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201.
Yakov S. Vygodskii Olga A. Mel'nik Elena I. Lozinskaya Alexander S. Shaplov Inna A. Malyshkina Nadejda D. Gavrilova Konstantin A. Lyssenko Mikhail Yu. Antipin Denis G. Golovanov Alexander A. Korlyukov Nikolai Ignat'ev Urs Welz‐Biermann 《先进技术聚合物》2007,18(1):50-63
Various 1,3‐dialkylimidazolium and tetraalkylphosphonium ionic liquids (ILs), including novel ones, have been studied as reaction media for free radical polymerization of methyl methacrylate (MMA), acrylonitrile (AN) and 1‐vinyl‐3‐ethylimidazolium salts (ViEtIm+)Y?. The influence of IL's nature upon the polymer formulation was investigated. The use of different ionic liquids allows not only to obtain the polymers with high molecular weight (PMMA, up to 5,770,000 g/mol; PAN, up to 735,000 g/mol and poly[(ViEtIm+)Y?], up to 1,130,000 g/mol) in high yields, but also to control the polymerization rate and molecular mass. The physicochemical characteristics, including mechanical properties, thermal stability and heat‐resistance of the obtained polymers were studied in order to compare with those of polymers prepared in a traditional media. It was found that elongation, tensile modulus and strength of PAN, which was synthesized in ionic liquid, are reliatively higher. The influence of IL's nature upon their ionic conductivity and the formation of conductive polymers from molten‐salt‐type vinyl monomers was investigated. Molecular design of the polymers simultaneously with the influence of IL's nature in order to achieve higher ionic conductivity is discussed. Flexible, transparent polymer films, obtained in different ways, show relatively high ionic conductivity (of about 10?5 S cm?1 at 20°C). Copyright © 2006 John Wiley & Sons, Ltd. 相似文献
202.
Kravchenko A. N. Lyssenko K. A. Chikunov I. E. Belyakov P. A. Il’in M. M. Baranov V. V. Nelyubina Yu. V. Davankov V. A. Pivina T. S. Makhova N. N. Antipin M. Yu. 《Russian Chemical Bulletin》2009,58(2):395-405
Russian Chemical Bulletin - The α-ureidoalkylation of N-(carboxyalkyl)ureas (ureido acids) with 1,3-H2 s-, 1,3-Me 2 s-, and 1,3-Et2 s-4,5-dihydroxyimidazolidin-2-ones was systematically... 相似文献
203.
A. A. Pasynskii Yu. V. Torubaev F. S. Denisov A. N. Grechkin K. A. Lyssenko S. E. Nefedov V. M. Novotortsev Zh. V. Dobrokhotova 《Russian Chemical Bulletin》1999,48(9):1744-1750
Complexes [RC5H4Fe(CO)2]2Sn(TePh)2 (R=H, Me) containing stable heterometallic Fe−Sn−Fe fragments with two phenyltellurium groups at the tin atom were synthesized
from [RC5H4Fe(CO)2]2SnCl2 (R=H, Me) and sodium phenyltelluride and their structures were established by X-ray analysis. Their chelates with tungsten
tetracarbonyl, [RC5H4Fe(CO)2]2Sn(TePh)2[W(CO)4] (R=Me, H), and complexes with two Cr(CO)5 fragments or dimeric trimethylplatinum iodide were synthesized and studied by X-ray analysis. Thermal decomposition of [RC5H4Fe(CO)2]2Sn(TePh)2 complexes and their adducts with ML fragments (ML=W(CO)4, 2 Cr(CO)5, (Me3PtI)2) into inorganic tellurides of a preset mixed-metal—chalcogenide composition was studied by differential scanning calorimetry.
The temperature of complete elimination of organic fragments from methylcyclopentadienyl complexes is about 100°C lower than
in the case of cyclopentadienyl analogs.
Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 1766–1772, September, 1999. 相似文献
204.
205.
Perekalin D. S. Petrovskii P. V. Lyssenko K. A. Kudinov A. R. 《Russian Chemical Bulletin》2009,58(5):1094-1096
Russian Chemical Bulletin - 相似文献
206.
D. G. Golovanov A. O. Tokareva A. I. Uraev Yu. I. Ryabukhin A. I. Pyshchev T. V. Kovaleva M. Yu. Antipin K. A. Lyssenko 《Russian Chemical Bulletin》2006,55(3):408-414
The nature and energy of the intramolecular H-bond in 3-(2-hydroxyphenyl)-1,2,4-triazoles was studied by X-ray diffraction
and quantum chemical methods. In this system, the conjugation does not additionally contribute to the enhancement of the H-bond
energy. The cooperative effects lead to a strengthening of the intramolecular H-bond.
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 3, pp. 396–402, March, 2006. 相似文献
207.
A. O. Borisova D. A. Garnovskii E. V. Korshunova A. I. Uraev A. S. Burlov K. A. Lyssenko 《Russian Chemical Bulletin》2012,61(11):2070-2075
The high-resolution X-ray diffraction study of dizinc bis(pyridine)-bis{[μ2-(2-oxybenzylidene)amino]-4,6-di(tert-butyl)phenoxide} and the analysis of the structures of related compounds refuted the data on the effect of the exchange or dative mechanism of the metalbridging ligand bond formation on the bond strength and revealed the factors controlling the energy of these bonds. 相似文献
208.
Analysis of the experimental electron density distribution function for the crystal and quantum chemical calculations revealed some distinctive features of stereoelectronic interactions (SI) in the fragment N-C-CN. The SI-induced changes in the atomic parameters were characterized in terms of the “Atoms in Molecules” theory. These interactions were compared with competitive SI in the fragment N-C-N. The crystal packing in organic cyanides is discussed. According to the data obtained, relatively weak SI in the fragment N-C-CN can be decisive for the molecular conformation in the crystal when there are no strong competitive interactions. 相似文献
209.
S. V. Makarenko E. V. Stukan’ K. A. Lyssenko I. V. Anan’ev V. M. Berestovitskaya 《Russian Chemical Bulletin》2013,62(6):1377-1381
A reaction of 1-bromo-3,3,3-trichloro-1-nitropropene with pyrocatechol, o-aminophenol, and their substituted derivatives led to 2-nitromethyl-2-trichloromethyl-1,3-benzodioxoles and 2-nitromethyl-2-trichloromethyl-1,3-benzoxazolines. The structure of the compounds synthesized was established by IR, 1H and 13C NMR spectroscopy with HMQC and HMBC 1H—13C experiments, and X-ray diffraction analysis. 相似文献
210.
O. V. Gusev N. A. Ustynyuk T. A. Peganova A. V. Gonchar P. V. Petrovskii K. A. Lyssenko 《Phosphorus, sulfur, and silicon and the related elements》2013,188(2):322-331
The behavior of different anilines H2NC6H4R (R = o-Me, p-Me, o-, m- and p? i Pr, p-OMe, p-CO2Et) and 2,6-Me2C6H3NH2 towards trihalophosphoranes was studied. 2,6-Me2C6H3NH2 failed to form the diaminophosphonium salt [Ph2PNH(2,6-Me2C6H3)2]Br, and the aminophosphine oxide Ph2(2,6-Me2C6H3NH)PO was the only isolated product. Both o- and p-toluidine gave the corresponding diaminophosphonium salts; however in the case of o-toluidine, the yield was low and a mixture with the respective aminophosphine oxide was observed. Anilines containing methoxy and ethoxycarbonyl groups in para-position form the diaminophosphonium salts in reasonable yields. 相似文献