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191.
A series of protic ionic salts were synthesised by a simple acid–base reaction from various pyridine derivatives and dodecylbenzenesulfonic acid in a common organic solvent and characterised in terms of their thermal and lyotropic liquid crystalline properties using various experimental techniques. All of them exhibited lyotropic liquid crystalline phases in toluene, methanol, acetonitrile, dimethyl sulfoxide and water. Their critical concentrations for the formation of biphasic solutions and concentrations for the formation of lyotropic solutions were quite broad depending on the dielectric constants of the solvents. Their lyotropic phases were identified as lamellar phases, since their textures exhibited bâtonnets, oily streaks and mosaic textures. They can potentially be used for many organic transformations, which may have implications in green chemistry. 相似文献
192.
A. P. Misra N. K. Ghosh C. Bhowmik 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2008,49(3):373-377
Existence of large amplitude stationary solitary wave structures in an unmagnetized electron-positron (e-p) plasma is studied
using a quantum hydrodynamic (QHD) model that includes the quantum force (tunnelling) associated with the Bohm potential and
the Fermi-dirac pressure law. It is found that in a quasi-neutral pair (e-p) plasma, where the dispersion is only due to the
the quantum tunnelling effects, the large amplitude stationary solitary structure exists only when the normalized Mach speed,M
<√2. Such solitary structures do not exist in absence of the Bohm potential term in an unmagnetized quasineutral pair (e-p)
plasma. The system is shown to support only rarefactive stationary solitary waves. For such waves the amplitude, being independent
of the quantum parameter H (the ratio of the electron plasmon to electron Fermi energy), decreases with the Mach number M, whereas the width increases with both M and H. The present theory is applicable to analyze the formation of localized coherent solitary structures at quantum scales in
dense astrophysical objects as well as in intense laser fields. 相似文献
193.
Surendra Barpete Priyanka Gupta Debjyoti Sen Gupta Jitendra Kumar Arpan Bhowmik Shiv Kumar 《Molecules (Basel, Switzerland)》2022,27(12)
ODAP (N-oxalyl-L-2,3-diaminopropionic acid) is present in the seeds of grass pea. In this study, variation of total ODAP accumulation in leaves throughout the crop growth starting from 40 days after sowing to maturity, and the distribution pattern of ODAP in different plant parts including the seeds at the mature stage was analyzed. Five grass pea accessions were evaluated for two subsequent growing seasons in one location of ICARDA, Aleppo (Syria). The results found that the rate of accumulation of total ODAP varied during plant development. Increased rates of synthesis were noticed in young leaves of grass pea. The highest total ODAP content in leaves was noted in the early growth stage (40–50 days after sowing). Mean total ODAP content in leaves ranged from 0.17 to 0.96 percent during 2010–2011 and from 0.19 to 1.28 percent during 2011–2012. During maturity, the total ODAP content was lowest in the seeds than in leaves, stems, pod cover, seed coat, and cotyledons. The ranges of total ODAP content were 0.13 (seed)–0.34 (stem), 0.20 (seed)–1.01 (leaf), 0.22 (seed)–0.62 (leaf), 0.21 (seed)–0.66 (leaf), and 0.21 (seed)–0.78 (leaf) percent in B387, B222, B390, Bio-520, and B587 accessions, respectively, during maturity. The results indicated that the rate of accumulation and synthesis of total ODAP varied during the plant lifespan. The lowest total ODAP content of leaves was observed after 130 days of sowing. The lower total ODAP content after the early vegetative stage of grass pea plants makes them suitable as a feed. 相似文献
194.
A Case Study on the Use of Binding Free Energies to Screen Inhibitors of Human Carbonic Anhydrase II
We present in this article a case study on the thermodynamics of binding to human carbonic anhydrase II (HCA II) by three well-known inhibitors, viz. (a) acetazolamide (AZM) that directly binds to the catalytic Zn(II) ion at the active site, (b) non-zinc binding 6-hydroxy-2-thioxocoumarin (FC5) (c) 2-[(S)-benzylsulfinyl]benzoic acid (3G1). In each case, the crystal structure or its analogue of inhibitor-bound HCA II has been used to perform classical molecular dynamics (MD) simulation in water till . AZM and FC5 are found to undergo repeated binding and unbinding with markedly different dynamics from the partially buried, substrate-binding hydrophobic pocket near the active site. 3G1, on the other hand, is found to remain mostly at its crystallographic binding site occluded from the active site of HCA II. The associated binding free energies ( ) have been computed using the known MM/GBSA method and compared to the available experimental data. Our results show that encounters several issues including limited sampling of multiple binding sites and incorrect prediction of the affinity of the chosen ligands. Possible use of the simulation results in further construction of Markov state models is also discussed. 相似文献