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951.
952.
R. Kimmich F. Klammler V. D. Skirda I. A. Serebrennikova A. I. Maklakov N. Fatkullin 《Applied magnetic resonance》1993,4(4):425-440
Geometrical restrictions of water diffusion in different aqueous protein systems were studied using two versions of the NMR field gradient technique. The samples were aqueous systems of bovine serum albumin, gelatin and horse myoglobin at concentrations ranging from diluted solutions to almost dry powders being only partly hydrated. Hydrated protein aerogels were produced by the aid of a special preparation procedure and studied in addition. The experiments referred to the, temperature and concentration dependences of the water diffusion coefficient above and below the free-water freezing temperature. The diffusion coefficient within clusters of overlapping hydration shells is reduced by one order of magnitude compared with that of bulk water. Geometrical restrictions manifest themselves (a) by the obstruction effect observed at low protein concentrations, (b) by the topologically two-dimensional diffusion in the network of overlapping hydration shells, (c) by the percolation threshold appearing at about 15%b.w. water and (d) by the anomalous diffusion behaviour concluded from the protein aerogel study. 相似文献
953.
Ablation of an optically homogeneous absorbing medium by scattered pulsed laser radiation 总被引:1,自引:0,他引:1
V. V. Golovlyov R. O. Esenaliev V. S. Letokhov 《Applied physics. B, Lasers and optics》1993,57(6):451-457
We have studied the ablation of an aqueous CuCl2 solution in a pulsed Nd:YAG laser field featuring a speckle-patterned structure characterized by spatial radiation energy fluence fluctuations. This leads to a nonuniform distribution of the energy absorbed in the bulk of the sample being irradiated and causes local overheating centers to form, wherein ablation is observed to take place at laser energy fluences below the threshold value found in experiments with a homogeneous laser beam. This effect should be manifest in the laser irradiation of biotissues which, as a rule, scatter light strongly. 相似文献
954.
A technique is proposed for improving the accuracy of the heat of fusion of semicrystalline polymers by DSC. The results of three commercially available instruments are compared. 相似文献
955.
S. A. J. Wiegers B. Tieke U. Zeitler R. Fletcher A. K. Geim J. C. Maan M. Henini 《Czechoslovak Journal of Physics》1996,46(5):2461-2462
We have investigated the interaction of phonons with a 2DEG in the FQH regime with phonon drag thermoelectric power (TEP). We find that the TEP at filling factors with the same even denominator is identical and at other even denominator filling factors they differ only by a constant. Assuming these states to be Composite Fermions (CF), we can explain our observations by extending a zero magnetic field theory for phonon drag to the CF-phonon interaction. This analysis is further corroborated by the observed T4 dependence of the CF TEP. 相似文献
956.
We generalize literature data and our own experimental data on using 1,3-dipolar cycloaddition reactions for synthesis of fullerene C60 derivatives containing annelated heterocyclic moieties.M. V. Lomonosov Moscow State University, Moscow 119899, Russia. Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 3, pp. 291–297, March, 1998. 相似文献
957.
Summary X-ray reflectivity may be used to determine the internal structure of thin polymer films. An electron density difference of 10% for polystyrene and polyisoprene is sufficient to distinguish between a random distribution of lamellae, complete orientation parallel to the substrate surface and a surface induced formation of lamellae. The disappearance of the lamellar Bragg-peaks, with heating of the film, shows the transition into the disordered state. 相似文献
958.
Thermally induced phase conjugation by degenerate four-wave mixing in solutions of Rhodamine 6G in ethanol in the weak absorption region, low-reflectivity regime, and nonosecond time domain is reported. Evidence of oscillatory acoustic modes in the nonlinear medium is presented and existing theories are shown to explain satisfactorily the experimental results. 相似文献
959.
G. Baldsiefen H. Hübel W. Korten U. J. van Severen J. A. Cizewski N. H. Medina D. R. Napoli C. Rossi Alvarez G. Lo Bianco S. Signorelli 《Zeitschrift für Physik A Hadrons and Nuclei》1996,355(1):337-338
High-spin states in196Pb have been populated using the reaction170Er(30Si,4n). The previously observed shears bands in this nucleus have been extended and some of their transitions have been reordered. They now form regular bands with band crossings. One of the bands splits into two pathways at high spin. 相似文献
960.
The X-ray patterns for the nematic phase in a series of side-on fixed polysiloxanes show different kinds of diffuse elements which imply complex short range ordering. A systematic structural study of the evolution of the patterns versus two molecular parameters, namely the spacer length and the length of the terminal aliphatic tails, suggests the possible occurrence of a smectic C phase for certain values of these parameters. Taking into account these tendencies, new synthesis led to a nematic-smectic C polymorphism observed for the first time in side-on fixed polysiloxanes. 相似文献