Steroids of the spirostan and furostan series of plants of the Allium genus. XXIII. Structure of cepagenin and of alliospirosides C and D from Allium cepa

Two new steroid glycosides of the spirostan series have been isolated from the fruit ofAllium cepa L. (family Liliaceae): alliospirosides C and D. On the basis of chemical transformations and spectral characteristics it has been established that the aglycon of both glycosides is a new steroid sapogenin — cepagenin — having the structure of (24S,25R)-spirost-5-ene-1β,3β,24-triol. Alliospirosides C and D are cepagenin 1-O-[O-α-L-rhamnopyranosyl-(1→2)α-L-arabinopyranoside] and 1-O-[O-α-L-rhamnopyranosyl-(1→2)-O-β-D-galactopyranoside], respectively.     

Chiral β-hydroxycarbonyl compounds based on (−)-menthone: structure and behavior in liquid crystalline systems

It has been established by X-ray structural analysis that 2-(1-biphenyl-4-yl-1-hydroxy)methyl-p-menthan-3-one, one of the products of the reaction of (–)-menthone triisopropyloxytitanium enolate with 4-phenylbenzaldehyde, has a 1R,2S,4S,1S configuration. In crystals, this -hydroxyketone adopts a chair conformation with equatorial methyl and isopropyl groups and an axial 2-(1-biphenyl-4-yl-1-hydroxy)methyl substituent. Unlike the stereoisomeric compound with the 1R,2S,4S,1S configuration, the exocyclic fragment of which has an intramolecular >C=O...H-O- hydrogen bond in crystals and solutions, in the crystals of the 1R,2S,4S,1S ketol under study, molecules are linked by a network of cooperative -O-H...O-H...O-H... hydrogen bonds. Based on the results of molecular mechanics calculations and experimental data of¹H NMR and IR spectroscopy, conformations of molecules of this compound, which are in equilibrium in solution, have been characterized. Based on data on spatial structures of stereoisomeric -hydroxyketones and the character of H-bonds formed by these compounds, the characteristic features of the effect of these chiral alloying additives on the supramolecular structure and macroscopic properties of liquid crystalline systems have been interpreted.The results of a study of stereoselectivity of the reactions of different (–)-menthone enolates with aromatic aldehydes will be published later.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 7, pp. 1247–1255, July, 1995.The work was supported by the Foundation for Basic Research of the State Science and Engineering Committee of Ukraine (Project No. 93-3.2/75).     

Inhibition of highly purified porcine kidney Na,K-ATPase by steroid glycosides of the spirostan and furostan series and a study of structure-activity relationships

A comparative investigation has been made of the action of 14 steroid glycosides of the spirostan and furostan series on highly purified Na,K-ATPase from the medullary layer of porcine kidneys (90% purity in terms of protein). It has been shown that alliospirosides A, B, and D, isolated from the collective fruit ofAllium sepa L., are capable of inhibiting the activity of the Na,K-ATPase The inhibition of the activity of the transport enzyme by alliospirosides A and B is of the uncompetitive type and by alliospiroside D of the competitive type. It is desirable to test alliospirosides on the intact organism.Institute of Physiology, Academy of Sciences of the Republic of Uzbekistan. Institute of the Chemistry of Plant Substances, Academy of Sciences of the Republic of Uzbekistan. Translated from Khimiya Prirodnykh Soedinenii, No. 4, pp. 558–566, July–August, 1993.     

Preparation of composite membranes by means of plasma polymerization of tiophene

The structure and the charge transport properties of poly(ethylene terephthalate) track membranes modified in a thiophene plasma were studied. It was found that polymer deposition on the surface of a track membrane via the plasma polymerization of thiophene results in composite membranes that, in the case of the formation of a semipermeable layer, exhibit conductivity asymmetry—rectifying effect—in electrolyte solutions. It was shown that chemical doping with iodine or photo-oxidation of the polymer layer produced in plasma leads to alteration in the electrochemical properties of plasma-modified membranes.     

