CuPc molecules adsorbed on Au(1 1 0)-(1 × 2): growth morphology and evolution of valence band states

We present the growth morphology, the long-range ordering, and the evolution of the valence band electronic states of ultrathin films of copper phthalocyanine (CuPc) deposited on the Au(1 1 0)-(1 × 2) reconstructed surface, as a function of the organic molecule coverage. The low energy electron diffraction patterns present a (5 × 3) reconstruction from the early adsorption stages. High-resolution UV photoelectron spectroscopy data show the disappearance of the Au surface states related to the (1 × 2) reconstruction, and the presence of new electronic features related to the molecule-substrate interaction and to the CuPc molecular states. The CuPc highest occupied molecular orbital gradually emerges in the valence band, while the interface electronic states are quenched, upon increasing the coverage.     

Gamow Vectors in Exactly Solvable Models

Through two examples: the Friedrichs model and a particular case of central potential scattering, we illustrate the way of constructing Gamow vectors.     

Van der waals waves in free-surface liquids

It is shown that, along with gravity waves, surface and internal waves caused by van der Waals forces may exist in a liquid with a horizontal free surface. A dispersion relation is found by using the stepwise approximation for the coefficients of a wave equation derived for these waves. The surface waves are similar to surface gravity waves in dispersion and amplitude distribution but differ in frequency by several orders of magnitude. Another sequence of roots in the spectrum corresponds to internal van der Waals waves that have an upper frequency bound and the dispersion law typical of a multimode waveguide.     

1,1,3-Trimethyl-3-phenylindan as a Luminescent Additive to a Plastic Scintillator Based on Poly(methyl Methacrylate)

The luminescence and scintillation properties of poly(methyl methacrylate) containing 1,1,3-trimethyl-3-phenylindan were studied.     

Multilayer optics for XUV spectral region: technology fabrication and applications

We present research investigations in the field of multilayer optics in X-ray and extreme ultra-violet ranges (XUV), aimed at the development of optical elements for applications in experiments in physics and in scientific instrumentation. We discuss normal incidence multilayer optics in the spectral region of “water window”, multilayer optics for collimation and focusing of hard X-ray, multilayer dispersing elements for X-ray spectroscopy of high-temperature plasma, multilayer dispersing elements for analysis of low Z-elements. Our research pays special attention to optimization of multilayer optics for projection EUV-lithography (ψ-13nm) and short period multilayer optics.     

Lattice parameter and luminescence properties of europium activated yttrium oxide

Samples of yttrium oxide doped with trivalent europium have been prepared by ceramic techniques, under different synthesis conditions; barium chloride (BaCl₂) and sodium tetraborate (Na₂B₄O₇) were tested as flux. The improvement of luminescence properties in dependence on substitution of Eu³⁺ for Y³⁺ in the host lattice, under electron and UV excitations is demonstrated. The lattice parameter as a quantitative assessment of activator incorporation degree is proposed. The obtained results are discussed with respect to the employed processing method.     

Effects of tributyltin(IV) chloride on the gametes and fertilization of Ascidia malaca (Ascidiacea: Tunicata)

Ascidia malaca gametes before fertilization incubated in 10^?5 or 10^?7 M solutions of tributyltin(IV) chloride, TBTCl, for 3 h appear highly damaged under transmission electron microscopy observation. Also, the fertilization process is affected by the compound: the damaged spermatozoa are present in the vitelline coat and the egg does not cleave. An increase of microbodies, structurally similar to peroxisomes, have been detected in the egg peripheral cytoplasm, probably in relation to their role in alleviating damage to some cellular components. The results have shown that the reproduction of ascidians under unfavourable environmental conditions is prevented. Copyright © 2003 John Wiley & Sons, Ltd.     

An Average-Stretch Full-Network Model for Rubber Elasticity

Two constitutive models that are based on the classical non-Gaussian, Kuhn-Grün probability distribution function are reviewed. It is shown that all chains of a network cell structure comprised of a finite number of identical chains in an affine deformation referred to principal axes may have the same invariant stretch, if and only if the chains are oriented initially along any of eight directions forming the diagonals of a unit cube. The 4-chain tetrahedral and the 8-chain cubic cell structures are familiar admissible models having this property. An easy derivation of the constitutive equation for the Wu and van der Giessen full-network model of initially identical chains arbitrarily oriented in the undeformed state is presented. The constitutive equations for the neo-Hookean model, the 3 -chain model, and the equivalent 4- and 8-chain models are then derived from the Wu and van der Giessen equation. The squared chain stretch of an arbitrarily directed chain averaged over a unit sphere surrounding all chains radiating from a cross-link junction as its center is determined. An average-stretch, full-network constitutive equation is then derived by approximation of the Wu and van der Giessen equation. This result, though more general in that no special chain cell morphology is introduced, is the same as the constitutive equation for the 4- and 8-chain models. Some concluding remarks on extensions to amended models are presented.