Adhesive-free bonding of Zerodur glass to silicon

This work demonstrates anodic bonding of Zerodur glass having very low co-efficient of thermal expansion (CTE) to Si, Zerodur glass to thermally grown silicon dioxide on silicon and Pyrex glass to Ge. Bonding results, using point cathode contact and plate cathode contact configurations, are discussed. Bonding parameters, i.e. applied dc voltage, temperature and bonding time were determined. Heating and cooling rates for crack-free bonding of Zerodur glass were also determined.     

Preparation of activated carbons from cherry stones by activation with potassium hydroxide

Using cherry stones, the preparation of activated carbon has been undertaken in the present study by chemical activation with potassium hydroxide. A series of KOH-activated products was prepared by varying the carbonisation temperature in the 400-900 °C range. Such products were characterised texturally by gas adsorption (N₂, −196 °C), mercury porosimetry, and helium and mercury density measurements. FT-IR spectroscopy was also applied. The carbons prepared as a rule are microporous and macroporous solids. The degree of development of surface area and porosity increases with increasing carbonisation temperature. For the carbon heated at 900 °C the specific surface area (BET) is 1624 m² g⁻¹, the micropore volume is 0.67 cm³ g⁻¹, the mesopore volume is 0.28 cm³ g⁻¹, and the macropore volume is 1.84 cm³ g⁻¹.     

Magnetooptical investigation of the micromagnetic structure and magnetization processes in Co69Fe4Si12B15 amorphous microwires

Magnetooptical investigation of the micromagnetic structure of Co₆₉Fe₄Si₁₂B₁₅ amorphous microwires 10–50 μm in diameter is carried out. The existence of domains with transverse circumferential magnetization is experimentally demonstrated in the near-surface region of microwires. The dependence of the width of circular domains on the length and diameter of wires is obtained. It is shown that the near-surface micromagnetic structure of amorphous wires is changed under a stretch-induced stress. It is proved that the magnetization reversal of microwires in a longitudinal magnetic field occurs due to the rotation of local magnetization vectors in circular domains.     

Winding Numbers and Average Frequencies in Phase Oscillator Networks

We study networks of coupled phase oscillators and show that network architecture can force relations between average frequencies of the oscillators. The main tool of our analysis is the coupled cell theory developed by Stewart, Golubitsky, Pivato, and Torok, which provides precise relations between network architecture and the corresponding class of ODEs in R^M and gives conditions for the flow-invariance of certain polydiagonal subspaces for all coupled systems with a given network architecture. The theory generalizes the notion of fixed-point subspaces for subgroups of network symmetries and directly extends to networks of coupled phase oscillators. For systems of coupled phase oscillators (but not generally for ODEs in R^M, where M ≥ 2), invariant polydiagonal subsets of codimension one arise naturally and strongly restrict the network dynamics. We say that two oscillators i and j coevolve if the polydiagonal θ_i = θ_j is flow-invariant, and show that the average frequencies of these oscillators must be equal. Given a network architecture, it is shown that coupled cell theory provides a direct way of testing how coevolving oscillators form collections with closely related dynamics. We give a generalization of these results to synchronous clusters of phase oscillators using quotient networks, and discuss implications for networks of spiking cells and those connected through buffers that implement coupling dynamics.     

Electronic spectra of cationic forms of meso-tetrapropylporphin in a nanoporous silicate gel matrix

We have studied the fluorescence and fluorescence excitation spectra at 300 K, 77 K, and 4.2 K for silicate gel matrices colored with meso-tetrapropylporphin by impregnation of the matrix with a solution of the pigment. Comparison of the data obtained with the absorption spectra in acidified solutions and analysis of the low-temperature fine-structure vibronic spectra, and also taking into account data obtained earlier for octaethylporphin in a xerogel showed formation of two cationic forms of meso-tetrapropylporphin in the gel matrix: the short-wavelength form has a dicationic structure, while the long-wavelength form has a monocationic structure. We have traced out the correlations of the vibrational structure in the spectra of the dicationic form with data for the porphin dication, and we have drawn a number of conclusions concerning the normal vibrational modes that are active in the vibronic fluorescence and absorption spectra of the studied cationic forms. Using the AM1 semiempirical quantum chemical method, we optimized the geometry of the mesotetrapropylporphin dication: the most stable of the possible conformers is the dication structure with saddleshaped macrocycle nonplanarity. __________ Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 73, No. 4, pp. 453–461, July–August, 2006.