首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   399篇
  免费   30篇
  国内免费   8篇
化学   258篇
晶体学   3篇
力学   17篇
数学   56篇
物理学   103篇
  2023年   2篇
  2022年   11篇
  2021年   17篇
  2020年   22篇
  2019年   28篇
  2018年   36篇
  2017年   16篇
  2016年   27篇
  2015年   17篇
  2014年   35篇
  2013年   59篇
  2012年   30篇
  2011年   14篇
  2010年   15篇
  2009年   15篇
  2008年   12篇
  2007年   19篇
  2006年   15篇
  2005年   12篇
  2004年   2篇
  2003年   5篇
  2002年   7篇
  2001年   1篇
  2000年   2篇
  1998年   1篇
  1997年   5篇
  1988年   2篇
  1980年   1篇
  1979年   1篇
  1977年   3篇
  1973年   1篇
  1969年   1篇
  1968年   2篇
  1967年   1篇
排序方式: 共有437条查询结果,搜索用时 31 毫秒
141.
Let (X, ) and (Y,C) be two measurable spaces withX being a linear space. A system is determined by two functionsf(X): X X and:X×YX, a (small) positive parameter and a homogeneous Markov chain {y n } in (Y,C) which describes random perturbations. States of the system, say {x n X, n=0, 1,}, are determined by the iteration relations:x n+1 =f(x n )+(x n ,Yn+1) forn0, wherex 0 =x 0 is given. Here we study the asymptotic behavior of the solutionx n as 0 andn under various assumptions on the data. General results are applied to some problems in epidemics, genetics and demographics.Supported in part by NSF Grant DMS92-06677.Supported in part by NSF Grant DMS93-12255.  相似文献   
142.
In this paper, the propagation of acoustic waves in the phononic crystal of 3D with rhombohedral(I) lattice is studied theoretically. The crystal composite constituted of nickel spheres embedded in epoxy. The calculations of the band structure and density of states are performed with the plane wave expansion method in the irreducible part of Brillouin zone. In the present work, we have investigated the effect of lattice angle on the band structure and width of the band gap rhombohedral(I) lattice in the irreducible part of the first Brillouin zone and its planes separately. The results show that more than one complete band gape are formed in the four planes of the irreducible part. The most complete band gaps are formed in the (111) plane and the widest complete band gap in (443) with an angle greater than 80 \(^{\circ }\) . So, if the sound passes through the (111) and (443) planes for the lattice angle close to 90 \(^{\circ }\) , the crystal phononic displays the excellent insulation behavior. Moreover, in the other planes, the lattice angle does not affect on the width and the number of band gaps. Also, for the filling fraction 5 %, the widest complete band gap is formed. These results are consistent with the effect of symmetry on the band gap width, because the (111) plane has the most symmetry.  相似文献   
143.
A mathematical model is developed for analysis the dynamics of an intra-cavity laser spectroscopy and mode competition using the CO2 laser as the coherent source. The governing equations of system are derived and effect of the absorbing material on the laser modes, as a time-dependent term is considered. Thus, the application of the CO2 laser for intra-cavity laser spectroscopy with considering an inhomogeneous medium and effect of the absorbing material is investigated.  相似文献   
144.
1,4-Diazabicyclo[2.2.2]octane-di-N-oxide-di-perhydrate[3pc] selectively oxidizes thiols to disulfides in acetonitrile in good yields. The method is generally useful for a wide variety of thiols.  相似文献   
145.
Abstract

A proline-based aminophosphinic acid ligand and it's vanadium complex have been synthesized and characterized by spectroscopic techniques. The inhibitory activity on pancreatic α-amylase and Baker's yeast α-glucosidase has been examined in vitro. The novel complex showed more inhibitory potency against pancreatic α-amylase and Baker's yeast α-glucosidase compared to acarbose as an antidiabetic drug.

Supplemental materials are available for this article. Go to the publisher's online edition of Phosphorus, Sulfur, and Silicon and the Related Elements to view the free supplemental file.  相似文献   
146.
H 3 PMo 12 O 40 · xH 2 O was found to be an effective catalyst for the preparation of bis-indolyl derivatives from indole and aromatic, aliphatic, heterocyclic aldehydes or ketones in ethanol at room temperature.  相似文献   
147.
Human papillomavirus (HPV) is an important pathogen which is classified into two, high- and low-risk groups. The proteins of high-risk and low-risk HPV types have different functions. Therefore, there is a need to develop a computational method for predicting these two groups. In the present study, the physiochemical properties of all early (E1, E2, E4, E5, E6, and E7) and late (L1 and L2) proteins in high- and low-risk HPV types have been studied. The concept of receiver operating characteristic analysis and support vector machines methods has been used for comparison of high- and low-risk HPV types. The results demonstrate that amino acid composition, physiochemical, and secondary structure of E2 protein are significantly different between these two groups. The results demonstrate that in silico properties can create useful information to predict high-risk and low-risk HPV types.  相似文献   
148.
In this paper, we propose a new Bi Level Fin Field Effect Transistor (BL-FinFET) where the fin regions consist of Bi level. The novel features of the BL-FinFET are simulated and compared with a Conventional FinFET (C-FinFET). The three-dimensional and two-carrier device simulation demonstrate that the application of Bi level to the FinFET structure results in an ideal threshold voltage roll-off, reduced DIBL, excellent behavior in voltage gain at high temperatures and the gate capacitance improvement when compared with the C-FinFET. Also, this paper illustrates the benefits of the high performance BL-FinFET device over the conventional one and expands the application of Silicon on Insulator Metal Oxide Semiconductor Field Effect Transistors (SOI MOSFETs) to high temperature.  相似文献   
149.
Molecular interactions in methylimidazolium tetrafluoroborate ionic liquid ([Mim+][BF4]) have been investigated using B3LYP, B3PW91 and MP2 methods with a wide range of basis sets. Binding energy, topological properties of electron density, charge transfer, nucleus-independent chemical shift (NICS) and NMR one- and two bonds spin-spin coupling constants were calculated. With five preferential binding sites in the vicinity of the Mim+ ring, five ion pairs (A-E) with three intermolecular hydrogen bonds were found on the potential energy surface. The most stable ion pairs are formed via N-H and C-H bonds of Mim+ and B-F bonds of BF4. Ion pairs have electronic binding energies (BEs) in the range of − 335.6 to − 402.9 kJ/mol at MP2/6-311++G(2d,2p) level and − 328.1 to − 383.6 kJ/mol at B3LYP/AUG-cc-pVTZ level. NBO analysis confirms that the charge transfer takes place from BF4 to Mim+. The NICS values reveal the aromaticity of imidazole ring. The results show a correlation between absolute value of 1hJ(H?F) and electron density at H?F bond critical point.  相似文献   
150.
This work reports the application of bismuth bulk electrode (BiBE) for the determination of 2‐methyl‐4,6‐dinitrophenol (MDNP) by differential pulse voltammetry (DPV) in Britton‐Robinson buffer of pH 12.0 as an optimal medium. BiBE was prepared by transferring molten bismuth into a glass tube under constant stream of nitrogen. The linear concentration dependences were measured from 1 to 10 μmol ? L?1 and from 10 to 100 μmol ? L?1 by using optimum accumulation potential of ?0.7 V and optimum accumulation time 30 s. Under these conditions limit of determination and limit of quantification was 0.45 and 1.5 μmol ? L?1, respectively. The developed method was successfully applied for the analysis of tap water as a model sample.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号