On the interpretation of the RHEED intensity oscillations during the growth of vicinal faces

A quantitative treatment of the crystallization kinetics in MBE growth of vicinal surfaces results the relation l ²=2D _sK between the surface diffusion coefficient D _s, the time for a monolayer deposition and the interstep distance l at which the RHEED intensity oscillations disappear. The correction factor K depends on the size and the energy of the two-dimensional critical nucleus and it is estimated to be smaller than 10^–2. The currently used interpretation of the RHEED intensity oscillations ignores the correction factor K and, therefore, the calculated values of D _s are several orders of magnitude smaller than its real values. The surface transport during the time of growth interruption is discussed in connection with the tendency to three dimensional growth at every second interface (where a deposition of the material with strong intermolecular bonds starts) of a small period superlattice.     

Upper-Branch Instability of Flow in Pipes of Large Aspect Ratio with Three-Dimensional Nonlinear Viscous Critical Layers

We consider the upper-branch neutral stability of flow in pipesof large aspect ratio, basically extending the work of F. T.Smith to the nonlinear regime. The inclusion of weak nonlinearityleads to an eigenproblem whose solution depends on the propertiesof three-dimensional nonlinear critical layers. Two specialcases are considered. The first is for very small amplitude perturbations, where R is a Reynolds numberbased on the height of the tube and which is assumed large.Then a fully analytical solution of the three-dimensional criticallayers is possible, from which the linear results of Smith maybe deduced. The second case studied is that of flow in a rectangularpipe, where a solution of the nonlinear critical layer problemcan be obtained. Further analysis of neutral modes in this lattercase suggests the possible existence, inter alia, of neutralmodes for finite aspect ratio tubes. These modes depend on thescaled amplitude and have O(1) wavespeeds.     

On the dynamics of cosmological particle production

The time evolution of the particle number density and spectrum of massive scalar particles, coupled conformally to a classical Friedman-Robertson-Walker gravitational field is followed numerically. Not only for a pure radiation cosmos, but also for one with an inflationary interlude, the density of particles produced remains constant in time. This results in a constant equivalent temperature scale up to the Compton time of the massive particles, and opens the possibility that during a sufficiently long inflation the energy density of the particles produced can exceed that of the radiation background.     

A modified Tolman mass-energy formula

A modified Tolman mass (energy) formula is derived for spherically symmetric, time-independent systems. In the absence of surfaces of discontinuity, the modified formula has, in contradistinction to the original formula, the following desirable properties: (i) it always gives the correct mass of the system as a whole; (ii) it always gives the correct mass of any portion of the system which is surrounded by vacuum; and (iii) it remains invariant under a rescaling of the time coordinate of the formt Ct, C=constant. In the presence of surfaces of discontinuity the Tolman mass formula is further modified by the addition of the Israel mass associated with each surface. The resulting formula also has the above three properties. A new exact solution of Einstein's equations which is well behaved everywhere and is, in a sense, a generalization of Florides' new interior Schwarzschild solution is also presented.This result explains why, takingT ₁ ¹ =[C] in Section 2, we were able to obtain a solution free of surfaces of discontinuity.     

Variation of the instability index on stationary curves of elliptic equations depending on a parameter

The set of solutions of the equation A(u, )=0 in the case of general position consists of smooth curves. Solutions of a quasilinear elliptic equation with large instability index are constructed and an estimate obtained for the number of turning points of the solution curves.Translated from Trudy Seminara imeni I. G. Petrovskogo, No. 12, pp. 47–58, 1987.     

Index formulas for generalized Wiener-Hopf operators and boson-fermion correspondence in 2N dimensions

The kernels of operators associated with special chiral gauge transformations (kinks) in the 2N-dimensional Dirac theory are explicitly determined. The result is used to obtain index formulas for Fredholm operators corresponding to continuous chiral gauge transformations. Moreover, the Fock space quadratic forms corresponding to the kinks are proved to converge to the Dirac field as the kink size goes to zero. It is also shown that forN 1, 2(mod 4) the Majorana field can be reached in a similar fashion.Work supported by the Netherlands Organisation for the Advancement of Research (NWO)     

