The structural and magnetic properties of barium ferrite powders prepared by the solben gel method

In this paper, M-type hexagonal barium ferrite powders are synthesized using the sol-gel method. A dried precursor heated in air is analyzed in the temperature range from 50 to 1200 ℃ using thermo-gravimetric analysis and differential scanning calorimetry. The effects of the additives and the cacinating temperature on the magnetic properties are investigated, and the results show that single-phase barium ferrite powders can be formed. After heat-treating at 950 ℃ for 4h with 3 wt% additive, the coercivity and saturation magnetization are found to be 440 Oe and 57.9 emu/g, respectively.     

Growth of gem-grade nitrogen-doped diamond crystals heavily doped with the addition of Ba（N3）2

Additive Ba(N 3) 2 as a source of nitrogen is heavily doped into the graphite-Fe-based alloy system to grow nitrogendoped diamond crystals under a relatively high pressure (about 6.0 GPa) by employing the temperature gradient method.Gem-grade diamond crystal with a size of around 5 mm and a nitrogen concentration of about 1173 ppm is successfully synthesised for the first time under high pressure and high temperature in a China-type cubic anvil highpressure apparatus.The growth habit of diamond crystal under the environment with high degree of nitrogen doping is investigated.It is found that the morphologies of heavily nitrogen-doped diamond crystals are all of octahedral shape dominated by {111} facets.The effects of temperature and duration on nitrogen concentration and form are explored by infrared absorption spectra.The results indicate that nitrogen impurity is present in diamond predominantly in the dispersed form accompanied by aggregated form,and the aggregated nitrogen concentration in diamond increases with temperature and duration.In addition,it is indicated that nitrogen donors are more easily incorporated into growing crystals at higher temperature.Strains in nitrogen-doped diamond crystal are characterized by micro-Raman spectroscopy.Measurement results demonstrate that the undoped diamond crystals exhibit the compressive stress,whereas diamond crystals heavily doped with the addition of Ba(N 3) 2 display the tensile stress.     

单轴〈111〉应力硅价带结构计算

基于k·p微扰法计算了单轴〈111〉应力作用下硅的价带结构, 并与未受应力时体硅的价带结构进行了比较. 给出了单轴〈111〉应力作用下硅价带顶处能级的移动、分裂以及空穴有效质量的变化情况. 计算所得未受应力作用时硅价带顶处重空穴带、轻空穴带有效质量与相关文献报道体硅有效质量结果一致. 拓展了单轴应力硅器件导电沟道应力与晶向的选择范围,给出的硅价带顶处重空穴带、轻空穴带能级间的分裂值和有效质量随应力的变化关系可为单轴〈111〉应力硅其他物理参数的计算提供参考. 关键词： 单轴应力硅 k·p法')" href="#">k·p法 价带结构     

Cr4+掺杂Li1.14Zn1.43SiO4透明微晶玻璃近红外宽带光谱特性

采用高温熔融法和热处理制备了Cr⁴⁺掺杂Li_1.14Zn_1.43SiO₄微晶玻璃, 探讨了不同热处理温度下样品的物相、微观形貌及发光性能. 结果表明: 580℃热处理2h得到的微晶玻璃, Li_1.14Zn_1.43SiO₄微晶的粒径约为5nm, 在808nm的二极管激发下, 可观察到中心波长位于1226nm, 半高宽为230nm的近红外宽带发射峰, 荧光寿命约为200.73±1.71μs. 随着热处理温度的升高, Cr⁴⁺离子所处的晶体场环境发生了变化, 且可以观察到样品吸收光谱发生微弱的蓝移, 而荧光光谱发生少量的红移, 分析了晶体场环境变化对样品发光性能的影响. 关键词： 铬离子 微晶玻璃 超宽带发光 晶体场     

关于具有多项式约束的I-环

In this paper, it is shown that an l-prime lattice-ordered ring in which the square of every element is positive must be a domain provided it has non-zero f-elements and be an l-domain provided it has a left (right) identity ele-ment or a central idempotent element .More generally,the same conclusion follows if the condition a²≥0 is replaced by p(a)≥0 or f(a,b)≥0 for suitable polyno-mials p(x) and f(x, y) . It is also shown that an l-algebra is an f-algebra provided it is archimedean, contains an f-element e>0 with r₁(e)=0, and satifies a polynomial identity p(x)≥0 or f(x,y)≥0 (for suitable f(x,y)).     

