Negative molecular ions of azafullerenes and their hydrogenated derivatives

The formation and decay of negative molecular ions of azafullerenes and their hydrogenated derivatives are investigated by mass spectrometry. The mechanisms of resonant electron capture and the lifetimes of negative molecular ions with respect to the electron autodetachment in azafullerene molecules are discussed. A comparative analysis of the data obtained for azafullerenes and hydrogenated fullerene derivatives is carried out.     

Applying Stochastic Algorithms to a Locomotive Scheduling Problem

This paper addresses a problem common to all railway networks. Given a fixed train timetable and locomotives (or other forms of traction) of various types, each train must be allocated a locomotive. This paper examines the use of stochastic algorithms for such a problem. Two types of algorithm are used—a simple ‘local improvement’ method, performed successively from randomly chosen starting points, and a ‘simulated annealing’ approach. Both are found to give considerably better results than a deterministic method in current use, and the annealing approach is probably the better stochastic method.     

On the Density-Density Critical Indices¶in Interacting Fermi Systems

The behaviour of correlation functions of d=1$ interacting fermionic systems is determined by a small number of critical indices. We prove that one of them is exactly zero. As a consequence, the behavior of the Fourier transform of the density-density correlation at zero momentum is qualitatively unaffected by the interaction, contrary to what happens at , if is the Fermi momentum. The result is obtained by implementing Ward identities in a Renormalization Group approach. Received: 12 November 2001 / Accepted: 25 February 2002?Published online: 2 October 2002     

The study and applications of photochemical-dynamical gravity wave model II

A nonlinear, compressible, non-isothermal gravity wave model that involves photochemistry is used to study the effects of gravity wave on atmospheric chemical species distributions in this paper. The changes in the distributions of oxygen compound and hydrogen compound density induced by gravity wave propagation are simulated. The results indicate that when a gravity wave propagates through a mesopause region, even if it does not break, it can influence the background distributions of chemical species. The effect of gravity wave on chemical species at night is larger than in daytime.     

Linear nonstationary optical dimensional resonances in atomic nanostructures

The existence of linear nonstationary optical resonances in a diatomic nanostructural object with a dipole-dipole atomic interaction has been proved. A new solution to the joint system of modified Bloch optical equations and nonlocal field equations is obtained for time intervals much shorter than the times of phase and energy relaxation. Formulas for effective polarizabilities of the object’s atoms, which have a set of dimensional resonances, are derived. The frequencies of these resonances significantly differ from the eigenfrequencies of the object’s atoms, and their properties depend on the interatomic distance, light-pulse duration, initial atomic inversions, and the orientation of the object’s axis relative to the direction of incidence of the external light wave.     

Radiation of a charge moving over the diffraction grating

The states of a charged particle with a finite free path are determined in the field of a resonant electromagnetic wave. The exact resonance conditions, the modulation and beam instability mechanisms, the charge and current densities (Ohm's law) are obtained for the collisionless beam of resonance particles. Quantum theory of radiation is developed for the resonant adiabatic interaction between a particle and a wave taking into account the interaction with a constant magnetic field induced at the grating surface by the charge and nonresonant waves. The radiation power, the spectrum, and the range of generated frequencies are determined. The results obtained can be used in the plasma and solid-state theories and in electronics.     

Generation of nonclassical states of a field with frequency-dependent squeezing

The generation of nonclassical states of light with specified frequency-dependent squeezing by way of introducing a correlation between the phase and amplitude of the input field is considered. Three schemes for measuring amplitude fluctuations of the input beam, based on a nondemolition measurement of the intensity in a nonlinear cubic crystal, the effect of light rectification in a quadratic optical crystal, and the use of a non-degenerate optical parametric oscillator, are proposed. The maximum possible value of noise suppression is estimated for each scheme. The prospects for practical realization of the proposed method for generation of frequency-dependent squeezed states are discussed.     

Application of quasi-steady-state plasma streams for simulation of ITER transient heat loads

The paper presents experimental investigation of energy characteristics of the plasma streams generated with quasi—steady—state plasma accelerator QSPA Kh-50 and adjustment of plasma paramenters from the point of view its applicability for simulation of transient plasma heat loads expected for ITER disruptions and type I ELMs. Possibility of generation of high-power magnetized plasma streams with ion impact energy up to 0.6 keV, pulse length 0.25 ms and heat loads varied in wide range from 0.5 to 30 MJ/m² has been demonstrated and some features of plasma interaction with tungsten targets in dependence on plasma heat loads are discussed.     

Hydrophobicity-induced drying transition in alkanethiol self-assembled monolayer—water interface

During the course of our investigation of the electron transfer properties of some redox species through highly hydrophobic long chain alkanethiol molecules on gold in aqueous and non-aqueous solvents, we obtained some intriguing results such as unusually low interfacial capacitance, very high values of impedance and film resistance, all of which pointed to the possible existence of a nanometer size interfacial gap between the hydrophobic monolayer and aqueous electrolyte. We explain this phenomenon by a model for the alkanethiol monolayer—aqueous electrolyte interface, in which the extremely hydrophobic alkanethiol film repels water molecules adjacent to it and in the process creates a shield between the monolayer film and water. This effectively increases the overall thickness of the dielectric layer that is manifested as an abnormally low value of interfacial capacitance. This behaviour is very much akin to the ‘drying transition’ proposed by Lum, Chandler and Weeks in their theory of length scale dependent hydrophobicity. For small hydrophobic units consisting of apolar solutes, the water molecules can reorganize around them without sacrificing their hydrogen bonds. Since for an extended hydrophobic unit, the existence of hydrogen bonded water structure close to it is geometrically unfavourable, there is a net depletion of water molecules in the vicinity leading to the possible creation of a hydrophobic interfacial gap.