两类记录值之和的中心极限定理

该文给出了Ｌｏｇｉｓｔｉｃ分布纪录值序列部分和的中心极限定理；对于Ｐａｒｅｔｏ分布纪录值序列的部分和T_n，获得了ｌｎT_n的中心极限定理．这一工作不仅具有概率论的极限理论方面的研究价值，而且在金融、保险等领域也具有相当重要的应用前景．     

First Total Synthesis of 12-Hydroxy-13-methylpodocarpa-9, 11, 13-trien-3-one

12-Hydroxy-13-methylpodocarpa-9, 11, 13-trien-3-one 9 was isolated from the twigs ofCroton salutaris1. Many diterpenes exhibit significant bioactivities, such as antibac-terial and antitumour and 9 has a rare structure. In order to study the relationshipb…     

Synthesis and light emitting properties of polyacetylenes having pendent fluorene groups

Five novel fluorene‐containing polymers, poly[(9,9‐dimethylfluoren‐2‐yl)acetylene] ( PFA1 ), poly[(1‐pentyl‐2‐(9,9‐dimethylfluoren‐2‐yl)acetylene) ( PFA2 ), poly[1‐decyl‐2‐(9,9‐dimethylfluoren‐2‐yl)acetylene] ( PFA3 ), poly[1‐phenyl‐2‐(9,9‐dimethylfluoren‐2‐yl)acetylene] ( PFA4 ), and poly[1‐(3,4‐difluorophenyl)‐2‐(9,9‐dimethylfluoren‐2‐yl)acetylene] ( PFA5 ) were synthesized by the polymerization of the corresponding fluorene‐substituted acetylenic monomers ( M1–M5), using WCl₆, MoCl_5, and TaCl₅ as catalysts and n‐Bu₄Sn as a cocatalyst. The synthesized polymers were thermally stable and readily soluble in common organic solvents. The degradation temperatures for a 5% weight loss of the polymers were ∼352–503 °C under nitrogen. PFA1–PFA5 show emission peaks from 402 to 590 nm. Besides, their electroluminescent properties were studied in heterostructure light‐emitting diodes (LEDs), using PFA2–PFA5 as an emitting layer. The PFA5 device revealed an orange‐red emission peak at 602 nm with a maximum luminescence of 923 cd/m² at 8 V. A device with the ITO/PEDOT/ a mixture of PFA2 (98 wt %) and PFA5 (2 wt %)/Ca/Al showed near white emission. Its maximum luminance and current efficiency are 450 cd/m² at 15 V and 1.3 cd/A, respectively. © 2005 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 519–531, 2006     

Preparation and characterization of rigid poly(vinyl chloride)/MMT nanocomposites. II. XRD,morphological and mechanical characteristics

A Haake torque rheometer equipped with an internal mixer is used to study the influence of the amount of sodium montmorillonite (Na⁺‐MMT) and organically modified MMT (O‐MMT) on X‐ray diffraction (XRD), morphology, and mechanical characteristics of rigid poly (vinyl chloride) (PVC)/Na⁺‐MMT and PVC/O‐MMT nanocomposites, respectively. Results of XRD and transmission electron microscopy (TEM) indicate that MMT is partially encapsulated and intercalated in the rigid PVC/Na⁺‐MMT nanocomposites. However, results of XRD and TEM show MMT is partially intercalated and exfoliated in the rigid PVC/O‐MMT nanocomposites. Tensile strength, yield strength, and elongation at break of the rigid PVC/MMT nanocomposites were improved simultaneously with adding 1–3 wt % Na⁺‐MMT or O‐MMT with respect to that of pristine PVC. However, the addition of Na⁺‐MMT or O‐MMT should be kept as not more than 3 wt % to optimize the mechanical properties and the processing stability of the rigid PVC/MMT nanocomposites. SEM micrographs of the fractured surfaces of the rigid PVC/Na⁺‐MMT and PVC/O‐MMT nanocomposites both before and after tensile tests were also illustrated and compared. © 2006 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 44: 2145–2154, 2006     

基于反相位脉冲技术的生物组织谐波成像研究

理论及实验研究了反相位脉冲技术在生物组织二次谐波成像中的应用。结合有限振幅声波的非线性传播理论,从理论上证明了反相位脉冲技术可有效抑制基波信号,同时二次谐波信号增强两倍,轴向及径向声场的实验测量结果基波被抑制30～50dB,二次谐波提高6dB,与理论相符。建立了相应的成像系统,对若干生物离体组织进行了基于反相位脉冲相位技术的二次谐波成像,并与常规的基波及二次谐波图像对比,进一步证明了该技术能有效提高图像的对比度和清晰度。     

13.5—14.6MeV中子能区锗的同位素反应截面的测量

报道了在13.5—14.6MeV中子能区用活化法测得的⁷⁶Ge(n,2n)⁷⁵Ge, ⁷⁰Ge(n,2n)⁶⁹Ge, ⁷⁰Ge(n, p)⁷⁰Ga, ⁷²Ge(n,p)⁷²Ga, ⁷³Ge(n,p)⁷³Ga, ⁷²Ge(n,α)^69mZn和⁷⁴Ge(n, α)^71mZn的反应截面值. 中子注量用⁹³Nb(n,2n)^92mNb反应截面得到. 单能中子由T(d,n)⁴He反应获得. 同时还列举了已收集到的文献值以作比较.     

Design of Two-Dimensional Photonic Crystal Edge Emitting Laser for Photonic Integrated Circuits

An edge emitting laser based on two-dimensional photonic crystal slabs is proposed. The device consists of a square lattice microcavity, which is composed of two structures with the same period but different radius of air-holes, and a waveguide. In the cavity, laser resonance in the inner structure benefits from not only the anomalous dispersion characteristic of the first band-edge at the M point in the first Brillouin-zone but also zero photon states in the outer structure. A line defect waveguide is introduced in the outer structure for extracting photons from the inner cavity. Three-dimensional finite-difference time-domain simulations apparently show the in-plane laser output from the waveguide. The microcavity has an effective mode volume of about 3.2（λ/nslab）^3 for oscillation mode and the quality factor of the device including line defect waveguide is estimated to be as high as 1300.     

Retracted: Determination of scutellarin isomer,a predominant metabolite of scutellarin,in human plasma by HPLC/tandem mass spectrometry and its application to a pharmacokinetic study in Chinese healthy volunteers

Retraction: The following article from Biomedical Chromatography, “Determination of scutellarin isomer, a predominant metabolite of scutellarin, in human plasma by HPLC/tandem mass spectrometry and its application to the pharmacokinetic study in Chinese healthy volunteers” by Chun‐hua Xia, Yu‐qing Xiong, and Guang‐ji Wang, published online on 21 June 2007 in Wiley Interscience (www.interscience.wiley.com/journal/bmc), has been retracted at the authors' request.     

LIMITING BEHAVIOR OF UNIFORM RECURSIVE TREES

The authors consider the limiting behavior of various branches in a uniform recursive tree with size growing to infinity.The limiting distribution ofζ_(n,m),the number of branches with size m in a uniform recursive tree of order n,converges weakly to a Poisson distribution with parameter 1/m with convergence of all moments.The size of any large branch tends to infinity almost surely.     

Chemoselective Catalytic Hydrogenation of α,β-Unsaturated Ketones and α,β-Unsaturated Carboxylic Esters

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