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11.
A simple one-step synthetic methodology for stereoselective synthesis of E- and Z-3-bromo-2-vinyl chromones in quantitative yield in polar solvents under ambient conditions without the use of catalysts is reported. 相似文献
12.
A simple and efficient transesterification process for the synthesis of β-ketoester derivatives has been achieved by the reaction of methyl β-ketoester with higher alcohols at 110 °C under solvent-free, catalyst-free conditions and its application in synthesis of 3,4-dihydropyrimidin-2(1H)-ones C-5 ester derivatives via Biginelli reaction has been described. 相似文献
13.
S. Kumar S. U. Kasar R. K. Bajpai C. P. Kaushik R. Guin S. K. Das B. S. Tomar 《Journal of Radioanalytical and Nuclear Chemistry》2014,300(1):45-49
Kinetics of sorption of Pu(IV) by smectite-rich clay has been studied at varying metal ion concentrations. Different concentrations were achieved using different isotopes of Pu, namely, 239Pu, 238Pu and 237Pu. 237Pu was produced by alpha induced reaction on 235U, followed by radiochemical separation of Pu from irradiated U3O8 target. The concentrations used are above and below the solubility of Pu(IV) under neutral pH conditions, thereby, indicating the mechanism of sorption reactions of Pu(IV) in typical laboratory experiments and field level observations. Kinetics of Pu(IV) at 10?13 M concentration was found to be fast whereas at higher metal concentration the rate is governed by a slow step, indicating the role of formation of Pu(IV) polymeric species at the sorbent surface. 相似文献
14.
Patra Kankan Sengupta Arijit Mishra R. K. Mittal V. K. Valsala T. P. Kaushik C. P. 《Journal of Radioanalytical and Nuclear Chemistry》2022,331(3):1473-1481
Journal of Radioanalytical and Nuclear Chemistry - Efficient and selective extraction of 137Cs and 90Sr from high level liquid waste (HLLW) is of utmost importance in the back end nuclear fuel... 相似文献
15.
Wang Haoran Wasim Akhtar Lalit Mohan Nainwal Sumit Kumar Kaushik Mymoona Akhter Mohammad Shaquiquzzaman Mohammad Mumtaz Alam 《Journal of heterocyclic chemistry》2020,57(9):3350-3360
Thirteen new benzimidazole pendant cyanopyrimidine derivatives were synthesized. The compounds were synthesized through multistep reaction protocol. The structures of synthesized derivatives were studied by EI-MS, 1H NMR, FT-IR and elemental analysis. All the compounds were studied for their anticancer activity at National Cancer Institute. Except compound 7j , all the compounds unveiled cytotoxicity against cancer cells. The most active compound 7a had shown highest value of growth inhibition of 88.44% and 84.19% against HOP-92 and T-47D cancer cell lines. 相似文献
16.
M.A. Mujawar H. Gohel S.K. Bhardwaj S. Srinivasan N. Hickman A. Kaushik 《Materials Today Chemistry》2020
Biosensors are emerging as efficient (sensitive and selective) and affordable analytical diagnostic tools for early-stage disease detection, as required for personalized health wellness management. Low-level detection of a targeted disease biomarker (pM level) has emerged extremely useful to evaluate the progression of disease under therapy. Such collected bioinformatics and its multi-aspects-oriented analytics is in demand to explore the effectiveness of a prescribed treatment, optimize therapy, and correlate biomarker level with disease pathogenesis. Owing to nanotechnology-enabled advancements in sensing unit fabrication, device integration, interfacing, packaging, and sensing performance at point-of-care (POC) has rendered diagnostics according to the requirements of disease management and patient disease profile i.e. in a personalized manner. Efforts are continuously being made to promote the state of art biosensing technology as a next-generation non-invasive disease diagnostics methodology. Keeping this in view, this progressive opinion article describes personalized health care management related analytical tools which can provide access to better health for everyone, with overreaching aim to manage healthy tomorrow timely. Considering accomplishments and predictions, such affordable intelligent diagnostics tools are urgently required to manage COVID-19 pandemic, a life-threatening respiratory infectious disease, where a rapid, selective and sensitive detection of human beta severe acute respiratory system coronavirus (SARS-COoV-2) protein is the key factor. 相似文献
17.
