Hg_(0.8)Cd_(0.2)Te光电二极管的外差量子效率的研究

介绍了n~+-P型离子注入Hg_(0.8)Cd_(0.2)Te光电二极管的敏面上外差量子效率分布函数η(x,y)的正则化分析方法,并通过CO_2相干激光探测的方法测量了η(x,y).     

固体激光器的稳模式热稳条件分析

对传统的稳模式热稳条件进行了推广，使之也可适用于非球面驻波稳定腔的其它谐振腔，如环形腔等；引入了稳模式弱热稳条件的概念，进而提出了一种折衷的优化设计方法——使谐振腔同时满足稳功率热稳条件和稳模式弱热稳条件，从而使得激光器的输出既稳功率又具有一定的模式热稳定性，如发散角的热稳定性；此外，还给出了球面驻波稳定腔、球面环形稳定腔的稳模式强、弱热稳条件的解析解     

Three New Compounds from Forsythia Suspensa (Thunb.) Vahl

Forsythiasuspensa(ThUnb.)VahlhasbeenusedintradihonalChinesemedicineforanhiallammatoryandamibacterialpmposes.AnUInberofcompoundssuchasforsythiaside,phillygeninrengyoletc.haVebeenidentifiedl-#fromthefactsofmisplat.AsPartofourstudyontheachveprinciplesoftradihonalChinesemedicine,wereinvestigatCdthechemicalconstitllentsofRsuspensa.heartycompoundshavebeenisolatCdfromthisspecies.ThispaperdescribesthestrUcturalelucidahonofthreenewcompoundsfsuspenolicacid(1),forSythensideA(2),andforsythensideB(3)…     

离子液体介质中钌纳米粒子催化苯乙酮及其衍生物的不对称加氢反应

采用水溶性三(间-磺酸钠苯基)膦(TPPTS)作稳定剂, 在离子液体1-丁基-3-甲基-咪唑四氟硼酸盐([BMIM]BF4)或1-丁基-3-甲基-咪唑对甲基苯磺酸盐([BMIM][p-CH3C6H4SO3])介质中用氢气还原RuCl3·3H2O, 得到钌纳米粒子. 将此钌纳米粒子与(1S, 2S)-1,2-二苯基乙二胺(简称(1S, 2S)-DPEN)、KOH在离子液体/异丙醇介质中原位生成一种不对称加氢催化剂, 用于催化苯乙酮及其衍生物的不对称加氢反应. 实验结果表明, 离子液体介质中的纳米钌催化剂体系具有良好的催化活性和对映选择性. 在优化反应条件下, 催化苯乙酮获得了100%的转化率和79.1%的对映选择性. 并且产物经正己烷萃取后, 含有钌纳米粒子的离子液体可以循环使用.     

湿法水解制备可见光催化剂N/TiO2

The N/TiO₂ was prepared by wet hydrolyzation method. The photocatalytic decomposition of benzoic acid solution was carried out under simulated sun light; the photocatalytic activity was 2.47 times of TiO₂. The products were characterized by XRD, SPS, EFISPS and XPS, respectively. The results of XRD showed that the N could restrain the crystallization transformation of TiO₂ from anatase to rutile. The N/TiO₂ was still n-type semiconductor, and the absorbance wavelength appeared red-shifted by N-doping. The band gap of N/TiO₂ was decreased to 2.7 eV. The amount of doped-N is about 0.94at.%. The binding energy of N1s are 396.62 eV (Ti-N bonds, β-N) and 400.87 eV (N-N bonds, γ-N₂), respectively, and the photocatalytic activity of N/TiO₂ under visible light is related to the β-N. The N atoms replace the O of the TiO₂ and form the Ti-N bonding.     

衡量互反矩阵一致性的一种新指标

本文针对ＡＨＰ中利用几何平均值来估计各因素权向量的方法提出了与之匹配的一种新的衡量互反矩阵一致性的指标，并且制定了相应的衡量标准，同时将其与利用最大特征值所建立的指标入标准进行了比较与讨论。     

Design of a Fused-Silica Subwavelength Polarizing Beam Splitter Grating Based on the Modal Method

A polarizing beam splitter （PBS） design based on a fused-silica lamellar subwavelength transmission grating is demonstrated with the modal method, where TE- and TM-polarized waves are mainly diffracted in the -1st and 0th orders, respectively. The physical explanation of the grating diffraction is illustrated by the interference of the corresponding parts of the two propagating modes, which is very similar to a Mach-Zehnder interferometer. It is shown that diffraction efficients over 99% for a TM-polarized wave in the -1st order and 90% for a TE-polarized wave in the 0th order are obtained at the wavelength of 1.053 μm. The polarization transmission extinction ratios are better than 33 dB and 51 dB for the order 0th and the -1st order, respectively. The splitting properties of the PBS grating designed by the modal method are in good agreement with the results simulated by the rigorous coupled wave analysis method.     

微波溶样FAAS法测定人发中锰

采用微波溶样技术消解头发样品,用FAAS法测定头发中锰,实验结果表明,用微波溶样技术消解头发具有节省时间,节约试剂,消解完全等优点,本方法的相对标准偏差为1.7%-3.6%,回收率为93.8%-102.5%.     

相位调制边带失衡问题研究

 高功率激光系统中一般利用相位调制器对单纵模激光进行频谱展宽以避免受激布里渊散射，当后继系统中的滤波器存在中心波长偏差时，则会导致相位调制产生的边带失衡，使光信号出现较为严重的高频起伏。基于前端系统模拟平台对此问题进行了数值模拟研究，结果表明滤波后的高频起伏随滤波器带宽变窄和中心波长偏差增大而加剧。分析表明0.2 nm带宽的滤波器出现0.05 nm左右的波长偏差时，将引起24.3%左右的顶部起伏。实验中根据分析将滤波器带宽从0.2 nm加大到0.4 nm，成功将脉冲顶部起伏从25.2%减小到了4.4%，对前端系统的研制起到了很好的指导作用。     

三元体系LiCl-LiNO3-H2O 273.15 K和323.15 K等温溶解度的测定

Solubility of the ternary system LiCl-LiNO₃-H₂O was measured at 273.15 K and 323.15 K by analyzing the equilibrated phase composition. Experimental result shows that there are three solubility branches at 273.15 K, corresponding to the solid phases LiCl·2H₂O，LiNO₃ and LiNO₃·3H₂O, respectively, while there are two solubility branches at 323.15 K, corresponding to the solid phase LiCl·H₂O and LiNO₃. The invariant point compositions are (1) 33.68wt% LiCl, 14.32wt% LiNO₃ and (2) 27.70wt% LiCl, 20.60wt% LiNO₃ at 273.15 K and (3) 39.07wt% LiCl, 16.89wt% LiNO₃ at 323.15 K. Also, the experimental results show that the solid phases in equilibrium with the solution {x(2.8LiCl+LiNO₃)-(1-x)H₂O} are LiNO₃·3H₂O or LiNO₃ at 273.15 K and LiNO₃ at 323.15 K.