On the nonlinear dynamics of elastically interacting asymmetric rigid bodies

A symmetric mathematical model is developed to describe the spatial motion of a system of space vehicles whose structure is represented by regular geometrical figures (Platonic bodies). The model is symmetrized by using the Euler-Lagrange equations of motion, the Rodrigues-Hamilton parameters, and quaternion matrix mathematics. The results obtained enable us to model a wide range of dynamic, control, stabilization, and orientation problems for complex systems and to solve various problems of dynamic design for such systems, including estimation of dynamic loading on the basic structure during maneuvers in space __________ Translated from Prikladnaya Mekhanika, Vol. 42, No. 1, pp. 126–132, January 2006.     

Aerodynamic coefficients of non-conical bodies with a star-shaped transverse cross section

It is well known that, in a supersonic flow, the wave resistance of a body of non-round transverse cross section can be less than the resistance of an equivalent body of revolution with the same length and volume. Starting from 1959, when an exact solution was obtained to the problem of supersonic flow around conical bodies with a pyramidal system of flat discontinuities [1], a number of publications have appeared [2–5] developing this direction. Article [3] pointed out the possibility of achieving a flow with reflected shock waves, normal to the faces of a pyramidal body, by selection of the form of the leading edge. In [6, 7], using the Newton resistance law, bodies were constructed with a transverse cross section of a star-shaped form, having a wave resistance several times less than for an equivalent body of revolution. Just such forms, with certain limitations, have the least wave resistance and retain optimality with respect to the total resistance, taking approximate account of friction forces. Still two more exact solutions were then found, corresponding to flow around star-shaped bodies with regular and Mach interaction between shock waves [8, 9]. At a seminar of the Institute of Mechanics of Moscow State University, G. G. Chernyi advanced the postulation of the existence of certain classes of three-dimensional bodies not having the property of similitude and retaining optimality with respect to determined characteristics, for example, the resistance, the aerodynamic quality, or the torque, and stated partial problems of finding various forms of optimal bodies. Classes of bodies, optimal with respect to the resistance, were obtained within the framework of the Newton theory; the bodies consisted of helical surfaces, as well as of sections of planes and conical surfaces, formed by straight lines connecting the leading edges with a round contour. As a result of calculations using the Newton theory and experimental investigations it was established that bodies with a wedge-shaped nose part, with determined geometric parameters, have greater values of the lifting and of the aerodynamic quality than round cones [10]. The possibility of lowering the resistance and increasing the aerodynamic quality of aircraft by giving them shapes of the transverse cross section in the form of a star [11–14] leads to new investigations of three-dimensional bodies which retain optimality with respect to their aerodynamic characteristics, and are used in conjunction with bodies of revolution. This latter factor is of decisive importance with the use of such configurations as the nose part of the aircraft, or of a multi-step diffusor. The present article gives the results of an experimental investigation of flow around two classes of such bodies: multi-wedge and helical.Translated from Izvestiya Akademii Nauk SSSR, Mekhanika Zhidkosti i Gaza, No. 6, pp. 127–132, November–December, 1974.     

Explosion of the Primer at the End of a Borehole Charge

International Applied Mechanics - The possibilities of controlling the edge effect of the explosion of the conic primer in the lower part of the borehole charge on the level of the bench sole are...     

Magneto-optical recording on the multilayers systems with plasmon excitation

The maximization of the sensitivity of magneto-optical recording media in the short wavelength region is discussed. We show that a combination of the optimized thickness of dielectric and Ag (or CoAg) films can increase the magneto-optic Kerr effect in FeTbCo media by about five times of magnitude in the UV and blue spectral range. It has been shown that the local plasmon excited in the Ag-based films strongly enhances the magneto-optical properties in amorphous FeTbCo magnetic film. The Kerr rotation spectra get the maxima values for the resonance conditions when the local plasmon can be excited in the Ag or CoAg films.     

Raman scattering of light in silicon nanostructures: First-and second-order spectra

First-and second-order Raman scattering spectra in Si nanocrystals have been studied. The shift to lower frequencies and the substantial broadening of first-order Raman scattering lines observed to occur with decreasing nanoparticle size were established to correlate with those in second-order spectra. It is shown that the experimentally observed shifts of peaks and their broadening cannot be predicted based only on the phenomenological model of strong phonon wave function localization. The anharmonic effect originating from the heating of the nanoparticle surface by laser radiation should also be included. Proper fitting of experimental data revealed that the anharmonic constants depend strongly on nanoparticle size. The shape and spectral positions of maxima in second-order Raman scattering spectra have been theoretically described.