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11.
Ranjit Bag Sourav Kar Suvam Saha Suman Gomosta Beesam Raghavendra Thierry Roisnel Sundargopal Ghosh 《化学:亚洲杂志》2020,15(6):780-786
Triply‐bridging bis‐{hydrido(borylene)} and bis‐borylene species of groups 6, 8 and 9 transition metals are reported. Mild thermolysis of [Fe2(CO)9] with an in situ produced intermediate, generated from the low‐temperature reaction of [Cp*WCl4] (Cp*=η5‐C5Me5) and [LiBH4?THF] afforded triply‐bridging bis‐{hydrido(borylene)}, [(μ3‐BH)2H2{Cp*W(CO)2}2{Fe(CO)2}] ( 1 ) and bis‐borylene, [(μ3‐BH)2{Cp*W(CO)2}2{Fe(CO)3}] ( 2 ). The chemical bonding analyses of 1 show that the B?H interactions in bis‐{hydrido (borylene)} species is stronger as compared to the M?H ones. Frontier molecular orbital analysis shows a significantly larger energy gap between the HOMO‐LUMO for 2 as compared to 1 . In an attempt to synthesize the ruthenium analogue of 1 , a similar reaction has been performed with [Ru3(CO)12]. Although we failed to get the bis‐{hydrido(borylene)} species, the reaction afforded triply‐bridging bis‐borylene species [(μ3‐BH)2{WCp*(CO)2}2{Ru(CO)3}] ( 2′ ), an analogue of 2 . In search for the isolation of bridging bis‐borylene species of Rh, we have treated [Co2(CO)8] with nido‐[(RhCp*)2(B3H7)], which afforded triply‐bridging bis‐borylene species [(μ3‐BH)2(RhCp*)2Co2(CO)4(μ‐CO)] ( 3 ). All the compounds have been characterized by means of single‐crystal X‐ray diffraction study; 1H, 11B, 13C NMR spectroscopy; IR spectroscopy and mass spectrometry. 相似文献
12.
Determination of pharmaceuticals, iodinated contrast media and musk fragrances in sludge by LC/tandem MS and GC/MS 总被引:1,自引:0,他引:1
Ternes TA Bonerz M Herrmann N Löffler D Keller E Lacida BB Alder AC 《Journal of chromatography. A》2005,1067(1-2):213-223
Analytical methods have been developed that allow for the determination of antiphlogistics, lipid regulators, the antiepileptic carbamazepine, cytostatic agents, the psychiatric drug diazepam and iodinated contrast media (ICM) as well as two major polycyclic musk fragrances HHCB (galaxolide) and AHTN (tonalide) in activated and digested sludge. The procedures consist of ultrasonic solvent extraction (USE) using methanol/acetone or pressurized liquid extraction (PLE) using 100% methanol. Clean-up was performed with C18ec material and silica gel followed by LC tandem MS (electrospray or atmospheric pressure chemical ionization) detection for pharmaceuticals and iodinated contrast media as well as GC/MS in the SIM mode for musk fragrances. Absolute recoveries from spiked activated sludge in general ranged from 88+/-4 to 119+/-20% for ICM and were 78+/-15 and 87+/-10% for the AHTN and HHCB, respectively. For the pharmaceuticals, absolute recoveries in activated sludge ranged between 43 and 78%. Subsequently, compensation of losses was carried out by using surrogate standards (acidic pharmaceuticals: fenoprop, neutral pharmaceuticals: dihydro-carbamazepine, musk fragrances: AHTN-D3). With one exception the recoveries were also adequate in digested sludge ranging from 43% to 120%. 相似文献
13.
When contributors to a common cause (or public good) are uncertain about each others’ valuations, early contributors are likely
to be cautious in free-riding on future contributors. Contrary to the case of complete information, when contributors have
independent private valuations for the public good, the expected total contribution generated in a sequential move game may
be higher than in a simultaneous move game. This is established in a conventional framework with quasi-linear utility where
agents care only about the total provision of the public good (rather than individual contribution levels) and there is no
non-convexity in the provision of the public good. We allow for arbitrary number of agents and fairly general distribution
of types. 相似文献
14.
Redox-controlled covalent templating and macrocyclization underlie a novel scheme for stepwise exponential self-replication. This process has been demonstrated by using Tr?ger's base analogue 1 as the template. 相似文献
15.
Novel enediynyl amino acids and peptides 3 and 5-8 were synthesized and their thermal reactivity towards Bergman cyclization studied and compared with the earlier reported amino acid 4, which demonstrated, for the first time, the effect of H-bonding and electrostatic interactions in lowering the activation energy of Bergman cyclization. 相似文献
16.
P. Majee G. Goswami M. K. Sen B. C. Bag 《The European Physical Journal B - Condensed Matter and Complex Systems》2009,72(3):435-439
In this paper we have studied the directed motion of a Brownian particle
in a multiplicative noise
driven flashing ratchet system. Our investigation shows
the current (j) is either maximum or minimum
in the super-diffusion (SPD) region depending on the asymmetric character of the ratchet potential.
