Tailoring Pore Structure and Morphologies in Covalent Organic Frameworks for Xe/Kr Capture and Separation

As a rising star among porous solid materials, covalent organic frameworks(COFs) with excellent properties including but not limit to facilely controllable structure, high porosity, and multi-chemical functionality represent significant potential for efficient ¹²⁷Xe/⁸⁵Kr capture and separation. In this study, through tuning the length of the organic ligands, two-dimensional(2D) COF mate-rials with identical connection group but different pore properties, denoted as ATFG-COF and TpPa-COF with AA-stacking model and TpBD-COF with AB-stacking model were synthesized and tested for Kr and Xe adsorption for the first time. Adsorption measurements indicate that the narrower pore apertures and higher porosity are conducive for COF materials to capture Xe and Kr. Furthermore, the Henry's constant, isosteric heat of adsorption(Q_st), and ideal adsorbed solution theory(IAST) selectivity of ATFG-COF, the pore size of which is closest to the kinetic diameter of the Xe atom(0.41 nm) among 2D COF materials, were carried out based on the single component sorption isotherms. The results illustrate that the high isosteric heat values of Xe/Kr adsorption on ATFG-COF are 25 and 16 kJ/mol at room temperature, respectively. Henry's law predicts that the selectivity factor of Xe to Kr is 6.07, consistent with the adsorption selectivity(ca. 6) calculated based on the IAST.     

键合氢对GDa—Si:H薄膜光致发光性质的影响

测量了在不同衬底温度下制备的GDa-Si:H膜的光致发光谱和光吸收谱。实验发现键合氢含量的增加导致光致发光峰强度、发光峰能量、发光带半宽度、Stokes位移和热淬灭的增大。由此导出:(1)键合氢不仅能消除无辐射复合中心,而且能产生辐射复合中心;(2)随着键合氢含量的增加电子-声子相互作用增强,带尾宽度缓慢变窄。 关键词：     

HL-1装置等离子体特性的初步研究

HL-1装置在环向磁场2.3T下运行,获得135kA平衡稳定等离子体,平顶时间160ms。实验表明,环向磁场杂散分量约为纵场的万分之一,导体壳和平衡场基本上能保证等离子体的平衡。观察到的电子温度约500eV,平均电子密度2.8×10~(13)cm~(-3),能量约束时间10ms,有效电荷数小于3,最低稳定运行安全因子2.5,最长放电持续时间1040ms。在对MHD稳定性进行观察的基础上,确定了稳定运行区域;极限密度服从Murakami定标律。     

A RECURSION THEORY STUDY OF THE ELECTRONIC STRUCTURE OF METALLIC SUPERLATTICES

We illustrate that the recursion method is useful in the study of the electronic structure of metallic superlattices.It reduces considerably the amount of computational works,and gives,nevertheless,fairly satisfactory densities of states.     

光子加速器的理论研究

研究了光子加速器(即利用等离子体中的朗谬尔波实现光脉冲频率上转换)所涉及的基本物理问题.文中导出了在存在朗谬尔波的条件下,光脉冲频率对于等离子体本底密度及电子密度扰动的依赖关系,并就最大频率转换、光脉冲俘获、波的加速位相(accelerating phase)以及位相滑动(phase slippage)效应进行讨论.     

Phase Diagram of Random Field Spin-S Ising Model with a Transverse Field

Random field spin-S Ising model with a transverse field has been studied by making use of the pair approximation with the discretized path-integral representation, and an analytical expression of second-order phase transition is derived for all the symmetric probability distributions of (longitudinal) random fields. The phase diagrams at T = 0 are obtained, and the conditions for existence of tricritical points are examined for an arbitrary number of nearest-neighbor spins.     

Hopfield神经网络模型的恢复特性

通过引入不同概率的双峰无规神经激活阈分布,来考虑对神经网络“记忆”恢复特性的影响,结果表明即使储存模式数超过孤立Hopfield模型的临界值α_c时系统仍然能成功地恢复储存信息。 关键词：     

武定县地域功能区划分方法研究

县级功能区划作为综合区划,既是落实省级主体功能区规划,又是编制县域空间发展规划的基础。首先探讨县级功能区划方法,然后以武定县为例运用主导因素法划分出城镇区、资源开发区、开发预留区、农业区、生态区等功能区。研究发现：(1)县级功能区划既要考虑县域资源环境本底与发展愿景,又要兼顾省级主体功能区对本县定位;(2)区划评价单元须考虑基础数据可获得性及各单项指标评价单元的统一;(3)指标体系选取以省级主体功能区划指标体系为参照,具有可行性;(4)单一区划方法无法合理区划县级各功能区单元,需多种方法相结合。     

以苯丙氨酸为例刍议芳香族氨基酸的生物合成机理

从磷酸烯醇式丙酮酸和4-磷酸赤藓糖为始探讨了3种芳香族氨基酸合成代谢共享的分支酸合成途径,并以苯丙氨酸为例从多学科角度讨论分析其合成代谢的独特性.通过多学科角度展示了生物体内不同代谢路径之间的关联及相似性,旨在展示一种教学新模式,帮助学生建立起跨学科内容的学习及归纳方法.