FIR Stark spectroscopy on optically pumped CH3OH laser

An extensive theoretical and experimental analysis of the absorption and emission spectrum of a CH₃OH FIR-laser excited by a conventional CO₂ laser is presented. Particular interest is devoted to the Stark shifts of the pump and lasing lines and to the electric field dependence of the Fir-laser output of the various lines. The offsets with respect to the exciting radiation and the Stark shifts of the IR absorption (pump) lines are measured by means of the transferred Lamb dip technique. The theoretical behaviours of the Stark patterns are calculated for several choices of the quantum numbers and selection rules involved in the transitions. A large variety of experimental results are reported and compared to theory. Non-linear Stark shifts have been observed for the 37.5m FIR laser line and for the IR-pump transitions excited by the 9-P(38) and 10-R(38) CO₂ laser Lines. Line assignments are proposed and new FIR laser lines are reported.     

Optical properties of YBaCuO thin films at Far-Infrared monochromatic light

By using monochromatic sources of radiation we measured the reflectivity and transmission vs temperature behavior of YBaCuO thin film in the Far Infrared region in the range 300-20 K. A smooth change of optical properties is observed from critical temperature down to 40 K with an evident reduction of the losses for all the frequencies we examined. To analyze the use of YBaCuO films as semireflecting elements in submillimeter devices we made a preliminary study of the optical properties of the substrate in the same conditions. The permanence of the sample in a superconducting phase can be deduced from its room-temperature transmittance, as it changes drastically if some degeneracy occurs in the film.Partially supported by the National Research Council of Italy, CNR, under the Progetto Finalizzato Superconductive and Cryogenics Technologies