全文获取类型
收费全文 | 1373篇 |
免费 | 35篇 |
国内免费 | 7篇 |
专业分类
化学 | 725篇 |
晶体学 | 8篇 |
力学 | 11篇 |
数学 | 210篇 |
物理学 | 461篇 |
出版年
2023年 | 6篇 |
2022年 | 11篇 |
2021年 | 24篇 |
2020年 | 13篇 |
2019年 | 12篇 |
2018年 | 15篇 |
2017年 | 9篇 |
2016年 | 31篇 |
2015年 | 26篇 |
2014年 | 41篇 |
2013年 | 60篇 |
2012年 | 55篇 |
2011年 | 56篇 |
2010年 | 33篇 |
2009年 | 37篇 |
2008年 | 67篇 |
2007年 | 55篇 |
2006年 | 51篇 |
2005年 | 80篇 |
2004年 | 211篇 |
2003年 | 34篇 |
2002年 | 35篇 |
2001年 | 20篇 |
2000年 | 26篇 |
1999年 | 14篇 |
1998年 | 18篇 |
1996年 | 15篇 |
1995年 | 8篇 |
1994年 | 17篇 |
1993年 | 7篇 |
1992年 | 19篇 |
1991年 | 21篇 |
1990年 | 19篇 |
1989年 | 12篇 |
1988年 | 10篇 |
1987年 | 16篇 |
1986年 | 9篇 |
1985年 | 18篇 |
1984年 | 14篇 |
1983年 | 11篇 |
1982年 | 14篇 |
1981年 | 10篇 |
1980年 | 15篇 |
1979年 | 9篇 |
1978年 | 14篇 |
1977年 | 13篇 |
1976年 | 15篇 |
1973年 | 9篇 |
1970年 | 5篇 |
1936年 | 6篇 |
排序方式: 共有1415条查询结果,搜索用时 31 毫秒
141.
142.
David P. Billington Dennis A. Nagy 《International Journal of Solids and Structures》1978,14(10):851-860
When the flexural acceleration of a plate is measured by an accelerometer, the mass of the accelerometer tends to reduce the magnitude of the acceleration.This study establishes a simple analytical relation between the accelerometer mass and the corresponding reduction of acceleration. This has been done by studying an idealized diffraction problem for the plate flexural waves.The complex frequency response depends upon the accelerometer mass, the frequency of the flexural wave, the plate thickness and the material parameters of the plate.A numerical filtering method is used to bring an experimental result and a corresponding numerical prediction closer together. 相似文献
143.
Direct analysis in real time mass spectrometry (DART‐MS) of highly non‐polar low molecular weight polyisobutylenes
下载免费PDF全文
![点击此处可从《Journal of mass spectrometry : JMS》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Lajos Nagy Tibor Nagy György Deák Ákos Kuki Borbála Antal Miklós Zsuga Sándor Kéki 《Journal of mass spectrometry : JMS》2015,50(9):1071-1078
Low molecular weight polyisobutylenes (PIB) with chlorine, olefin and succinic acid end‐groups were studied using direct analysis in real time mass spectrometry (DART‐MS). To facilitate the adduct ion formation under DART conditions, NH4Cl as an auxiliary reagent was deposited onto the PIB surface. It was found that chlorinated adduct ions of olefin and chlorine telechelic PIBs, i.e. [M + Cl]? up to m/z 1100, and the deprotonated polyisobutylene succinic acid [M? H]? were formed as observed in the negative ion mode. In the positive ion mode formation of [M + NH4]+, adduct ions were detected. In the tandem mass (MS/MS) spectra of [M + Cl]?, product ions were absent, suggesting a simple dissociation of the precursor [M + Cl]? into a Cl? ion and a neutral M without fragmentation of the PIB backbones. However, structurally important product ions were produced from the corresponding [M + NH4]+ ions, allowing us to obtain valuable information on the arm‐length distributions of the PIBs containing aromatic initiator moiety. In addition, a model was developed to interpret the oligomer distributions and the number average molecular weights observed in DART‐MS for PIBs and other polymers of low molecular weight. Copyright © 2015 John Wiley & Sons, Ltd. 相似文献
144.
