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51.
Asymmetric synthesis plays an important role in the synthesis of therapeutics and natural products. Asymmetric oxindoles with a stereogenic quaternary carbon center are extensively present in various natural products and biologically active compounds. Several methods such as employing chiral auxiliaries or chiral catalysts were developed for asymmetric synthesis of spirooxindoles or 3,3-disubtituted oxindoles. In this review, we make a detailed overview of the latest developments in the use of isatin as starting material for the asymmetric synthesis of spirooxindoles and 3,3-disubstituted oxindoles during the period from 2015 to 2017. 相似文献
52.
Accuracy analysis of predicted velocity profiles of laminar duct flow with entropy generation method
The objective of this work is to estimate the accuracy of a predicted velocity profile which can be gained from experimental results, in comparison with the exact ones by the methodology of entropy gen... 相似文献
53.
B. MOHAMMADI 《International Journal of Computational Fluid Dynamics》2013,27(1-2):27-50
Abstract We present through this paper some new results with our approach for optimal shape design based on a CAD-free framework for shape and unstructured mesh deformations, automatic differentiation by program for the gradient computation and mesh adaption by metric control. Automatic differentiation allows for an easy, reliable and fast discrete adjoint computation. We managed to get the Jacobian of our Navier-Stokcs solver including a k-e turbulence model and wall-laws. The CAD-free framework is shown to be particularly convenient for optimization when the mesh connectivities and the shape discretization arc variable during optimization. Using these ingredients constrained optimization for turbulent transonic flows has been investigated in both 2 and 3D. 相似文献
54.
Payman Hashemi Alireza Badiei Mohammad Shamizadeh Ghodsi Mohammadi Ziarani Ali Reza Ghiasvand 《中国化学会会志》2012,59(6):727-732
LUS‐1 typed nanoporous silica particles were synthesized and silylated with hexamethyldisilazane and investigated as a highly porous fiber coating for solid‐phase microextraction (SPME). The pore size distribution of the prepared Sil‐LUS‐1 was still typical of MCM‐41 and centered at 3 nm with a specific surface area of 720 m2g?1. The SPME fiber was prepared by liming the material on a copper wire. The extraction efficiency of the new fiber was compared with a commercial PDMS fiber for headspace extraction and GC‐MS analysis of phenol, 4‐nitrophenol, 2,4‐dichlorophenol and 4‐chlorophenol in water samples. Due to the high porosity of the prepared fiber it showed a higher sensitivity and better selectivity for the extraction of the target compounds. For optimization of different factors affecting the extraction efficiency, a simplex optimization method was used. The relative standard deviation for the measurements by one fiber was better than 7% for five replicates and the fiber‐to‐fiber reproducibility was about 10% for five fabricated fibers. Detection limits in the range of 0.002 to 0.026 μg mL?1 were obtained for the phenolic compounds. The fiber was successfully applied for the determination of phenolic compounds in natural water samples. 相似文献
55.
Ghasem SHIRAVAND Alireza BADIEI Ghodsi Mohammadi ZIARANI Morteza JAFARABADI Majid HAMZEHLOO 《催化学报》2012,33(8):1347-1353
Fe-g-C3N4-LUS-1 was prepared by the thermal decomposition of dicyandiamide inside the pores of LUS-1 under an inert atmosphere.It was used as a photocatalyst for the hydroxylation of benzene to phenol in sunlight.The catalysts were characterized by Fourier transform infrared spectroscopy,N2 adsorption-desorption,X-ray diffraction,and scanning electron microscopy.In Fe-g-C3N4-LUS-1,a single layer of graphitic carbon nitride(g-C3N4) was formed on the surface of LUS-1.The photocatalytic activity of the iron containing g-C3N4 based catalysts was investigated,and the catalytic activity was remarkably enhanced when the reaction condition was changed from dark to sunlight.The best result was obtained with 20%Fe-g-C3N4-LUS-1 in sunlight. 相似文献
56.
Davoud Ghodsi Nahri 《Optics & Laser Technology》2012,44(8):2436-2442
The effects of temperature (homogeneous broadening (HB)) on output power, gain spectrum, and light–current (L–I) characteristics of self-assembled quantum-dot lasers (SAQDLs) are investigated. We also analyze the effects of inhomogeneous broadening (IHB) and QD coverage on L–I characteristics and the effects of carrier relaxation and recombination lifetimes on L–I and optical gain–current characteristics. We propose the possibility of single mode lasing for every HB that is comparable, near, or equal to IHB and for every lasing injected current. We also show that peak optical gain does not change with variations of temperature (HB) and injected current. Simulation of L–I characteristics shows that L–I curves become nonlinear as HB elevates up to near IHB. Exceeding HB from IHB and elevating IHB result in degradation of L–I characteristics. Threshold current grows as temperature (HB) enhances. It is, therefore, concluded that the SAQDL has the best L–I characteristics when HB is equal to IHB. It is also shown that there is a threshold and an optimum QD coverage. We reveal that the phonon bottleneck degrades L–I characteristics and that the maximum output power decreases significantly with enhancement of IHB. Finally, we show that the phonon bottleneck, low wetting layer and QD crystal quality reduce the differential gain, relaxation oscillation frequency and modulation bandwidth. 相似文献
57.
