Research on Chemical Intermediates - In this research, tin oxide nanoparticles (SnO2-nanoparticles) are synthesized using sol–gel method in polymeric bed and considering the principals of... 相似文献
One-pot condensation/oxidation of aldehydes and primary anilines into nitrones using graphite oxide (GO) and Oxone as the oxidant under very mild reaction conditions is described. The proposed method provides a direct oxidative synthesis of various nitrones in good to excellent yields under metal-free conditions in short reaction times. 相似文献
Research on Chemical Intermediates - Magnetic graphene oxide (GO)/amino-functionalized Fe3O4 nanocomposite was prepared using tannic acid as binder. For this purpose, Fe3O4 nanoparticles were... 相似文献
A simple and efficient protocol has been developed for the construction of novel 6-oxo-7-aryl-6,7-dihydrochromenopyrano[2,3-b]pyridine derivatives using one-pot, three-component cyclocondensation of 4-hydroxycoumarin, various aromatic aldehydes and 2-aminoprop-1-ene-1,1,3-tricarbonitrile using 10?mol % guanidine hydrochloride as the organocatalyst under solvent-free conditions at 90?°C for the first time. The significant features of this protocol are operational simplicity, provide good to high yields, avoidance of toxic solvents, straightforward work-up, no column chromatographic purification and atom-economy which is considered to be relatively environmentally benign. 相似文献
In this work, density and viscosity have been determined for (polyethylene glycol dimethyl ether 250 + 1,2-propanediol, or 1,2-butanediol, or 1,2-pentanediol, or 1,2-hexanediol) binary systems over the whole concentration range at temperatures of (293.15, 303.15, 313.15, 323.15) K and atmospheric pressure. Experimental data of mixtures were used to calculate the excess molar volumes VE, and viscosity deviations Δη. These results were fitted by the Redlich–Kister polynomial relation to obtain the coefficients and standard deviations. 相似文献
The catalytic activity of dioxidobis{2-[(E)-p-tolyliminomethyl]phenolato}molybdenum(VI) complex was studied, for the first time, in the selective oxidation of various primary and secondary alcohols using tert-BuOOH as oxidant under organic solvent-free conditions at room temperature. The effect of different solvents was studied in the oxidation of benzyl alcohol in this catalytic system. It was found that, under organic solvent-free conditions, the catalyst oxidized various primary and secondary alcohols to their corresponding aldehyde or ketone derivatives with high yield. The effects of other parameters such as oxidant and amount of catalyst were also investigated. Among different oxidants such as H2O2, NaIO4, tert-BuOOH, and H2O2/urea, tert-BuOOH was selected as oxygen donor in the oxidation of benzyl alcohol. Also, it was found that oxidation of benzyl alcohol required 0.02 mmol catalyst for completion. Dioxomolybdenum(VI) Schiff base complex exhibited good catalytic activity in the oxidation of alcohols with tert-BuOOH under mild conditions. In this catalytic system, different primary alcohols gave the corresponding aldehydes in good yields without further oxidation to carboxylic acids. 相似文献
A new green protocol has been developed for the synthesis of 12‐aryl‐8,9,10,12‐tetrahydrobenzo[a]xanthen‐11‐ones using guanidine hydrochloride as an organocatalyst under solvent‐free conditions. Operational simplicity, mild reaction conditions, enhanced rates, high isolated yields of the pure products, and purification of products by nonchromatographic methods are significant advantages of the protocol presented here. 相似文献
It has been stated that up-down-state (UDS) cortical oscillation levels between excitatory and inhibitory neurons play a fundamental role in brain network construction. Predicting the time series behaviors of neurons in periodic and chaotic regimes can help in improving diseases, higher-order human activities, and memory consolidation. Predicting the time series is usually done by machine learning methods. In paper, the deep bidirectional long short-term memory (DBLSTM) network is employed to predict the time evolution of regular, large-scale UDS oscillations produced by a previously developed neocortical network model. In noisy time-series prediction tasks, we compared the DBLSTM performance with two other variants of deep LSTM networks: standard LSTM, LSTM projected, and gated recurrent unit (GRU) cells. We also applied the classic seasonal autoregressive integrated moving average (SARIMA) time-series prediction method as an additional baseline. The results are justified through qualitative resemblance between the bifurcation diagrams of the actual and predicted outputs and quantitative error analyses of the network performance. The results of extensive simulations showed that the DBLSTM network provides accurate short and long-term predictions in both periodic and chaotic behavioral regimes and offers robust solutions in the presence of the corruption process.
We present a novel, convenient, and efficient method for synthesizing polysubstituted 3-oxo-2,3-dihydro-5H-[1,3]thiazolo[3,2-a]pyrimidines via a three-component reaction. The zwitterions generated from the reaction of isocyanides and dialkyl acetylenedicarboxylates react with 2-imino-1,3-thiazolidin-4-one to produce the title compounds in good yields. 相似文献