But the optimum behavior disappears for the symmetric
ratchet potential and there is a current inversion around the normal diffusion (ND). With increase of
half cycle period(tp/2) (which controls the on-off operation
mechanism of the potential), j
passes through a maximum and the peak height is the highest for the SPD. Also
at low asymmetry in the system, the mobility is more dominating for
the normal and the super-diffusion cases than the sub-diffusion.
For large asymmetry in the ratchet potential,
the diffusion control positive current
is larger for the ND compared to the other cases.
Finally, we observe that there is a maximum in the variation of current as a function of noise correlation time for
SPD. But it disappears for the other cases. 相似文献
17.
Dibyendu S. Bag Dhiraj Dutta T. C. Shami K. U. Bhasker Rao 《Journal of polymer science. Part A, Polymer chemistry》2009,47(9):2228-2242
A chiral monomer containing L ‐leucine as a pendant group was synthesized from methacryloyl chloride and L ‐leucine in presence of sodium hydroxide at 4 °C. The monomer was polymerized by free radical polymerization in propan‐2‐ol at 60 °C using 2,2′‐azobis isobutyronitrile (AIBN) as an initiator under nitrogen atmosphere. The polymer, poly(2‐(Methacryloyloxyamino)‐4‐methyl pentanoic acid) is thus obtained. The molecular weight of the polymer was determined to be: Mw is 6.9 × 103 and Mn is 5.6 × 103. The optical rotation of both chiral monomer and its polymer varies with the solvent polarity. The amplification of optical rotation due to transformation of monomer to polymer is associated with the ordered conformation of chiral monomer unit in the polymeric chain due to some secondary interactions like H‐bonding. The synthesized monomer and polymer exhibit intense Cotton effect at 220 nm. The conformation of the chain segments is sensitive to external stimuli, particularly the pH of the medium. In alkaline medium, the ordered chain conformation is destroyed resulting disordered random coils. The ordered coiling conformation is more firmly present on addition of HCl. The polymer exhibits swelling‐deswelling characteristics with the change of pH of the medium, which is reversible. The Cotton effect decreases linearly with the increase of temperature which is reversible on cooling. © 2009 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 47: 2228–2242, 2009 相似文献
18.
We consider a weakly dissipative quasilinear system of PDEs, governingthe unsteady one-dimensional motion of a relaxing gas, and investigatethe effects ofhigher order terms and the source term, present in the differentialsystem, on the wave motion associated with it. The undisturbed stateof the medium, which is assumed to be uniform and at restadmits mixed nonlinearity, i.e., the quadratic nonlinearity parameter inherent in the system changes sign depending on the basestate. The method of multiple scales is employed to determine theevolution equation governing small perturbations to the state where is of O(), and the effects of nonlinearity arenoticeable over times of order O(–2). 相似文献
19.
Ionization of aliphatic and aromatic aldehydes is improved by performing simultaneous chemical derivatization using 4-aminophenol to produce charged iminium ions during paper spray ionization. Accelerated reactions occur in the microdroplets generated during the paper spray ionization event for the tested aldehydes (formaldehyde, n-pentanaldehyde, n-nonanaldehyde, n-decanaldehyde, n-dodecanaldehyde, benzaldehyde, m-anisaldehyde, and p-hydroxybenzaldehyde). Tandem mass spectrometric analysis of the iminium ions using collision-induced dissociation demonstrated that straight chain aldehydes give a characteristic fragment at m/z 122 (shown to correspond to protonated 4-(methyleneamino)phenol), while the aromatic aldehyde iminium ions fragment to give a characteristic product ion at m/z 120. These features allow straightforward identification of linear and aromatic aldehydes. Quantitative analysis of n-nonaldehyde using a benchtop mass spectrometer demonstrated a linear response over 3 orders of magnitude from 2.5 ng to 5 μg of aldehyde loaded on the filter paper emitter. The limit of detection was determined to be 2.2 ng for this aldehyde. The method had a precision of 22%, relative standard deviation. The experiment was also implemented using a portable ion trap mass spectrometer. 相似文献
20.
Amphiphilic graft copolymers consisting of poly(vinyl chloride)(PVC) main chains and poly(4-vinyl pyridine)(P4VP) side chains were synthesized via atom transfer radical polymerization(ATRP) using direct initiation of chlorine atoms. The successful synthesis of PVC-g-P4 VP graft copolymers was confirmed by Fourier transform infrared spectroscopy(FTIR) and proton nuclear magnetic resonance(1H-NMR). Transmission electron microscope(TEM) and small angle X-ray scattering(SAXS) analysis showed that PVC-g-P4 VP exhibited microphase-separated, ordered structure with 37.6 nm of domain spacing, which was not observed in neat PVC. For antibacterial applications, the tertiary nitrogen atoms of PVC-gP4 VP was quaternized using 1-bromohexane, as confirmed by FTIR measurements. Bacteria including Escherichia coli(E. coli), Staphylococcus aureus(S. aureus), Bacillus cereus(B. cereus), and Pseudomonas aeruginosa(P. aeruginosa) were completely killed in 24 h on the quaternized PVC-g-P4VP(46% grafting) surface, indicating its excellent antibacterial behavior while it showed to be cytotoxic to mammalian cell. 相似文献