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Sulfuric acid-functionalized mesoporous benzene-silica with a molecular-scale periodicity in the walls 总被引:2,自引:0,他引:2
Novel sulfuric acid-functionalized mesoporous benzene-silicas with a molecular-scale periodicity in the walls were derived from the mesoporous benzene-silica possessing mercaptopropyl groups by the oxidative transformation of -SH into -SO3H. 相似文献
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Summary The kinetics of reduction of vanadium(V) ions by NaBH4 in aqueous acidic medium have been studied. The rate of the reaction depends upon the first powers of the concentrations of the reactants. The activation parameters were evaluated. Evidence is presented for the formation of vanadium(IV) as the reduction product. A plausible mechanism for the reduction reaction is suggested. 相似文献
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M.S. Sethi P.S. Raghavan B.S. Garg R.P. Singh Mahendra K. Gadia 《Microchemical Journal》1980,25(1):129-135
Polarography of 9,10-phenanthraquinone monoxime has been carried out in buffers (pH 3.50 to 13.40) of constant ionic strength 0.5 M in 40% alcoholic solutions at 35 ± 0.5 °C. The oxime group underwent diffusion-controlled reduction (4e) over the whole pH range studied. The number of electrons involved in the reduction was found coulometrically as well as by incorporating the value of the diffusion coefficient, obtained by using a McBain-Dawson cell, into the Ilkovic equation. Controlled potential electrolyses and uv spectroscopic methods were used to identify the products. Koutecky's method was used to compute the kinetic parameters (αnaand ?log kf,ho) for the reduction of the oxime group and reduction mechanisms are proposed. 相似文献
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Keane JM Chordia MD Mocella CJ Sabat M Trindle CO Harman WD 《Journal of the American Chemical Society》2004,126(21):6806-6815
A series of metal complexes was synthesized in which arenes were dihapto-coordinated to pi-basic metal fragments having the general form [TpM(pi-acid)(L)], where Tp = hydridotris(pyrazolyl)borate, M = rhenium, molybdenum, or tungsten, pi-acid = CO or NO(+), and L = 1-methylimidazole, 1-butylimidazole, pyridine, or trimethylphosphine. The arene complexes were shown to be significantly more basic than the analogous pentaammineosmium(II) arene complexes and were protonated by moderate acids to give remarkably stable eta(2) and eta(3) arenium cation complexes. A crystal structure of [TpRe(CO)(MeIm)(5,6-eta(2)-2H-anisolium)](OTf) confirmed the eta(2) coordination of the anisolium ligand, but suggests a weak long-range interaction between the metal and C1 of the anisolium. 相似文献