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We reformulate the leaky mode condition of planar Bragg waveguides as two simple, separate conditions on the propagation constant; a phase match condition and a loss formula. These relations enable efficient numerical calculations of the mode properties. Furthermore, we use the phase match condition as a starting point to discuss the dispersion of waveguides with advanced cladding structures. In particular, we point out that chirped claddings, where the effective reflection point is dependent on frequency, do not give dispersion characteristics significantly different from metallic waveguides or waveguides with periodic claddings. 相似文献
105.
The efficiency of thermoelectric power generators and the coefficient of performance of thermoelectric refrigerators increase rapidly in the region of small ZT, and then level off to a flat curve in the region of large ZT, where ZT is the figure of merit. Therefore, simply because one-dimensional thermoelectric materials have high ZT predicted theoretically does not imply that efficient thermoelectric devices can be built with such one-dimensional systems. Our numerical analysis, based on the fundamental thermodynamics which is independent of material systems, with emphasis on energy transport has confirmed this conjecture. 相似文献
106.
Ortho‐Quinone Methides as Reactive Intermediates in Asymmetric Brønsted Acid Catalyzed Cycloadditions with Unactivated Alkenes by Exclusive Activation of the Electrophile 下载免费PDF全文
MSc. Chien‐Chi Hsiao Dr. Sadiya Raja MSc. Hsuan‐Hung Liao Prof. Dr. Magnus Rueping 《Angewandte Chemie (International ed. in English)》2015,54(19):5762-5765
An efficient method for the highly enantioselective synthesis of chiral chromanes bearing multiple stereogenic centers was developed. A chiral BINOL‐based N‐triflylphosphoramide proved to be an effective catalyst for the in situ generation of ortho‐quinone methides (o‐QMs) and their subsequent cycloaddition reaction with unactivated alkenes provided chromanes with excellent diastereo‐ and enantioselectivity. 相似文献
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Nicola Bellomo Nils Calander Eugen Mamontov Magnus Willander 《Comptes Rendus Mecanique》2003,331(7):461-467
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Magnus Ekh Robert Lillbacka Kenneth Runesson 《International Journal of Plasticity》2004,20(12):2143-2159
We develop a model framework for anisotropic damage coupled to crystal (visco)plasticity, which is based on the concept of a fictitious (undamaged) configuration. The theoretical setting is that of finite strains, which is natural when studying crystal inelasticity even in the case of actual small strains. It turns out that the evolution law for damage, which reflects degradation in the slip planes and which is the key new relation, bears strong resemblance with the inelastic flow rule. Some numerical results showing qualitatively the anisotropic development of damage concludes the paper. 相似文献
110.
Eriksen JJ Olsen JM Aidas K Ågren H Mikkelsen KV Kongsted J 《Journal of computational chemistry》2011,32(13):2853-2864
In this study, we have applied two different spanning protocols for obtaining the molecular conformations of L-tryptophan in aqueous solution, namely a molecular dynamics simulation and a molecular mechanics conformational search with subsequent geometry re-optimization of the stable conformers using a quantum mechanically based method. These spanning protocols represent standard ways of obtaining a set of conformations on which NMR calculations may be performed. The results stemming from the solute-solvent configurations extracted from the MD simulation at 300 K are found to be inferior to the results stemming from the conformations extracted from the MM conformational search in terms of replicating an experimental reference as well as in achieving the correct sequence of the NMR relative chemical shifts of L-tryptophan in aqueous solution. We find this to be due to missing conformations visited during the molecular dynamics run as well as inaccuracies in geometrical parameters generated from the classical molecular dynamics simulations. 相似文献