An approach to substituted 4-hydroxypyran-2-ones

We examined a method for the preparation of 4-hydroxypyran-2-ones in two steps from aryl ketones and ethyl malonyl chloride (or ethyl 2-methylmalonyl chloride). These 4-hydroxypyran-2-ones are useful precursors as they may be transformed in two steps to the 2-methoxypyran-4-ones, which is found in phenoxan—a naturally occurring compound discovered to have anti-HIV activity.     

Thermal and chromatographic behaviour of metal complexes. Part III. Complexes of palladium(II) with iminodiacetic acid

A study of the thermal properties of the complexes formed between Pd(II) and iminodiacetic acid (IDA) and the chromatographic analysis of their thermal decomposition products have been carried out. The dehydration of the isolated compounds is detected above 100°C. The decarboxylation process of the COO^? groups takes place yielding CO₂ and CO simultaneously or consecutively if they are not coordinated, respectively. The formation of gases (methane, ethane, etc.) is also observed.     

Abraham Model Correlations for Triethylene Glycol Solvent Derived from Infinite Dilution Activity Coefficient,Partition Coefficient and Solubility Data Measured at 298.15 K

A gas chromatographic headspace analysis method was used to experimentally determine gas-to-liquid partition coefficients and infinite dilution activity coefficients for 29 liquid organic solutes dissolved in triethylene glycol at 298.15 K. Solubilities were also determined at 298.15 K for 23 crystalline nonelectrolyte organic compounds in triethylene glycol based on spectroscopic absorbance measurements. The experimental results of the headspace chromatographic and spectroscopic solubility measurements were converted to gas-to-triethylene glycol and water-to-triethylene glycol partition coefficients, and molar solubility ratios using standard thermodynamic relationships. Expressions were derived for solute transfer into triethylene glycol by combining our measured experimental values with published literature data. Mathematical correlations based on the Abraham model describe the observed partition coefficient and solubility data to within 0.16 log₁₀ units (or less).     

Lithium diisopropylamide solvated by hexamethylphosphoramide: substrate-dependent mechanisms for dehydrobrominations

Lithium diisopropylamide-mediated dehydrobrominations of exo-2-bromonorbornane, 1-bromocyclooctene, and cis-4-bromo-tert-butylcyclohexane were studied in THF solutions and THF solutions with added hexamethylphosphoramide (HMPA). Rate studies reveal a diverse array of mechanisms based on mono-, di-, and trisolvated monomers as well as triple ions. The results are contrasted with analogous eliminations in THF in the absence of HMPA.     

Searching for an extra neutral gauge boson from muon pair production at LHC

We search for signatures of the extra neutral gauge boson Z^′$Z^{\prime }$, predicted in some extensions of the Standard Model, from the analysis of some distributions for p+p→μ⁺+μ⁻+X$p+p\to {\mu }^{+}+{\mu }^{-}+X$, where the only exotic particle involved is Z^′$Z^{\prime }$. In addition to the invariant mass and charge asymmetry distributions, we propose in our search to use the transverse momentum distribution (pT$p_T$) as an observable. We do our calculation for two values of the LHC center of mass energy (7 and 14 TeV), corresponding to 1 and 100 fb⁻¹ of luminosity, in order to compare our findings from some models with the distributions following from the Standard Model. By applying convenient cuts in the invariant mass, we show that the final particles pT$p_T$ distributions can reveal the presence of an extra neutral gauge boson contribution. We also claim that it is possible to disentangle the models considered here and we emphasize that the minimal version of the model, based on SUC₍₃₎×SUL₍₃₎×UX₍₁₎$\mathit{SU}{(3)}_C\times \mathit{SU}{(3)}_L\times U{(1)}_X$ symmetry, presents the more clear signatures for Z^′$Z^{\prime }$ existence.