Disorder arising from the location of enantiomers in a twist-boat structure: 2,6-trans-2,4,6-tris(trichloromethyl)-1-oxa-3,5-dithian

Crystals of the title compound are orthorhombic, Pca2₁;a=27.586(4),b=10.509(3),c=11.080(2) Å,V=3212(1) ų,Z=8. The structure was solved by direct methods, from data collected at room temperature on an Enraf-Nonius CAD4 diffractometer, and refined by full-matrix least squares to a finalR value of 0.055 using 2043 reflections. One of the two independent molecules in the asymmetric unit is disordered. The disorder is manifested mainly between the oxygen atom and one sulfur atom and is caused by opposite enantiomers occupying corresponding positions in different unit cells. The endocyclic torsion angles in both independent molecules are very similar but the disposition of the heteroatoms on the twist-boat framework is different in the two molecules. Site occupancy of the two models on this framework in the disordered molecule is in the ratio 2179 with the smaller proportion being very similar to the ordered molecule and the remainder similar to that found in the normal molecule oftrans-4-chloro-2,4,6-tris(trichloromethyl)-1-oxa-3,5-dithian (Irving and Irving, 1988).     

Effect of the flow regime in an underexpanded jet issuing into a subsonic counterstream on the pressure distribution on a body

The pressure distribution on a cone with a half-angle =75°, from which a single central underexpanded jet issues into a subsonic counterstream, has been experimentally investigated. The effect of the flow regime in the jet on the pressure distribution is demonstrated. Generalized relations for the pressure on the body are obtained for various jet-flow momentum ratios J and flow Mach numbers M = 0.35–0.9; the Mach number M_a at the exit of the conical nozzle with half-angle _a=10° was equal to 2.9. The working medium of the jet and the flow was air with stagnation temperatures T_0a = T₀ 260–265°K. The ratio of the nozzle outlet radius to the radius of the maximum cross section of the cone _a/R_M=0.1.Translated from Izvestiya Akademii Nauk SSSR, Mekhanika Zhidkosti i Gaza, No. 1, pp. 182–185, January-February, 1988.     

Crystal and molecular structure of 1R,3S,5S,7R,10R-3,6,6,10,14-Pentamethyltricyclo[10.3.0.05,7]pentadeca-11,14-diene-1, 10-dihydroxy-2,13-dione (Japodagrol), C20H28O4

A new cytotoxic macrocyclic diterpenoid named Japodagrol, C₂₀H₂₈O₄, has been isolated from the ornamental plantJatropha podagrica, family Euphorbiaceae, grown in Nigeria. The structure of the title compound, C₂₀H₂₈O₄, was solved by X-ray analysis.M _r =332.44, monoclinic space groupC2,a=23.285(4),b=6.5105(12),c=12.505(3) Å,=98.504(17),V=1874.8 ų,Z=4,D _c =1.178 Mg/m³. CuK radiation (graphite crystal monochromator, =1.54184 A), (CuK)=6.13 cm^–1,F(000)=720,T=290 K. Final conventionalR factor=0.035,R _w =0.038 for 3349 observed reflections. The structure was solved with the programDirdif. The 5-membered ring is closed to a half-chair form. The compound contains inter- and intramolecular hydrogen bonds.     

Intra- versus intermolecular hydrogen bonds in salicylamide derivatives

The crystal structures, solid-state infrared patterns, and thermal properties of two polymorphs of 4-nitrosalicylanilide are presented. In both polymorphs, intramolecular hydrogen bonds are found between the phenol oxygen and the amide proton, and intermolecular hydrogen bonds are found between the amide carbonyl oxygen and the phenol proton. These hydrogen bond patterns are compared to those found in other known salicylamide derivatives and an analysis is given of the factors contributing to preferences for intra- or intermolecular hydrogen bonds in these structures. Crystal data: polymorph, orthorhombic,Pbca,a=11.003(4),b=27.959(7),c=7.622(5) Å,Z=4,V=2345(3) ų, andR=0.038 (1351 reflections); polymorph, monoclinic,P2₁/a,a=28.36(1),b=11.64(1),c=7.293(8) Å,=90.68(6)°,Z=8,V=2408 ų, andR=0.043 (2425 reflections).