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131.
Two series of size‐fractionated combusted residues, a bag‐house ash and a scrubber residue, from a municipal solid waste incinerator (MSWI) were prepared and extracted by means of sequential chemical extraction (SCE) procedures proposed by Tessier. Concentrations of water‐soluble phase, exchangeable phase, carbonated phase, Fe/Mn oxide phase, organic matter phase, and residual phase bound amphoteric metals (Pb and Zn) were obtained, and have been compared with those of single batch extraction of toxic characteristic leaching procedure (TCLP). In each size fraction of baghouse ash or scrubber residue, lead or zinc shows a common phenomena that the TCLP value is always lower than the content of the water‐soluble fraction. For lead, baghouse ash has a significant size‐dependent distribution on the water‐soluble phase to perform a size‐dependent test of lead in the TCLP test. The zinc TCLP data having less size dependence might be due to that neither the baghouse ash nor the scrubber residue has a size‐dependent distribution on the water‐soluble zinc phase. 相似文献
132.
ThefascinatingsbocturesandpropertiesoffullereneshaveoPeneduPanewfieldofchendstry.Inparticular,F.Wudletal.l'2haveshownthatwatersofubleC6ocomPoundsinhibittheHITVen-zymesprotease(HIVP)andreversetranscriPtase(HIVRT).IthasbeenafocusofstUdytoinvestigatethebiologicalactivitiesofthesenovelsubstances.Fortheirpossiblemedicaluses,tolinkC6omoleculetonaturalProductssuchassugars,pephdes,amioacides,andsoonisanimPortantmethodinthisfield.Vasella3reportedthefirstglucosidederivativeofC6o'InthispaPer,w… 相似文献
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Kan‐Yi Pu Yi Chen Xiao‐Ying Qi Chun‐Yang Qin Qing‐Quan Chen Hong‐Yu Wang Yun Deng Qu‐Li Fan Yan‐Qin Huang Shu‐Juan Liu Wei Wei Bo Peng Wei Huang 《Journal of polymer science. Part A, Polymer chemistry》2007,45(16):3776-3787
In this contribution, we demonstrate a new effective methodology for constructing highly efficient and durable poly(p‐phenyleneethynylene) (PPE) containing emissive material with nonaggregating and hole‐facilitating properties through the introduction of hole‐transporting blocks into the PPE system as the grafting coils as well as building the energy donor–acceptor architecture between the grafting coils and the PPE backbone. Poly(2‐(carbazol‐9‐yl)ethyl methacrylate) (PCzEMA), herein, is chosen as the hole‐transporting blocks, and incorporated into the PPE system as the grafting coils via atom transfer radical polymerization. The chemical structure of the resultant copolymer, PPE‐g‐PCzEMA, was characterized by NMR and gel permeation chromatography, showing that the desirable copolymer was obtained with the narrow polydispersity. The increased thermal stability of PPE‐g‐PCzEMA was confirmed by thermogravimetric analysis and differential scanning calorimetry along with its macroinitiator. The optoelectronic properties of this copolymer were studied in detail by ultraviolet‐visible absorption, photoluminescence emission and excitation spectra, and cyclic voltammogram (CV). The results indicate that PPE‐g‐PCzEMA exhibits the solid‐state luminescent property dominated by individual lumophores, and also the energy transfer process from the PCzEMA blocks to the PPE backbone with a relatively higher energy transfer efficiency in the solid‐state compared to that of the solution state. Additionally, the hole‐injection property is greatly facilitated due to the presence of PCzEMA, as confirmed by CV profiles. All these data indicate that PPE‐g‐PCzEMA is a good candidate for use in optoelectronic devices. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 3776–3787, 2007 相似文献
135.
本文以3-甲基苯甲酸为配体,合成了与三价稀土镧离子的固体配合物LaL3.H2O,并对该配合物进行了元素分析,红外光谱,UV光谱,TG-DTA,HNMR等的测试与表征。该配合物属螯合双齿配位。 相似文献
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本文考虑积分方程的ε复杂性问题.问题的ε复杂性是在误差不超过ε的前提下解决问题所需的最小成本.对某些具各向异性核与自由项的第二类Fredholm方程,求得了ε复杂性的精确阶.同时,找到了解决该问题具最小成本的算法. 相似文献
139.
该文给出了Logistic分布纪录值序列部分和的中心极限定理;对于Pareto分布纪录值序列的部分和T_n,获得了lnT_n的中心极限定理.这一工作不仅具有概率论的极限理论方面的研究价值,而且在金融、保险等领域也具有相当重要的应用前景. 相似文献
140.
Cheng Lu ZHANG Xiao Lei ZHU Ying Ge MA Li Wei ZOU 《中国化学快报》2006,17(2):163-164
12-Hydroxy-13-methylpodocarpa-9, 11, 13-trien-3-one 9 was isolated from the twigs ofCroton salutaris1. Many diterpenes exhibit significant bioactivities, such as antibac-terial and antitumour and 9 has a rare structure. In order to study the relationshipb… 相似文献