Supercritical carbon dioxide extraction of Sm+3 and Nd+3 from solid matrix using Cyanex 921

The goal of this research was to investigate the feasibility of removing samarium and neodymium ions from solid matrix using Cyanex 921 in supercritical CO₂. The effect of various parameters such as pressure, temperature, extraction time, and stoichiometry of the complexation reaction was studied and optimized. It was found that optimal parameters are, respectively, 9 and 11 MPa, 45°C, 30 min, and 1: 3 (metal: ligand) for both samarium and neodymium. The conditional formation constant for the complexation reaction of samarium and neodymium with Cyanex 921 in the supercritical fluid phase was calculated as log K _d = 1.51 and log K _d = 1.08, respectively.

     

An efficient method for synthesis of acylals from aldehydes using multi-walled carbon nanotubes functionalized with phosphonic acid(MWCNTs-C-PO_3H_2)

MWCNTs-C-PO_3H_2 has been used as an efficient,heterogeneous and reusable nanocatalyst for synthesis of acylals from aldehydes under solvent-free conditions at room temperature.A wide range of aldehydes was studied and corresponding products were obtained in good to excellent yields in short reaction times.Nanocatalyst can be easily recovered by centrifuge and reused for subsequent reactions for at least five times without deterioration in catalytic activity.The major advantages of the present method are high yields,short reaction time,recyclable catalyst and solvent-free reaction conditions at room temperature.     

Synthesis,characterization, anticancer activity,thermal and electrochemical studies of some novel uranyl Schiff base complexes

Some tetradentate N₂O₂ Schiff base ligands, such as N,N′-bis(naphtalidene)-1,2-phenylenediamine, N,N′-bis(naphtalidene)-4-methyl-1,2-phenylenediamine, N,N′-bis(naphtalidene)-4-chloro-1,2-phenylenediamine, N,N′-bis(naphtalidene)-4-nitro-1,2-phenylenediamine, N,N′-bis(naphtalidene)-4-carboxyl-1,2-phenylenediamine, and their uranyl complexes were synthesized and characterized by ¹H NMR, IR, UV–Vis spectroscopy, TG (thermogravimetry), and elemental analysis (C.H.N.). Thermogravimetric analysis shows that uranyl complexes have very different thermal stabilities. This method is used also to establish that only one solvent molecule is coordinated to the central uranium ion and this solvent molecule does not coordinate strongly and is removed easier than the tetradentate ligand and also trans oxides. The electrochemical properties of the uranyl complexes were investigated by cyclic voltammetry. Electrochemistry of these complexes showed a quasireversible redox reaction without any successive reactions. Also, the kinetic parameters of thermal decomposition were calculated using Coats–Redfern equation. According to Coats–Redfern plots the kinetics of thermal decomposition of the studied complexes is first-order in all stages. Anticancer activity of the uranyl Schiff base complexes against cancer cell lines (Jurkat) was studied and determined by MTT (3-[4,5-dimethylthiazol-2-yl]-2,5-diphenyltetrazoliumbromide) assay.     

Vector Product Approach of Producing Non-Gaussian States

International Journal of Theoretical Physics - Two new configurations of superposition of quantum states corresponding to the angular momentum of spin-1 quantum system is proposed in this article....     

Proton radioactivity half-lives with nuclear asymmetry factor

The dependence of proton emission half-lives on the nuclear asymmetry parameter is investigated using the WKB method and two types of empirical formula.Using the single-folding formalism with asymmetry-depend-ent nuclear radius and surface diffuseness of nuclear matter,the nuclear potential and consequently the half-life are functions of the asymmetry factor.Despite small values of asymmetry in neutron-deficient proton emitters,notice-able changes in the half-lives are observed.The addition of an asymmetry parameter term to the two forms of empir-ical formulas leads to a reduction in the rms error for ground state and isomeric transitions.A noticeable reduction of about 43%is obtained for isomeric transitions in the second form of the empirical formula.Considering ground state transitions in two categories,odd-even and odd-odd emitters,and adopting deformation and asymmetry-dependent empirical formulas,the rms decreases remarkably.The low est values of rms errors,viz.0.1492,0.2312,and 0.1999,are obtained for the aforementioned empirical formulas for ground state transitions of odd-even and odd-odd emit-ters and for all isomeric transitions,respectively.     

Application of graphene oxide nanosheets as probe oligonucleotide immobilization platform for DNA sensing

In this work, a simple and novel electrochemical biosensor based on a glassy carbon electrode (GCE) modified with graphene oxide nanosheets (GO) was developed for detection of DNA sequences. The morphology of prepared nanoplatform was investigated by scanning electron microscopy, infrared (FTIR) and UV/Vis absorption spectra. The fabrication processes of electrochemical biosensor were characterized with cyclic voltammetry and electrochemical impedance spectroscopy (EIS) in an aqueous solution. The optimization of experimental conditions such as immobilization of the probe BRCA1 and its hybridization with the complementary DNA was performed. Due to unique properties of graphene oxide nanosheets such as large surface area and high conductivity, a wide liner range of 1.0 × 10^?17–1.0 × 10^?9 M and detection limit of 3.3 × 10^?18 M were obtained for detection of BRCA1 5382 mutation by EIS technique. Under the optimum conditions, the proposed biosensor (ssDNA/GO/GCE) revealed suitable selectivity for discriminating the complementary sequences from non-complementary sequences, so it can be applicable for detection of breast cancer.