Extraction of PCDD/PCDF from soil with supercritical CO2: Optimization by a three-level factorial design approach

A highly sensitive and selective voltammetric procedure is described for the simultaneous determination of eleven elements (Cd, Pb, Cu, Sb, Bi, Se, Zn, Mn, Ni, Co and Fe) in water samples. Firstly, differential pulse anodic stripping voltammetry (DPASV) with a hanging mercury drop electrode (HMDE) is used for the direct simultaneous determination of Cd, Pb, Cu, Sb and Bi in 0.1 M HCl solution (pH = 1) containing 2 M NaCl. Then, differential pulse cathodic stripping voltammetry (DPCSV) is used for the determination of Se in the same solution. Zn is subsequently determined by DPASV after raising the pH of the same solution to pH 4. Next, the pH of the medium is raised to pH 8.5 by adding NH₃/NH₄Cl buffer solution for the determination of Mn by DPASV. Ni and Co are determined in the same solution by differential pulse adsorptive stripping voltammetry (DPAdSV) after adding DMG (1 × 10^–4 M). Finally, 1 × 10^–5 M 2-(5-bromo-2-pyridylazo)-5-diethylaminophenol (5-Br-PADAP) is added to the solution for the determination of Fe by DPAdSV. The optimal conditions are described. Relative standard deviations and relative errors are calculated for the eleven elements at three different concentration levels. The lower detection limits for the investigated elements range from 1.11 × 10^–10 to 1.05 × 10^–9 M, depending on the element determined. The proposed analysis scheme was applied for the determination of these eleven elements in some ground water samples.     

Bose-Einstein correlations in neutrino and antineutrino interactions in deuterium

Bose-Einstein correlations between pions of equal charge have been observed in Charged Current and Neutral Current (anti)neutrino-deuterium interactions in the BEBC bubble chamber exposed to the SPS wide band beam. The pion emission region is found to be essentially spherical with a mean radius of (0.48±0.07) fm; the chaoticity parameter is 0.36±0.04.     

High transverse momentumη production in π− p, π+ p,andpp interactions at 280 GeV/c

The inclusive cross sections for η production by the interactions of 280 GeV/c momentum π^?, π⁺, and proton beams in hydrogen have been measured. The kinematical range covered is ?0.45<x _F <0.45, and 4.0<P _T <7.0 GeV/c for Feynmanx _F and transverse momentum respectively. The η to π⁰ cross section ratios are given for the three reactions. The ratio of π^? p to π⁺ p cross sections for η production in the above kinematic ranges is 1.22±0.08±0.11.     

Event-by-event search for charged-neutral fluctuations in Pb-Pb collisions at 158 A⋅GeV

We analyse the proton electromagnetic form factor ratioR(Q ² ) =QF ₂ (Q ² )/F ₁ (Q ² ) as a function of momentum transferQ ² within perturbative QCD. We find that the prediction for (R(Q ² ) at large momentum transferQ depends on the exclusive quark wave functions, which are unknown. For a wide range of wave functions we find thatQF ₂ F ₁ ～ const. at large momentum transfer, which is in agreement with recent JLAB data.     

Production of π0 mesons and charged hadrons in\bar v neon and ν neon charged current interactions

The average multiplicities of charged hadrons and of π⁺, π^? and π⁰ mesons, produced in \(\bar v\) Ne and νNe charged current interactions in the forward and backward hemispheres of theW ^±-nucleon center of mass system, are studied with data from BEBC. The dependence of the multiplicities on the hadronic mass (W) and on the laboratory rapidity (y _Lab) and the energy fraction (z) of the pion is also investigated. Special care is taken to determine the π⁰ multiplicity accurately. The ratio of average π multiplicities \(\frac{{2\left\langle {n_{\pi ^O } } \right\rangle }}{{[\left\langle {n_{\pi ^ + } } \right\rangle + \left\langle {n_{\pi ^ - } } \right\rangle ]}}\) is consistent with 1. In the backward hemisphere \(\left\langle {n_{\pi ^O } } \right\rangle \) is positively correlated with the charged multiplicity. This correlation, as well as differences in multiplicities between \(\mathop v\limits^{( - )} \) and \(\mathop v\limits^{( - )} \) , \(\mathop v\limits^{( - )} \) scattering, is attributed to reinteractions inside the neon nucleus of the hadrons produced in the initial \(\mathop v\limits^{( - )} \) interaction.     