Morteza Hosseini Mohammad Reza Ganjali Zahra Rafiei-Sarmazdeh Farnoush Faridbod Hassan Goldooz Alireza Badiei Parviz Nourozi Ghodsi Mohammadi Ziarani 《Analytica chimica acta》2013
A new Lu3+ sensitive fluorescent chemosensor is designed using 8-hydroxyquinoline functionalized mesoporous silica with highly ordered structure (LUS-SPS-Q). The characterization of LUS-SPS-Q showed that the organized structure has been preserved after the post grafting procedure. The synthesized material showed a selective interaction with Lu3+ ion, most probably due to the presence of the fluorophore moiety at its surface. The emission intensity of the Lu3+-bound mesoporous material increases with an increase in concentrations of Lu3+ ion. Addition of other mono-, di-, trivalent ions resulted in insignificant change in the fluorescent intensity. The enhancement of fluorescence is attributed to the strong covalent binding of Lu3+ ion. The linear response range of Lu3+ chemo-sensor was from 1.6 × 10−7 to 1.0 × 10−5 mol L−1. The Limit of detection obtained was 8.2 × 10−8 mol L−1 and the pH range which the proposed chemo-sensor can be applied was 3.3–8.3. 相似文献
58.
A carbon paste electrode (CPE) modified with carbon nanotubes and 5‐amino‐3’,4’‐dimethyl‐ bi‐ phenyl‐2‐ol (5ADB) is prepared. Under the optimum pH of 7.0, the oxidation of ascorbic acid (AA) on the modified CPE occurs at a potential about 280 mV less positive than that on the unmodified CPE. Some kinetic and thermodynamic parameters for electrocatalytic oxidation of AA, including electron transfer coefficient (α = 0.58) and diffusion coefficient (D = 2.2 × 10-6 cm2/s), are also determined. AA, acetaminophen (AC), and tryptophan (TRP) were detected simultaneously using the modified CPE. The peak potentials recorded using the modified CPE in phosphate‐buffered solution at pH 7.0 were 265, 465, and 780 mV for AA, AC, and TRP, respectively. The modified CPE was successfully used to determine the concentrations of AA, AC, and TRP in real samples. 相似文献
59.
Designed nitrogen and sulfur co‐doped graphene wrapped magnetic core‐shell supported Pd nanoparticles were synthesized through the following steps. Firstly, Fe3O4 was prepared, coated with silica and then functionalized with amine groups to create a positive charge on the structure for enhancing the interaction of the Fe3O4@SiO2 with graphene oxide. Secondary, the pre‐catalyst wrapped with graphene to enhance adsorption of aromatic substrates through π–π stacking. Thirdly, graphene was doped with nitrogen and sulfur to increase the grafting of Pd in hybrid. Finally, Pd NPs were attached on the surface of pre‐engineered structure to produce Fe3O4@SiO2@N,S‐wG@Pd which exhibited high performance in Suzuki reactions. This superior activity can be indexed to the incorporation of N and S atoms into graphene led to high anchoring and well‐dispersion of Pd NPs on the nanocomposite surface offering large amounts of active centers, that strongly increased the interaction between Pd and substrates to decreases Pd leaching. 相似文献
60.
In the present study, the modification of a mesoporous organosilica nanocomposite SBA-15 (Santa Barbara Amorphous 15) was carried out in two steps, first through the surface functionalization of SBA-Pr-NH2 with 2-chloroquinoline-3-carbaldehyde to form SBA-Pr-NCQ, and then through a post-modification process with palladium ions. The target nanocompound structure of SBA-Pr-NCQ-Pd was characterized by different techniques (thermogravimetric analysis, X-ray diffraction, scanning electron microscopy, Energy-dispersive X-ray spectroscopy (EDX), and Fourier transform infrared spectroscopy). The catalytic performance of the porous inorganic–organic hybrid nanocomposite (SBA-Pr-NCQ-Pd) in one of the most important carbon–carbon bond-forming processes, the Mizoroki–Heck coupling reaction of aryl halides and methacrylate in water/ethanol media, was examined. Compared to previous reports, this protocol afforded some advantages, such as high yields of products, short reaction times, catalyst stability without leaching, simple methodology, easy workup, and greener conditions. Also, the nanocatalyst can be easily separated from the reaction mixture and reused several times without a significant decrease in activity and promises economic as well as environmental benefits. 相似文献