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M.T. Averbuch-Pouchot 《Journal of solid state chemistry》1978,25(4):401-402
(NH4)2HCr3AsO13 is monoclinic () with a tetramolecular unit cell: a = 13.99(1), b = 9.47(1), c = 9.55(1) Å, and β = 93.10(1)°. We describe the chemical preparation and give crystal data for this compound. 相似文献
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Ammonium tetrametaphosphate-tellurate dihydrate, (NH4)4P4O12 · 2Te(OH)6 · 2H2O, is triclinic with the following unit cell dimensions: a = 11.845(6), b = 8.554(5), c = 7.433(5) Å, α = 66.28(5), β = 95.91(5), γ = 76.00(5)° space group: and Z = 1. The crystal structure has been determined with a final R value of 0.021. As in the previously described phosphate-tellurates, monophosphate-tellurate and trimetaphosphate-tellurates, the phosphoric anion (here the P4O12 ring) is independent of the octahedral Te(OH)6 group. A complete pattern of the hydrogen bonds is given. 相似文献
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M. Rzaigui Kbir Ariguib M.T. Averbuch-Pouchot A. Durif 《Journal of solid state chemistry》1983,50(2):240-246
Cerium(III) diammonium polyphosphate, (NH4)2Ce(PO3)5, is triclinic P1 with the following unit cell dimensions: a = 7.241(5) Å, b = 13.314(8) Å, c = 7.241(5)Å, α = 90.35(5)°, β′ = 107.50(5)°, γ = 90.28(5)°, and Z = 2, V = 665.7 Å3, Dx = 2.85 g/cm3. The crystal structure of this new type of polyphosphate has been solved and refined from 4130 independent reflections to a final R value 0.029. The most interesting feature of this salt is the existence of two infinite crystallographically nonequivalent (PO3)?∞ chains, one running parallel to the a axis, the other along the c axis, both with a period of five tetrahedra. This compound seems to be the first example of a long chain polyphosphate with crystallographic independent chains. 相似文献
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Marie-Thrse Averbuch-Pouchot 《无机化学与普通化学杂志》1987,545(2):118-124
Chemical preparation and crystal structure of CaNb2O(P4O13)(P2O7) are described. The monoclinic unit cell has the following dimensions: a = 13.264(9), b = 10.577(8), c = 12.393(9) Å, β = 96.09(1)°. Space group is C2/m with Z = 4. The crystal structure has been solved by using 1204 unique reflexions with a final R value 0.049. The main outstanding feature of this compound rests on the coexistence in its atomic arrangement of two kinds of phosphate anions with different degrees of condensation: a tetrameric linear one: (P4O13)6? and dimeric linear one: (P2O7)4?. The atomic arrangement can be schematically described as a stacking of alternating rows of P4O13 and P2O7 groups, parallel to the ā axis. The P4O13 groups have a twofold symmetry while the P2O7 groups have a non usual mirror symmetry. One of the oxygen atoms does not belong to the phosphoric groups. 相似文献
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Crystal structures of K4P4O12 · 2H2O and of two polymorphs of Na2K2P4O12 · 2H2O are reported. K4P4O12 · 2H2O is triclinic P1 with a = 8.153(4), b = 8.222(4), c = 11.154(8) Å, α = 97.33(5), β = 95.46(5), γ = 88.92(5)°, and Z = 2. R = 0.021 for 2898 reflections. Na2K2P4O12 · 2H2O has two crystalline forms: a triclinic one () with a = 11.366(8), b = 7.908(5), c = 7.929(5) Å, α = 90.07(5), β = 106.85(5), γ = 95.66(5)°, and Z = 2, and a tetragonal one (P41) with a = 7.928(5), c = 21.66(2), and Z = 4. The crystal structures of the first and second crystalline forms have been solved with final R values of 0.022 for 2505 reflections and 0.036 for 1347 reflections, respectively. Crystal data and chemical preparations are given for Na2(NH4)2P4O12 · 2H2O and Na2Rb2P4O12 · 2H2O, both isotypic with the triclinic form of Na2K2P4O12 · 2H2O. Unit-cell dimensions are, respectively, a = 11.547(8), b = 8.012(5), c = 8.044(5) Å, α = 89.76(5), β = 106.22(5), and γ = 94.78(5)°, for the ammonium salt, and a = 11.577(8), b = 8.006(5), c = 8.032(5) Å, α = 89.79(5), β = 106.58(5), and γ = 95.19(5)° for the rubidium salt. In addition the crystal structures of the two crystalline forms of Na4P4O12 · 4H2O were reexamined in order to localize the hydrogen atoms and refine their positions. 相似文献
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