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101.
102.
Maas FE Achenbach P Aulenbacher K Baunack S Capozza L Diefenbach J Grimm K Imai Y Hammel T von Harrach D Kabuss EM Kothe R Lee JH Lorente A Lopes Ginja A Nungesser L Schilling E Stephan G Weinrich C Altarev I Arvieux J Collin B Frascaria R Guidal M Kunne R Marchand D Morlet M Ong S van de Wiele J Kowalski S Plaster B Suleiman R Taylor S 《Physical review letters》2004,93(2):022002
We report on a measurement of the parity-violating asymmetry in the scattering of longitudinally polarized electrons on unpolarized protons at a Q2 of 0.230 (GeV/c)(2) and a scattering angle of theta (e) = 30 degrees - 40 degrees. Using a large acceptance fast PbF2 calorimeter with a solid angle of delta omega = 0.62 sr, the A4 experiment is the first parity violation experiment to count individual scattering events. The measured asymmetry is A(phys)=(-5.44+/-0.54(stat)+/-0.26(sys))x10(-6). The standard model expectation assuming no strangeness contributions to the vector form factors is A(0) = (-6.30+/-0.43) x 10(-6). The difference is a direct measurement of the strangeness contribution to the vector form factors of the proton. The extracted value is G(s)(E) + 0.225G(s)(M) = 0.039+/-0.034 or F(s)(1) + 0.130F(s)(2) = 0.032+/-0.028. 相似文献
103.
104.
Propyne iminium triflates R1C(N+R3R4)CCR2 CF3SO readily react with Ph3PNPh to form 1:1 adducts which formally result from a metathetical addition of the phosphorane imine across the triple bond of the alkyne. These adducts are best described as enamino‐phosphonium salts or iminio‐substituted phosphorus ylides. The configuration of these salts has been determined from NMR data and an X‐ray crystal structure analysis of salt 3h . The base‐induced elimination of the PPh3 substituent from enamino‐phosphonium salt 3a was studied. © 2005 Wiley Periodicals, Inc. Heteroatom Chem 16:437–446, 2005; Published online in Wiley InterScience ( www.interscience.wiley.com ). DOI 10.1002/hc.20131 相似文献
105.
106.
K. D. Mooiman R. F. Maas‐Bakker H. Rosing J. H. Beijnen J. H. M. Schellens I. Meijerman 《Biomedical chromatography : BMC》2013,27(9):1107-1116
Complementary and alternative medicines (CAM) can affect the pharmacokinetics of anticancer drugs by interacting with the metabolizing enzyme cytochrome P450 (CYP) 3A4. To evaluate changes in the activity of CYP3A4 in patients, levels of 1‐hydroxymidazolam in plasma are often determined with liquid chromatography–quadrupole mass spectrometry (LC‐MS/MS). However, validated LC‐MS/MS methods to determine in vitro CYP3A4 inhibition in human liver microsomes are scarce and not optimized for evaluating CYP3A4 inhibition by CAM. The latter is necessary because CAM are often complex mixtures of numerous compounds that can interfere with the selective measurement of 1‐hydroxymidazolam. Therefore, the aim was to validate and optimize an LC‐MS/MS method for the adequate determination of CYP3A4 inhibition by CAM in human liver microsomes. After incubation of human liver microsomes with midazolam, liquid–liquid extraction with tert‐butyl methyl ether was applied and dried samples were reconstituted in 50% methanol. These samples were injected onto a reversed‐phase chromatography consisting of a Zorbax Extend‐C18 column (2.1 × 150 mm, 5.0 µm particle size), connected to a triple quadrupole mass spectrometer with electrospray ionization. The described LC‐MS/MS method was validated over linear range of 1.0–500 nm for 1‐hydroxymidazolam. The results revealed good inter‐assay accuracy (≥85% and ≤115%) and within‐day and between‐day precisions (coefficient of variation ≤ 4.43%). Furthermore, the applicability of this assay for the determination of CYP3A4 inhibition in complex matrix mixtures was successfully demonstrated in an in vitro experiment in which CYP3A4 inhibition by known CAM (β‐carotene, green tea, milk thistle and St. John's wort) was determined. Copyright © 2013 John Wiley & Sons, Ltd. 相似文献
107.
Chunkan Yu Paola Breda Michael Pfitzner Ulrich Maas 《Proceedings of the Combustion Institute》2021,38(2):2645-2653
For general reacting flows the numerical simulation faces two main challenges. One is the high dimensionality and stiffness of the governing conservation equations due to detailed chemistry, which can be solved by using simplified chemical kinetics. The other one is the difficulty of modeling the coupling of turbulence with thermo-chemical source term. The probability density function (PDF) method allows to calculate turbulent reacting flows by solving the thermal-chemical source term in closed form. Usually, the PDF method for turbulent processes such as mixing processes and the reduction method for chemical kinetics are developed separately. However, coupling of both processes plays an important role for the numerical accuracy. To investigate the importance of coupling between turbulence and simplified chemistry, two different coupling strategies for mixing and reduced chemistry are discussed and tested for the well-known Sandia Flames E and F, in which there is a strong interaction between turbulence and chemical kinetics. The EMST mixing model is chosen for turbulent mixing, while the Reaction-Diffusion Manifolds (REDIMs) is used as simplified chemistry. However, the proposed strategies are also valid for other mixing models and manifold based simplified chemistry. 相似文献
108.
The properties of elementary particles are encoded in their respective propagators and interaction vertices. For a SU(2) gauge
theory coupled to a doublet of fundamental complex scalars these propagators are determined in both the Higgs phase and the
confinement phase and compared to the Yang–Mills case, using lattice gauge theory. Since the propagators are gauge dependent,
this is done in the Landau limit of the ’t Hooft gauge, permitting to also determine the ghost propagator. It is found that
neither the gauge boson nor the scalar differ qualitatively in the different cases. In particular, the gauge boson acquires
a screening mass, and the scalar’s screening mass is larger than the renormalized mass. Only the ghost propagator shows a
significant change. Furthermore, indications are found that the consequences of the residual non-perturbative gauge freedom
due to Gribov copies could be different in the confinement and the Higgs phase. 相似文献
109.
We prove a Trotter product formula for gradient flows in metric spaces. This result is applied to establish convergence in the L 2-Wasserstein metric of the splitting method for some Fokker-Planck equations and porous medium type equations perturbed by a potential. 相似文献
110.
Bis(N,N,N′,N′-tetraalkyl)formamidinium ethers, readily prepared from a N,N,N′,N′-tetraalkyl urea and triflic anhydride, yield push-pull olefins with activated methylene compounds H2CXY, where X, Y are CN, COOR, C6H4-4-NO2. 相似文献