conditions for the highest and most economical yields were obtained. Deviation from the optimum conditions decreases the yields. Oxidation in aromatic aldehydes is selective at the aldehydeic group only and other groups remain unaffected. This new, simple and economical method, which is environmentally safe, also requires less time. Reactive species of catalysts, existing in the reaction mixture are also discussed. Copyright © 2007 John Wiley & Sons, Ltd. 相似文献
17.
In this short communication, we have evaluated the effect of thermal velocity of the plasma particles on the energy of resonantly
interacting energetic electrons with the propagating whistler mode waves as a function of wave frequency and L-value for the
normal and disturbed magnetospheric conditions. During the disturbed conditions when the magnetosphere is depleted in electron
density, the resonance energy of the electron enhances by an order of magnitude at higher latitudes, whereas the effect is
small at low latitudes. An attempt is made to explain the enhanced wave activity observed during magnetic storm periods. 相似文献
18.
JPC – Journal of Planar Chromatography – Modern TLC - A high-performance thin-layer chromatographic (HPTLC) method has been established for simple and rapid quantification of two... 相似文献
19.
The output characteristics of a high repetition rate pulsed dye laser has both short-term fluctuations and long-term drift.
In high power high repetition rate lasers flow induced variations dominate over those due to other factors. In this paper
it is shown by dye laser measurements that bandwidth fluctuations can be traced to the effective changes of the resonator
dispersion due to fluctuations in the penetration depth of the pump beam in the dye medium. Short-term wavelength fluctuations
can be traced to instantaneous deflection of the dye laser axis by the refractive index changes due to absorption of the pump
beam. The fluctuations in both the bandwidth and the wavelength decreases with increasing flow rates within a laminar region.
A copper vapor laser operating at 5.6 kHz repetition rate pumped the Rhodamine 6G dye laser used. The wavelength fluctuation
of ±0.0035, 0.0030, 0.0004 nm and the bandwidth fluctuation of ±710, 132, 45 MHz over approx. 60 minutes were observed at
1.2, 3.7, 5.5 lpm flow rates respectively. 相似文献
20.
S. C. Joshi M. P. Singh V. P. Pandey B. S. Rajput 《International Journal of Theoretical Physics》2002,41(6):1107-1125
In four-dimensional N = 4 supersymmetric gauge theory, we obtain an exact metric on the moduli space of quantum vacua and analyze the spectra of BPS states in weak as well as in strong coupling regions. Identifying the hypermultiplet of the dyonic state as a string stretched between D3-brane probe and a 7-brane, we demonstrate that the two hypermultiplets, which become massless at two singularities in supersymmetric theory, correspond to open strings beginning on the D3-brane and ending on the respective 7-brane. 相似文献