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81.
Motivated by the long-standing unresolved enigma of the relaxor ferroelectric ground state, we performed a high-resolution heat capacity and polarization study of the field-induced phase transition in the relaxor ferroelectric single crystal Pb(Mg_{1/3}Nb_{2/3})O_{3} (PMN) oriented along the [110] direction. We show that the discontinuous evolution of polarization as a function of the electric field or temperature is a consequence of a true first order transition from a glassy to ferroelectric state, which is accompanied by an excess heat capacity anomaly and released latent heat. We also find that in a zero field there is no ferroelectric phase transition in bulk PMN at any temperature, indicating that the nonergodic dipolar glass phase persists down to the lowest temperatures. 相似文献
82.
Pradipta Kr. Das 《Electrophoresis》2016,37(2):347-355
Surface properties of nanoparticle are of high importance in the field of biotechnology, drug delivery and micro/nanofabrication. In this article, we developed a comprehensive theoretical model and subsequently solved that numerically to study the effect of thermodiffusion of ions on surface charge properties of nanoparticle. The theoretical study has been done considering silica nanoparticle for two aqueous solutions NaCl and KCl. The effect of solution pH in conjunction with nanoparticle temperature on surface charge density has been obtained for different salt concentrations (1, 10 and 100 mM) and nanoparticle size (diameter of 2 and 100 nm). It is observed from the results that with increasing temperature of the nanoparticle, the negative surface charge density gets higher due to increasing thermodiffusion effect. It is also found out that the magnitude of surface charge density is higher for KCl solution than NaCl solution under same condition which is attributed mostly due to less thermodiffusion of counterions for KCl than NaCl. Present study also shows that magnitude of surface charge density decreases with increasing nanoparticle size until it reaches a limiting value (called critical size) above which the effect of nanoparticle size on surface charge density is insignificant. 相似文献
83.
New process, instantaneous controlled pressure drop (DIC) was applied on Cananga odorata dry flowers with the aim to isolate essential oil. DIC is based on high temperature, short time heating followed by an abrupt pressure drop into a vacuum. A part of volatile compounds is carried away from flowers in the form of vapor (DIC direct oil) that evolves adiabatically during the pressure drop (proper isolation process) and the other part remains in the DIC-treated flowers (DIC residual oil). In the present paper, the effect of DIC cycle number (1-9) and heating time (4.3-15.7 min) on the availability of oil compounds was investigated at three levels of steam pressure (0.28, 0.4 and 0.6 MPa). The availability was defined as the amount of a compound in direct or residual oil divided by the amount of this compound in the reference oil extracted from non-treated flowers by chloroform during 2h. The total availability and yield of volatiles in the direct oil increased with pressure and cycle number. At a higher pressure, the effect of heating time was insignificant. The amount of oxygenated monoterpenes and other light oxygenated compounds (i.e. predominantly exogenous compounds) in the residual flowers was lower than in the direct oil and this amount decreased with cycle number. On the other hand, the availability of oxygenated sesquiterpenes and other heavy oxygenated compounds (i.e. predominantly endogenous compounds) in residual flowers exhibited a maximum for about five cycles and their quantity at this point was three times as much as in the direct oil. The total availability of each compound at 0.6 MPa was higher than one. The rapid DIC process (0.6 MPa, 8 cycles, 6 min) gave better results than steam distillation (16 h) concerning direct oil yield (2.8%dm versus 2.5%dm) and content of oxygenated compounds (72.5% versus 61.7%). 相似文献
84.
Barbara Marciniec M. Stawny Magdalena Hofman M. Naskrent 《Journal of Thermal Analysis and Calorimetry》2008,93(3):733-737
The study has been undertaken to check the effect of ionising radiation on the physical and chemical properties of florfenicol,
an antibiotic of a wide range of antibacterial activity. The solid-state samples were subjected to an electron beam generated
by accelerator corresponding to the doses of 25, 100 and 400 kGy, and the effect of the exposure was analysed by the methods
not requiring changes in the state (with no preliminary treatment), such as SEM, DSC, FTIR, XRD, EPR and HPLC.
Florfenicol irradiated with a dose of 25 kGy has not changed the form or colour, however, a small increase in intensity of
some absorption bands in the FTIR spectrum and of some peaks in the XRD pattern, a decrease in the melting point by 0.6°C,
the appearance of free radicals and a loss in the FF content within the error of the method (0.91%) have been observed. After
irradiation with greater doses (100 and 400 kGy) the changes have intensified, yellow discolouration appeared and the loss
of FF content has increased to 6.39%. As follows from the results, the compound studied in solid-state undergoes radiolysis
after e-beam irradiation in the doses ≥25 kGy, but lower doses (15–20 kGy) can be applied for its decontamination or sterilization
with no adverse effect on its physico-chemical properties. 相似文献
85.