Wijsman topology on function spaces

LetC(X,Y) be the space of continuous functions from a metric space (X,d) to a metric space (Y, e).C(X, Y) can be thought as subset of the hyperspaceCL(X×Y) of closed and nonempty subsets ofX×Y by identifying each element ofC(X,Y) with its graph. We considerC(X,Y) with the topology inherited from the Wijsman topology induced onCL(X×Y) by the box metric ofd ande. We study the relationships between the Wijsman topology and the compact-open topology onC(X,Y) and also conditions under which the Wijsman topology coincide with the Fell topology. Sufficient conditions under which the compactopen topology onC(X,Y) is weaker than the Wijsman topology are given (IfY is totally bounded, then for every metric spaceX the compactopen topology onC(X,Y) is weaker than the Wijsman topology and the same is true forX locally connected andY rim-totally bounded). We prove that a metric spaceX is boundedly compact iff the Wijsman topology onC(X, ℝ) is weaker than the compact-open topology. We show that ifX is a σ-compact complete metric space andY a compact metric space, then the Wijsman topology onC(X,Y) is Polish.     

A study of the centrally producedK *0 K^{*0} \bar K^{*0} final state in the reactionpp→p f (K + K -π+π-)p s at 300 GeV/c

The reactionpp→p _f (K ⁺ K ^-π⁺π^-)p _s , where theK ⁺ K ^? π⁺π^- system is centrally produced, has been studied at 300 GeV/c. TheK ^*0 \(K^{*0} \bar K^{*0} \) final state has been observed and the cross sections for its central production are found to be the same at 300 and 85 GeV/c. TheK ^*0 \(K^{*0} \bar K^{*0} \) final state appears to be produced as a non-resonant threshold enhancement.     

Measurement of the structure functionsF 2 andxF 3 and comparison with QCD predictions including kinematical and dynamical higher twist effects

The isoscalar nucleon structure functionsF ₂(x, Q ²) andxF ₃(x, Q ²) are measured in the range 0<Q ²<64 GeV², 1.7<W ²<250 GeV²,x<0.7 using ν and \(\bar v\) interactions on neon in BEBC. The data are used to evaluate possible higher twist contributions and to determine their impact on the evaluation of the QCD parameter Λ. In contrast to previous analyses reaching to such lowW ² values, it is found that a low \(\Lambda _{\overline {MS} } \) value in the neighbourhood of 100 MeV describes the data adequately and that the contribution of dynamical higher twist effects is small and negative.     

Study of theK + K − π+ π− system centrally produced in the reactions π+ p→π+(K + K − π+ π−)p andpp→p(K + K − π+ π−)p at 85 GeV/c

The reactions π⁺ p→π⁺(K ⁺ K ^? π⁺ π^? p andpp→p(K ⁺ K ^? π⁺ π^?)p where the (K ⁺ K ^? π⁺ π^?) system is centrally produced have been studied at 85 GeV/c. 48% of the final state proceeds through single or double vector meson resonant production i.e.,K ^*0(890) (37%), ? (4%),ρ ⁰ (7%). Evidence is found for associatedK ^*0 (890) \(\bar K\) ^*o (890) production (6.4±1.1%) with a cross section ten times higher than that found for associated ? ? production in the same experiment.     

A measurement of $K^{*\pm}$ production in the hyperon beam experiment at CERN

We report on a measurement of the differential cross sections of inclusive production in and neutron beams. A strong leading particle effect was observed for production by . The measured –distributions are compared with calculations based on the Lund model (PYTHIA) and the quark-gluon string model. Received: 6 August 2001 / Revised version: 3 September 2001 / Published online: 5 October 2001