Epoxy resins cured with ionic liquids as novel supports for metal complex catalysts

In this work, the application of an epoxy resin cured with ammonium ionic liquids as a support for palladium complex catalyst is reported. Supports based on epoxy resin were obtained as a result of the use of ionic liquids: didecyldimethylammonium tetrafluoroborate [d₂m₂am][BF₄], 1-methyltheobromine tetrafluoroborate [mthb][BF₄], didecyldimethylammonium theobrominate [d₂m₂am][thb], didecyldimethylammonium theophyllinate [d₂m₂am][thp] as cross-linking agents. The characterization of polymeric supports and heterogenized palladium catalysts has involved research methods like time-of-flight secondary ion mass spectrometry (TOF-SIMS), infrared spectroscopy (IR), scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS). The activity and stability during long-term use of the investigated catalytic systems were tested in a model Heck reaction. The influence of the type of ILs used as epoxy hardeners on the catalytic properties of epoxy-supported palladium catalysts is discussed.     

Aggregation in dispersions of hematite and of hematite-akageneite composite containing anionic surfactants

The aggregation in dispersions of iron oxides was studied by dynamic light scattering and by TEM. In spite of high absolute value of zeta potential induced by specific adsorption of alkyl (C12–C16) sulfates, the particles showed substantial degree of aggregation. The particle size distributions observed in SDS-stabilized dispersions by dynamic light scattering were sensitive to the impurities contained in reagent-grade SDS. Namely, different specimens of reagent-grade SDS produced very different particle size distributions at otherwise identical experimental conditions.     

Interactions of 10.6 GeV/nucleon gold nuclei in nuclear emulsion

Stacks of nuclear emulsion were exposed at the Brookhaven AGS to a 10.6 GeV/n beam of gold nuclei in the BNL 868 experiment. A preliminary analysis of the main features of the interactions of these nuclei is reported here and compared with those observed previously at lower energies,E<1 GeV/n. The multiplicity and pseudo-rapidity distributions of the singly charged particles emitted both in central and in minimum bias samples of interactions have been analyzed in order to look for any non random effects indicative of the nuclear state during the interactions. The fragmentation characteristics of the gold projectiles appear to be different at 10.6 GeV/n from those at ≦1 GeV/n incident energy. Fission of the gold projectiles, which was relatively frequent at low energy, is almost entirely suppressed. Some of alpha particles from the projectile are emitted with very large transverse momenta. In gold-emulsion interactions the residual target nuclei are significantly smaller than in oxygen and sulfur interactions in emulsion.

     

Functional properties of quantum logics

A quantum logic is defined as a setL of functions from the set of all statesS into [0, 1] satisfying the orthogonality postulate: for any sequencea ₁,a ₂, ... of members ofL satisfyinga _i+a _j≤1 fori≠j there isb∈L such thatb+a ₁+a ₂+...=1. Every logicL is in a natural way an orthomodular σ-orthocomplemented partially ordered set (L, ≤, ′) with members ofS inducing a full set of measures onL. It is shown that a logicL is quite full if and only if (L,≤,′) is isomorphic to an orthocomplemented set lattice of subsets ofS. Sufficient conditions are given in order that a quite full logic be representable in the set of projection quadratic formsf(u)=(Pu, u) on a complex Hilbert space, or in the set of trace functionsf(A)=Trace (AP) generated by projectionsP, where the domain off is the set of non-negative self-adjoint trace operators of trace 1 in a complex Hilbert space.     

Adsorbed states of substituted α‐aminophosphinic acids on a silver electrode surface: comparison with a colloidal silver substrate

We investigated the interfacial structures of various aromatic (each compound contains one or two phenyls) di‐α‐amino ( L¹ – L³ ) and α‐amino‐α‐hydroxyphosphinic ( L⁴ – L⁶ ) acids immobilized onto an electrochemically roughened silver electrode surface in an aqueous solution using surface‐enhanced Raman scattering (SERS). These structures were compared to those on a colloidal silver surface to determine the relationship between adsorption strength and geometry. The presence of an enhanced ν_19a ring band in the SERS spectra of L⁶ , L² , and L³ on the electrode indicated that the benzene rings of those molecules interact with the electrode surface through localized CC bond(s). We observed significant band broadening of the benzene ring modes for all α‐hydroxyphosphinic acids on both substrates, except for L¹ deposited onto the electrode surface. This suggests the possibility of direct interaction between the ring and Ag, although the benzene ring–surface π overlap is weaker for the colloidal silver than for the Ag electrode. The downward shift in wavenumber and alternations in the enhancement of a ν₁₂ ring band indicate a general increase of tilt angle on both silver substrates in the order L³ < L⁴ < L⁵ < L⁶ . The altered enhancement of the bands due to the vibrations of the  NH₂ and O PO fragments, a finding observed on both silver substrates, strongly suggests that the groups interact with different strength and geometry with these substrates. Copyright © 2009 John Wiley & Sons, Ltd.     