The paper deals with the analysis of a non-stationary parabolic partial differential equation with a time delay. The highest order derivative term is affected by the small parameter. This is precisely the case when the magnitude of the convective term becomes much larger compare to that of diffusion term. The solution of problem exhibits steep gradients in the narrow intervals of space and short interval of times. In these cases a dissipative loss turned out to be more complex. Even for the one spatial dimension and one temporal variable, not all difference scheme can capture these steep variation. Although the analysis is restricted to the model in one space dimension, the technique and comparison principles developed should prove useful in assessing the merits of numerical solution of other nonlinear model equations too. 相似文献
18.
Tania Chowdhury Kaushik Bera Debabrata Samanta Sandip Dolui Suvendu Maity Nakul C. Maiti Prasanta Kumar Ghosh Debasis Das 《应用有机金属化学》2020,34(4):e5556
Four new zinc (II) complexes [Zn (HL1H)Br2] (1), [Zn (HL1H)Cl2] (2), [Zn2(HL2)Br3] (3), and [Zn (HL2)Cl] (4) have been synthesized by adopting template synthetic strategy and utilizing two homologous Schiff base ligands (H2L1 = 4-bromo-2-{[2-(2-hydroxyethylamino)-ethylimino]-methyl}-6-methoxyphenol, H2L2 = 4-bromo-2-{[3-(2-hydroxyethylamino)propylimino]methyl}-6-methoxyphenol), differing in one -CH2- unit in the ligating backbone, by adopting template synthetic strategy. All the complexes have been characterized by single crystal X-ray diffraction analysis as well as by other routine physicochemical techniques. Ligand mediated structural variations have been observed and rationalized by density functional theoretical (DFT) calculations. Interaction of the complexes 1–4 with Bovine Serum Albumin protein (BSA) has been studied by different spectroscopic techniques. A complete thermodynamic profile (ΔHo, ΔSo and ΔGo) was evaluated initially from the change in absorption and fluorescence spectra upon addition of BSA to the complexes. Appreciable binding constant values in the range ~ 0.94–4.51 × 104 M−1 indicate efficient binding tendency of the complexes to BSA with the sequence 1 ≅ 2 > 3 ≅ 4. Circular dichroism (CD), isothermal calorimetric titration experiments, molecular docking and molecular dynamics have been performed to gain deep insight into the binding regions of complex 1 to BSA. Experimental evidences suggest an interaction of zinc complexes at the surface of BSA protein and this particular binding has been exploited to determine unknown concentration of BSA protein. For this purpose complex 1 was explored as a BSA protein quantification tool. 相似文献
19.
We study the asymptotic properties of both the horizontal and vertical shift functions based on independent ranked set samples
drawn from continuous distributions. Several tests derived from these shift processes are developed. We show that by using
balanced ranked set samples with bigger set sizes, one can decrease the width of the confidence band and hence increase the
power of these tests. These theoretical findings are validated through small-scale simulation studies. An application of the
proposed techniques to a cancer mortality data set is also provided.
Part of the research was conducted while Kaushik Ghosh was visiting Statistical Research and Applications Branch of the National
Cancer Institute on an Intergovernmental Personnel Assignment. 相似文献
20.
Kaushik Mukherjee Srinivasan Natesan 《Numerical Methods for Partial Differential Equations》2014,30(6):1931-1960
In this article, we consider a class of singularly perturbed mixed parabolic‐elliptic problems whose solutions possess both boundary and interior layers. To solve these problems, a hybrid numerical scheme is proposed and it is constituted on a special rectangular mesh which consists of a layer resolving piecewise‐uniform Shishkin mesh in the spatial direction and a uniform mesh in the temporal direction. The domain under consideration is partitioned into two subdomains. For the spatial discretization, the proposed scheme is comprised of the classical central difference scheme in the first subdomain and a hybrid finite difference scheme in the second subdomain, whereas the time derivative in the given problem is discretized by the backward‐Euler method. We prove that the method converges uniformly with respect to the perturbation parameter with almost second‐order spatial accuracy in the discrete supremum norm. Numerical results are finally presented to validate the theoretical results.© 2014 Wiley Periodicals, Inc. Numer Methods Partial Differential Eq 30: 1931–1960, 2014 相似文献