Synthesis and Characterization of A Novel Cholesteric Liquid Crystalline Containing Carboxyl Group

A novel liquid crystal compound with a carboxyl group at one end, cholest-5-en-3-ol-(3β) hydrogen decanedioate (1) was successfuly prepared by the reaction of cholesterol with sebacoxl chloride. Its chemical structure and liquid crystalline properties were characterized by FTIR.CNMR,HNMR,POM and DSC. The compound with an active carboxyl group shows themortropic liquid crystalline behaviour.     

氟代糖的合成

本文综述了氟代糖合成的新进展及利用选择性氟化合成具有生物活性的物质。     

Ce~(3+)在YGG中的光谱性质

本文首次报导并讨论Y_3Ga_5O_(12)石榴石中Ce~(3+)离子的漫反射吸收光谱,激发光谱及荧光性质。发现无论在紫外辐射,可见蓝光或电子束激发下,Ce~(3+)激活的YGG均呈现Ce~(3+)的5d-4f充许跃迁吸收和荧光性质。从440nm扩展到680nm附近的宽发射带是由于Ce~(3+)的最低的5d态跃迁到2FJ(J=5/2和7/2)终态结果。和YAG:Ce石榴石相比,YGG中Ce~(3+)的吸收带和发射带的位置向短波移动。     

难度系数评分法

本文运用概率统计的理论导出难度系数的计算公式 :D (x) =0 .1Φ- 1(x* ) + 0 .5,进而给出以此公式的计分公式 T =aΦ- 1(x* ) + b,此公式可广泛用于各种综合评价的场合     

酶促合成棕榈酸维生素C酯及其光谱表征

本文用棕榈酸甲酯和维生素C，以脂肪酶（LIPOZYM IM）为催化剂，合成了棕榈酸维生素C酯，酯的一次收率达68.2%。通过红外光谱对产物进行了结构分析。     

基于随机波动模型的沪深股市波动分析——以06,07年度沪深股指为例

基于马尔科夫链蒙特卡罗(MCMC)模拟的贝叶斯(Bayes)分析方法,应用随机波动(SV)模型实证分析06、07年度中国股票市场指数的波动性,并对比沪市与深市的股指,对不同形式的SV模型的参数进行估计,对结论作出合理的解释.     

One Step to Generate Cluster States Using Dipole-Induced Transparency in a Cavity-Waveguide System

We present a very simple scheme for generating four-qubit cluster states with one step using parity measurement based on dipole-induced transparency in a cavity-waveguide system. The scheme only uses the photon detectors to check the parity of the spatially separated dipole, which are the same （even parity） or different （odd parity） through measuring the light fields in the waveguide. The initial entangled states remain after nondetective identification and they can be used for successive tasks.     

求解非线性方程组的L-M方法

本文研究了求解奇异非线性方程组的Levenberg-Marquardt方法的收敛性.利用选取新的迭代参数求解非线性方程组的L-M方法,获得点列的超线性收敛性和二阶收敛性,并把试验结果与文献[19,20]的结果进行了比较.     

STUDIES ON RESPONSE CHARACTERISTICS OF DRUG ISE''''S (Ⅳ) SELECTIVITY OF, DRUG ISE''''S WITH HETERO-POLY ACID ANION SITE TOWARD METAL IONS

The relationship between the selectivity of six drug ion-selective electrodes with anionic species of hetero-poly acid as exchange site and the structural and thermodynamical parameters of the metal ion has been investigated experimentally and theoretically. The electrode selectivity is controlled mainly by the extractibility or hydrophobicity of the metal ion, but not by the ion-association-complex formation process. Linear relationship exists between the pK_(ij) value and the structural parameter z~2/(r + 0.85) and the thermodynamic parameter of hydration (△G_h) of the metal ion. Better correlation is obtained for the pK_(ij)vs. (z~2/r)~(-k) relationship.