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101.
Zheng-Jia Shen Dr. Chen Zhu Xiao Zhang Prof. Dr. Chao Yang Prof. Dr. Magnus Rueping Prof. Dr. Lin Guo Prof. Dr. Wujiong Xia 《Angewandte Chemie (International ed. in English)》2023,62(7):e202217244
(Deuterium-labeled) CF2H- and CFH2-moieties are of high interest in drug discovery. The high demand for the incorporation of these fluoroalkyl moieties into molecular structures has witnessed significant synthetic progress, particularly in the (deutero)hydrodefluorination of CF3-containing compounds. However, the controllable replacement of fluorine atoms while maintaining high chemoselectivity remains challenging. Herein, we describe the development of a selective (deutero)hydrodefluorination reaction via electrolysis. The reaction exhibits a remarkable chemoselectivity control, which is enabled by the addition of different organoboron sources. The procedure is operationally simple and scalable, and provides access in one step to high-value building blocks for application in medicinal chemistry. Furthermore, density functional theory (DFT) calculations have been carried out to investigate the reaction mechanism and to rationalize the chemoselectivity observed. 相似文献
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Rodrigues Filipe Agra Agostinho Hvattum Lars Magnus Requejo Cristina 《Journal of Heuristics》2021,27(3):459-496
Journal of Heuristics - Proximity search is an iterative method to solve complex mathematical programming problems. At each iteration, the objective function of the problem at hand is replaced by... 相似文献
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Chiral phosphoric acids and derivatives have attracted considerable attention as a powerful tool in asymmetric catalysis. Various enantioselective reactions have been developed by using these efficient Br?nsted acid organocatalysts. Although initially the activation was restricted to reactive Br?nsted basic substrates, recent reports are demonstrating the versatility of phosphoric acid catalysts in the activation of carbonyl compounds in a stereochemically controlled fashion. This tutorial review gives an overview of enantioselective Br?nsted acid catalyzed transformations with the main focus on carbonyl activation. Different activation modes, key features of the catalysts and the applied substrates are presented and discussed with the goal to elucidate the origin of stereoselectivity in these Br?nsted acid catalyzed transformations. 相似文献
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We reformulate the leaky mode condition of planar Bragg waveguides as two simple, separate conditions on the propagation constant; a phase match condition and a loss formula. These relations enable efficient numerical calculations of the mode properties. Furthermore, we use the phase match condition as a starting point to discuss the dispersion of waveguides with advanced cladding structures. In particular, we point out that chirped claddings, where the effective reflection point is dependent on frequency, do not give dispersion characteristics significantly different from metallic waveguides or waveguides with periodic claddings. 相似文献