Thermal Effects and Structural Changes of Photosynthetic Reaction Centers Characterized by Wide Frequency Band Hydrophone: Effects of Carotenoids and Terbutryn
下载免费PDF全文
![点击此处可从《Photochemistry and photobiology》网站下载免费的PDF全文](/ch/ext_images/free.gif)
László Nagy Vladimir Kiss Vlad Brumfeld Károly Osvay Ádám Börzsönyi Melinda Magyar Tibor Szabó Márta Dorogi Shmuel Malkin 《Photochemistry and photobiology》2015,91(6):1368-1375
Photothermal characteristics and light‐induced structural (volume) changes of carotenoid‐containing and noncontaining photosynthetic reaction centers (RCs) were investigated by wide frequency band hydrophone. We found that the presence of carotenoid either does not play considerable role in the light‐induced conformational movements, or these rearrangements are too slow for inducing a photoacoustic (PA) signal. The kinetic component with a few tens of microseconds, exhibited by the carotenoid‐less RCs, appears to be similar to that of triplet state lifetimes, identified by other methods. The binding of terbutryn to the acceptor side is shown to affect the dynamics of the RC. Our results do not confirm large displacements or volume changes induced by the charge movements and by the charge relaxation processes in the RCs in few hundreds of microseconds time scale that accompanies the electron transfer between the primary and secondary electron acceptor quinones. 相似文献
145.
Krisztina Majer-Baranyi András Nagy Olga Bukovskaya István Szendrő András Székács 《International journal of environmental analytical chemistry》2015,95(6):481-493
A label-free, optical waveguide lightmode spectroscopy based immunosensor was developed for frog (Bombina orientalis) vitellogenin (Vtg) determination in biological samples as a biomarker for exogenous oestrogen compounds. Antibody against Vtg was produced in rabbits immunised with purified lipovitellin (Lpv), a precursor of Vtg, from the homogenised ovary of oriental fire-bellied toads (B. orientalis). The purified protein and Lpv/Vtg-specific serum were applied in both competitive and direct immunoassay formats using optical waveguide lightmode spectroscopy immunosensor. When measuring Vtg in direct manner, the Lpv antibody (1.76 µg mL?1) was immobilised on the sensor surface, and the linear measuring range for Vtg was 0.1–10 µg mL?1. During the competitive measurement, 100 ng mL?1 Lpv was applied for the immobilisation. The linear measuring range for Vtg was 0.5–50 ng mL?1. We studied the relative substrate specificity of the antibody, and it was concluded that the method is suitable for the sensitive and selective determination of Vtg levels in toads. Heart, liver and gonad samples from male animals were spiked with Vtg and were analysed using the newly developed method, and female toads and spawn samples were tested and compared to the calibration curve obtained by the spiked samples. 相似文献
146.
Zoltán Lóránt Nagy 《Journal of Graph Theory》2017,84(4):566-580
We study the existence and the number of k‐dominating independent sets in certain graph families. While the case namely the case of maximal independent sets—which is originated from Erd?s and Moser—is widely investigated, much less is known in general. In this paper we settle the question for trees and prove that the maximum number of k‐dominating independent sets in n‐vertex graphs is between and if , moreover the maximum number of 2‐dominating independent sets in n‐vertex graphs is between and . Graph constructions containing a large number of k‐dominating independent sets are coming from product graphs, complete bipartite graphs, and finite geometries. The product graph construction is associated with the number of certain Maximum Distance Separable (MDS) codes. 相似文献
147.
Huszank R Szikra D Simon A Szilasi SZ Nagy IP 《Langmuir : the ACS journal of surfaces and colloids》2011,27(7):3842-3848
In this study we investigated the chemical and surface wettability changes of poly(dimethylsiloxane) (PDMS) induced by a 2.0 MeV He(+) beam irradiation. The chemical changes created in PDMS were characterized by universal attenuated total reflectance infrared (UATR-FTIR) spectroscopy, while the changes of the wettability were determined by contact angle measurements. In a separate analysis, hydrogen depletion was also investigated with a 1.6 MeV He(+) beam by applying the elastic recoil detection analysis (ERDA) and Rutherford backscattering spectrometry techniques simultaneously. The ERDA results showed that the hydrogen content of PDMS decreased irreversibly, which means that volatile products were formed under radiolysis, such as hydrogen or methane. The results were completed with UATR-FTIR measurements. We propose a complete reaction mechanism for the processes taking place in PDMS. These ion beam induced processes, such as chain scissions, cross-linking, and depletion of small molecular weight fragments, lead to the formation of a silica-like final product (SiO(x)). The significant chemical changes at the surface influence the wettability of PDMS, making it considerably more hydrophilic. The penetration depth of the 2.0 MeV He(+) ions is significantly higher compared to that of other surface modification techniques, which makes the modified layer thick and homogeneous; on the other hand, it is easily controllable by the energy of the incident ions. 相似文献
148.
