A Remark on the Estimate of a Determinant by Minami

In the context of the Anderson model, Minami proved a Wegner type bound on the expectation of 2 × 2 determinant of Green’s functions. We generalize it so as to allow for a magnetic field, as well as to determinants of higher order.      

Herman-Wallis factor to improve thermometric accuracy of vibrational coherent anti-Stokes Raman spectra of H2

The Herman-Wallis factor is a molecular parameter that measures the influence of centrifugal force on the intensity of spectral lines. Understandably, the effect is significant for very light molecules that necessarily have large couplings between vibrational and rotational degrees of freedom. Although known, the conceptual basis of the Herman-Wallis factor are nevertheless not clearly established in the literature. Over the years, different approaches have been proposed to explain the corrections to spectral line-strengths and, recently, an experimental study has demonstrated that Q-branch Raman transitions of H₂ are highly sensitive to the theoretical model employed to determine the Herman-Wallis factor. In this paper, this fact is used to analyze the consequences on thermometry based on coherent anti-Stokes Raman scattering (CARS) designed to probe H₂ molecules in combustion studies. It is found that the different Herman-Wallis factors lead to relative thermometric disagreements from several tens up to hundreds of degrees. This analysis could explain why H₂ CARS thermometry has been considered less reliable than thermometric predictions based on CARS of more common molecules such as N₂, O₂ and others. In particular, it is remarked that unreliable expressions of Herman-Wallis factors have been used so far to interpret Q-branch H₂ CARS experiments.     

Optimization of the Hermitian and Skew-Hermitian Splitting Iteration for Saddle-Point Problems

We study the asymptotic rate of convergence of the alternating Hermitian/skew-Hermitian iteration for solving saddle-point problems arising in the discretization of elliptic partial differential equations. By a careful analysis of the iterative scheme at the continuous level we determine optimal convergence parameters for the model problem of the Poisson equation written in div-grad form. We show that the optimized convergence rate for small mesh parameter h is asymptotically 1–O(h ^1/2). Furthermore we show that when the splitting is used as a preconditioner for a Krylov method, a different optimization leading to two clusters in the spectrum gives an optimal, h-independent, convergence rate. The theoretical analysis is supported by numerical experiments.This revised version was published online in October 2005 with corrections to the Cover Date.     

Investigation of ion-selective electrodes with neutral ionophores and ionic sites by EIS. I. Theory

Models of an ion selective electrode involving an ionophore and mobile sites in a membrane are proposed. The first model, called the phase boundary potential model, supposed thermodynamic equilibrium; it allows the concentrations of the various species to be calculated. Then, a kinetic model, which takes into account the ionic transfer at the membrane|solution interfaces, was derived. The impedance of the membrane was calculated. It shows that a membrane with nernstian behavior shows only one capacitive loop in the impedance diagram, which is related to the conductivity and dielectric properties of the material of the membrane. Non-nernstian behavior is related to slow ionic transfer at the membrane|solution interfaces or/and transport limitation of the species in the membrane. Finite rate constants of the ionic transfer lead to a capacitive loop in the middle frequency range, whereas finite rate transport leads to a diffusional impedance in the low frequency range.     

Molecular weight distribution in emulsion polymerization. I. The homopolymer case

A model for evaluating the instantaneous degree of polymerization distribution of homopolymers produced in emulsion, based on the mathematics of the Markov chains, is developed. The model accounts for any number of active chains per particle, as well as for the two fundamental mechanisms of chain termination: mono- and bi-molecular, both by combination and by disproportionation. The core of the model is the so called subprocessmain process treatment, which allows us to correctly evaluate the degree of polymerization of the chains growing in the polymer particles, by distinguishing between the events experienced by the polymer chain which imply a change of its degree of polymerization (subject transitions) and those which imply only a change in the particle state (environment transitions). This is obtained by properly defining the one-step transition probability matrix of the relevant Markov process. Once this is done, the evaluation of the distribution of the degrees of polymerization reduces to a few simple operations among matrices. Explicit expressions for the instantaneous probability density functions and the relative cumulative distributions are obtained. The application of such relationships is facilitated by the numerical procedures reported in the Appendices. The results of the model developed in this work are in agreement with those of earlier models in the range of parameter values of practical interest. In the limit of very low molecular weights, only the model developed in this work provides the correct answer. Moreover, a much more significant result is its applicability to the case of emulsion copolymerization, as it is shown in Part II.     

GaSb and InAs: New Materials for Metal-Semiconductor Point-Contact Diodes

Metal-semiconductor point contact diodes have proved to be good detectors and mixers for radiation from the far-infrared to visible. Until now GaAs, InSb and InP are the most studied and used semiconductor materials for these devices. In this work we present the performance in the visible and infrared region for metal-semiconductor point-contact diodes with GaSb or InAs as the semiconductor layers. These two new materials have shown good characteristics.     

Existence and uniqueness of splittings for stationary iterative methods with applications to alternating methods

Summary. Given a nonsingular matrix , and a matrix of the same order, under certain very mild conditions, there is a unique splitting , such that . Moreover, all properties of the splitting are derived directly from the iteration matrix . These results do not hold when the matrix is singular. In this case, given a matrix and a splitting such that , there are infinitely many other splittings corresponding to the same matrices and , and different splittings can have different properties. For instance, when is nonnegative, some of these splittings can be regular splittings, while others can be only weak splittings. Analogous results hold in the symmetric positive semidefinite case. Given a singular matrix , not for all iteration matrices there is a splitting corresponding to them. Necessary and sufficient conditions for the existence of such splittings are examined. As an illustration of the theory developed, the convergence of certain alternating iterations is analyzed. Different cases where the matrix is monotone, singular, and positive (semi)definite are studied. Received September 5, 1995 / Revised version received April 3, 1996     

Lagrange approach to the optimal control of diffusions

A new approach to the optimal control of diffusion processes based on Lagrange functionals is presented. The method is conceptually and technically simpler than existing ones. A first class of functionals allows to obtain optimality conditions without any resort to stochastic calculus and functional analysis. A second class, which requires Ito's rule, allows to establish optimality in a larger class of problems. Calculations in these two methods are sometimes akin to those in minimum principles and in dynamic programming, but the thinking behind them is new. A few examples are worked out to illustrate the power and simplicity of this approach.Research performed at the Mathematisches Seminar der Universität Kiel with support provided by an Alexander von Humboldt Foundation fellowship.