We report extensive molecular dynamics simulations of (i) model ions in water at high concentrations as a function of the size and charge of the ion as well as (ii) realistic simulation of Cl- and Br- ions at low concentrations in water at room temperature. We also analyze existing experimental data in light of the results obtained here. The halide ion simulations have been carried out using the interaction potentials of Koneshan et al. (J. Phys. Chem. B 1998, 102, 4193). We compute structural and dynamical properties of ions in water and explore their variation with size and charge of the ion. We find that ions of certain intermediate sizes exhibit a maximum in self-diffusivity in agreement with previous experimental measurements and computer simulations. We analyze molecular dynamics trajectories in light of the previous understanding of the levitation effect (LE) and the recent suggestion that ionic conductivity has its origin in LE (J. Phys. Chem. B 2005, 109, 8120). We report the distribution of void and neck radii that exist amidst water. Our analysis suggests that the ion with maximum self-diffusivity is characterized by a lower activation energy and a single-exponential decay of F(s)(k,t). The behavior of these and other related quantities of the ion with maximum self-diffusivity are characteristic of the anomalous regime of the LE. The simulation results of Br- and Cl- ions in water also yield results in agreement with the predictions of LE. A plot of experimental conductivity data in the literature for alkali ions in water by Kay and Evans (J. Phys. Chem. 1966, 70, 2325) also yields a lower activation energy for the ion with maximum conductivity in excellent agreement with the LE. To the best of our knowledge, none of the existing theories predict a lower activation energy for the ion with maximum conductivity. 相似文献
86.
Summary The use of 1,2-naphthoylenebenzimidazole-6-sulphochloride has been proposed as the reagent for derivatization of aliphatic amines prior to their separation, identification and quantitation both in HPLC and in TLC. The reaction of amines with this compound is quantitative and highly fluorescent derivatives are formed that provide favourable detection limits and sensitivity as compared to Dansyl derivatives of aliphatic amines. Actual detection limits achieved correspond to ca. 10–10 mol of the amine in a spot after elution from the thin-layer plate and to ca. 5·10–14 mol of the amine in a sample volume of 10 l injected into the liquid chromatograph. The use of this derivatization reagent offers good potential for the analysis of trace amounts of amines in environmental samples and in biological material.Presented at the 14th International Symposium on Chromatography London, September, 1982 相似文献
87.
88.
Ceborska M Zimnicka M Pietrzak M Troć A Koźbiał M Lipkowski J 《Organic & biomolecular chemistry》2012,10(27):5186-5188
The formation of different complexes of folic acid depending on the size of the host cyclodextrin resulting in either an exclusion compound (with the smallest α-cyclodextrin) or 2-rotaxane, where cyclodextrin is threaded over folic acid (with β- and γ-cyclodextrins), is presented. The formation is carried out in water which allows both possible application in pharmaceutical sciences and usage of environmentally friendly "green chemistry". The obtained compounds are thoroughly characterized using one and two dimensional NMR, mass spectrometry, differential scanning calorimetry and thermogravimetric analysis. 相似文献
89.
S-nitrosylated proteins are biomarkers of oxidative damage in aging and Alzheimer's disease (AD). Here, we report a new method for detecting and quantifying nitrosylated proteins by capillary gel electrophoresis with laser induced fluorescence detection (CGE-LIF). Dylight 488 maleimide was used to specifically label thiol group (SH) after switching the S-nitrosothiol (S-NO) to SH in cysteine using the "fluorescence switch" assay. In vitro nitrosylation model-BSA subjected to S-nitrosoglutathione (GSNO) optimized the labeling reactions and characterized the response of the LIF detector. The method proves to be highly sensitive, detecting 1.3 picomolar (pM) concentration of nitrosothiols in nanograms of proteins, which is the lowest limit of detection of nitrosothiols reported to date. We further demonstrated the direct application of this method in monitoring protein nitrosylation damage in MQ mediated human colon adenocarcinoma cells. The nitrosothiol amounts in MQ treated and untreated cells are 14.8±0.2 and 10.4±0.5 pmol/mg of proteins, respectively. We also depicted nitrosylated protein electrophoretic profiles of brain cerebrum of 5-month-old AD transgenic (Tg) mice model. In Tg mice brain, 15.5±0.4 pmol of nitrosothiols/mg of proteins was quantified while wild type contained 11.7±0.3 pmol/mg proteins. The methodology is validated to quantify low levels of S-nitrosylated protein in complex protein mixtures from both physiological and pathological conditions. 相似文献
90.
This paper reviews literature information on the behaviour of semivolatile organic compounds (SVOCs) in the indoor environment,
as well as the most likely emission sources. The consecutive stages of analytical procedures used for monitoring SVOCs in
indoor environments are described. The most common approaches used for collecting samples from the gas and particulate phases
are mentioned. The paper discusses and compares various types of sorbents and filters applied in dynamic, passive and denudational
techniques, as well as the techniques used to liberate the SVOCs, including Soxhlet, sonication and microwave extraction.
The main advantages and disadvantages of each technique are discussed, together with possible future trends. The approaches
commonly used during the final determination step, such as gas chromatography and liquid chromatography, are presented together
with their possible drawbacks, and ways of eliminating them are suggested. The review makes brief reference to the effects
of human exposure to SVOCs in house dust and discusses the main aspects of the analytical procedures used to monitor the presence
of SVOCs in this medium. 相似文献