Giotta L Mastrogiacomo D Italiano F Milano F Agostiano A Nagy K Valli L Trotta M 《Langmuir : the ACS journal of surfaces and colloids》2011,27(7):3762-3773
The ability of microorganisms to adhere to abiotic surfaces and the potentialities of attenuated total reflection Fourier transform infrared (ATR-FTIR) spectroscopy have been exploited to study protonation and heavy metal binding events onto bacterial surfaces. This work represents the first attempt to apply on bacteria the recently developed method known as perfusion-induced ATR-FTIR difference spectroscopy. Such a technique allows measurement of even slight changes in the infrared spectrum of the sample, deposited as a thin layer on an ATR crystal, while an aqueous solution is perfused over its surface. Solutions at different pH have been used for inducing protonation/deprotonation of functional groups lying on the surface of Rhodobacter sphaeroides cells, chosen as a model system. The interaction of Ni(2+) with surface protonable groups of this microorganism has been investigated with a double-difference approach exploiting competition between nickel cations and protons. Protonation-induced difference spectra of simple model compounds have been acquired to guide band assignment in bacterial spectra, thus allowing identification of major components involved in proton uptake and metal binding. The data collected reveal that carboxylate moieties on the bacterial surface of R. sphaeroides play a role in extracellular biosorption of Ni(2+), establishing with this ion relatively weak coordinative bonds. 相似文献
149.
A novel, simple and environmentally friendly procedure for copper determination has been developed. The method is based on the formation of an ion associate of Cu(I) with 1,3,3-trimethyl-2-[5-(1,3,3-trimethyl-1,3-dihydroindol-2-ylidene)-penta-1,3-dienyl]-3H-indolium (DIDC) in the presence of chloride ions as ligand, followed by dispersive liquid-liquid microextraction (DLLME) of the formed ion associate into organic phase and UV-Vis spectrophotometric detection. The following experimental conditions were used: pH 3, 0.24 mol L− 1 chloride ions, 0.06 mmol L− 1 DIDC. The effect of the nature of the extraction solvent, auxiliary solvent and disperser solvent used was studied. A mixture of amyl acetate, tetrachloromethane, and methanol in a 1:1:3 v/v/v ratio was selected for the DLLME procedure. The absorbance of the coloured extracts at 640 nm wavelength obeys Beer's law in the range 0.020-0.090 mg L− 1 of Cu. The limit of detection calculated from a blank test (n = 10) based on 3s is 0.005 mg L− 1 of Cu. The developed procedure was applied to the analysis of water samples. The suggested DLLME is compared with two procedures previously reported from our laboratory based on (1) conventional liquid-liquid extraction, and (2) sequential injection extraction performed in a dual-valve sequential injection system. The advantages and disadvantages of each method are discussed. 相似文献
150.
A simple, rapid, and sensitive RP-HPLC method using photodiode array detection was developed and validated for the simultaneous determination of granisetron hydrochloride, 1-methyl-1H-indazole-3-carboxylic acid (the main degradation product of granisetron), sodium benzoate, methylparaben, propylparaben, and 4-hydroxybenzoic acid (the main degradation product of parabens) in granisetron oral drops and solutions. The separation of the compounds was achieved within 8 min on a SymmetryShield RP18 column (100 x 4.6 mm id, 3.5 microm particle size) using the mobile phase acetonitrile--0.05 M KH2PO4 buffered to pH 3 using H3PO4 (3+7, v/v). The photodiode array detector was used to test the purity of the peaks, and the chromatograms were extracted at 240 nm. The method was validated, and validation acceptance criteria were met in all cases. The robust method was successfully applied to the determination of granisetron and preservatives, as well as their degradation products in different batches of granisetron oral drops and solutions. The method proved to be sensitive for determination down to 0.04% (w/w) of granisetron degradation product relative to granisetron and 0.03% (w/w) 4-hydroxybenzoic acid relative to total parabens. 相似文献