利用啁啾脉冲光谱滤波和非线性偏振旋转技术实现高稳定性和开机自启动的全光纤掺Yb~(3+)光纤锁模激光器

建立理论模型,讨论了非线性偏振旋转全光纤锁模激光器的锁模过程、谐波过程以及导致激光器锁模运行难以稳定的影响因素.讨论了采用啁啾脉冲光谱滤波产生脉冲自振幅调制、增加激光器锁模稳定性和自启动能力的机理以及非线性偏振旋转与啁啾脉冲光谱滤波相结合实现锁模的物理过程和脉冲演化过程.研制出全光纤结构的超短脉冲掺Yb~(3+)光纤环形激光器,采用非线性偏振旋转和啁啾脉冲光谱滤波相结合的锁模技术,实现了激光器锁模的开机自启动和高稳定运行.对激光器进行了长期运行稳定性、锁模开机自启动能力、锁模输出参数可重复性监测.锁模脉冲中心波长1052.9 nm,谱宽9.1 nm,脉冲能量4.25 nJ,脉冲宽度17.8 ps.运行期间,各参数波动均小于0.3%.开机自启动能力和可重复性测试显示,激光器可实现一键自启动,启动后各参数可重复精度在0.55%以内.     

基于有限元法分析宝石级金刚石的合成腔体温度场

以有限元法为理论分析手段模拟分析了温度梯度法合成宝石级金刚石大单晶的腔体温度场,实现了对宝石级金刚石的合成腔体内各位置温度同时测量.模拟结果表明:在宝石级金刚石合成过程中,其温度分布呈不均匀分布.腔体内高温区分布在样品(碳源+触媒)边缘,低温区分布在籽晶附近.样品腔内热量的传递方式和样品腔内的碳源输运方式相同,均由碳源的两侧向籽晶附近传输.籽晶附近轴向温度梯度大于径向温度梯度,导致单位时间内其轴向生长尺寸大于径向生长尺寸.宝石级金刚石腔体温度场分析的理论模型的成功构建,为新型宝石级金刚石腔体的研制提供了良好的设计基础,对促进优质宝石级金刚石的生长技术具有指导意义.     

2.0μm附近模拟呼吸气体中~(13)CO_2/~(12)CO_2同位素丰度的高精度实时在线测量

采用可调谐二极管激光吸收光谱技术,结合一新型多通池搭建了一套模拟呼吸气体中CO_2同位素丰度的测量装置.气体的压强、温度和流速被很好地控制且均能保持长期的稳定性;采用三次多项式拟合光谱基线,对光谱进行归一化,很好地消除了功率变化对测量结果的影响;利用移窗-回归技术消除频率漂移对同位素丰度测量的影响.实验结果表明:移窗-回归法的引入不仅延长了系统的稳定时间,还提高了系统的测量精度;小波去噪的应用获得了比多光谱平均法高2倍的信噪比;系统的稳定时间为100 s;Kalman滤波后系统测量精度为0.067‰.     

高效液相色谱法同时测定生物质乳酸发酵液中有机酸及糖类化合物

建立了高效液相色谱(HPLC)同时测定生物质乳酸发酵液中有机酸及糖类的分析方法。使用Bio-Rad Aminex HPX-87H色谱柱,以5 mmol/L的H2SO4为流动相,在柱温55 ℃,流速0.6 mL/min条件下,采用示差折光检测器进行检测。结果表明,该方法可在17 min内实现发酵液中各种有机酸和糖类化合物等的完全分离与定量,6种有机酸和3种糖类化合物在0.15～5.19 g/L范围内的线性关系良好,回归方程的线性相关系数在0.9998以上。将该法用于米根霉发酵液的检测,两个水平的加标回收率为96.91%～103.11%,相对标准偏差(n=6)为0.81%～4.61%。该法适用于微生物发酵液中多种有机酸和糖类的快速、高效分离和定量测定。     

基于随机并行梯度下降算法的多波长激光相干合成

由于受到受激布里渊散射(SBS)等非线性效应的限制,单频激光放大器的功率在百瓦量级,以非单频激光多波长激光作为种子源能够有效地抑制SBS并提高放大器功率.与单频激光相干合成相比,非单频率、多波长激光的相干合成有望将输出激光功率成量级地提高.基于随机并行梯度下降(stochastic parallel gradient descent,SPGD)算法,实现了四波长激光的相干合成.在系统闭环时,四路多波长激光合成后的主瓣能量能够提高3倍,达到理想值的75%.验证了多波长、非单频激光相干合成的可行性,为高功率相干合成的发展提供了新的途径.