Non-triviality conditions for integer-valued polynomial rings on algebras

Let D be a commutative domain with field of fractions K and let A be a torsion-free D-algebra such that \(A \cap K = D\). The ring of integer-valued polynomials on A with coefficients in K is \( Int _K(A) = \{f \in K[X] \mid f(A) \subseteq A\}\), which generalizes the classic ring \( Int (D) = \{f \in K[X] \mid f(D) \subseteq D\}\) of integer-valued polynomials on D. The condition on \(A \cap K\) implies that \(D[X] \subseteq Int _K(A) \subseteq Int (D)\), and we say that \( Int _K(A)\) is nontrivial if \( Int _K(A) \ne D[X]\). For any integral domain D, we prove that if A is finitely generated as a D-module, then \( Int _K(A)\) is nontrivial if and only if \( Int (D)\) is nontrivial. When A is not necessarily finitely generated but D is Dedekind, we provide necessary and sufficient conditions for \( Int _K(A)\) to be nontrivial. These conditions also allow us to prove that, for D Dedekind, the domain \( Int _K(A)\) has Krull dimension 2.     

Heat capacity of MnAs0.88P0.12 from 10 to 500 K: Thermodynamic properties and transitions

The heat capacity of MnAs_0.88P_0.12 has been measured by adiabatic shield calorimetry from 10 to 500 K. It is shown that very small energy changes are connected with two magnetic order-order transitions, indicating that these can be regarded as mainly “noncoupled” magnetic transitions. At higher temperatures contributions to the excess heat capacity arises from a magnetic order-disorder transition, a conversion from low- to high-spin state for manganese, and a MnP- to NiAs-type structural transition. The observed heat capacity is resolved into contributions from the different physical phenomena, and the character of the transitions is discussed. In particular it is substantiated that the dilational contribution, which includes magnetoelastic and magnetovolume terms as well as normal anharmonicity terms, plays a major role in MnAs_0.88P_0.12. The entropy of the magnetic order-disorder transition is smaller than should be expected from a complete randomization of the spins, assuming a purely magnetic transition. Thermodynamic functions have been evaluated and the respective values of C_p, {S^O_m(T) - S^O_m(0)}, and -{G^O_m(T) - H^O_m(0)}/T at 298.15 K are 68.74, 72.09, and 32.30 J K⁻¹ mole⁻¹, and at 500 K 56.05, 108.12, and 56.64 J K⁻¹ mole⁻¹.     

Development of the HPLC Method for Simultaneous Determination of Lidocaine Hydrochloride and Tribenoside Along with Their Impurities Supported by the QSRR Approach

A new liquid chromatographic (LC) method for simultaneous determination of lidocaine hydrochloride (LH) and tribenoside (TR) along with their related compounds in pharmaceutical preparations is described. Satisfactory LC separation of all analytes after the liquid–liquid extraction (LLE) procedure with ethanol was performed on a C₁₈ column using a gradient elution of a mixture of acetonitrile and 0.1 % orthophosphoric acid as the mobile phase. The procedure was validated according to the ICH guidelines. The limits of detection (LOD) and quantification (LOQ) were 4.36 and 13.21 μg mL^?1 for LH, 7.60 and 23.04 μg mL^?1 for TR, and below 0.11 and 0.33 μg mL^?1 for their impurities, respectively. Intra- and inter-day precision was below 1.97 %, whereas accuracy for all analytes ranged from 98.17 to 101.94 %. The proposed method was sensitive, robust, and specific allowing reliable simultaneous quantification of all mentioned compounds. Moreover, a comparative study of the RP-LC column classification based on the quantitative structure-retention relationships (QSRR) and column selectivity obtained in real pharmaceutical analysis was innovatively applied using factor analysis (FA). In the column performance test, the analysis of LH and TR in the presence of their impurities was carried out according to the developed method with the use of 12 RP-LC stationary phases previously tested under the QSRR conditions. The obtained results confirmed that the classes of the stationary phases selected in accordance with the QSRR models provided comparable separation for LH, TR, and their impurities. Hence, it was concluded that the proposed QSRR approach could be considered a supportive tool in the selection of the suitable column for the pharmaceutical analysis.     

Improved Protocol for Mononitration of Phenols with Bismuth(III) and Iron(III) Nitrates

A simple and efficient multigram procedure was developed for the selective mononitration of various activated phenols. The reaction proceeded smoothly with 0.5 equivalents of Bi(NO₃)₃ · 5H₂O or Fe(NO₃)₃ · 9H₂O in acetone at ambient temperature or at reflux. The desired products were isolated in 62–93% total yield and essentially no overnitrated compounds were detected.