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131.
A. S. Amarasekara O. S. Owereh K. A. Lyssenko T. V. Timofeeva 《Journal of Structural Chemistry》2009,50(6):1159-1165
The Schiff base derivatives prepared from 4-acetyl-5-methyl-2-phenyl-2,4-dihydro-pyrazol-3-one and alkyl amines are shown
to remain exclusively in the amine-one(I) tautomeric form in chloroform solutions at room temperature using a combination
of 1H, 13C, APT, COSY, HMQC, and HMBC NMR spectroscopic methods. The crystal structure of 5-methyl-2-phenyl-4-{1-[(pyridin-2-ylmethyl)-amino]-ethylidene}-2,4-dihydro-pyrazol-3-one
showed that this 4-acylpyrazolone Schiff base stays in the amine-one(I) form in the solid state as well, and the solid state
structure supports the fact that strong hydrogen bonding between amine hydrogen and the pyrazolone C3 carbonyl oxygen helps to stabilize the amine-one(I) tautomer. 相似文献
132.
Alexeev Alexander A. Nurieva Evgeniya V. Lyssenko Konstantin A. Grishin Yuri K. Zefirova Olga N. 《Structural chemistry》2019,30(2):473-479
Structural Chemistry - In an attempt to synthesize 4-thia-6-azatricyclo[5.3.1.13,9]dodecan-5-imine as putative antihypotensive agent with prolonged effect, a reaction of... 相似文献
133.
134.
We present a new “economic” method for performing two-photon spectroscopy using just one exciting dye-laser and taking advantage of the hereby produced broad emission bands of highly excited semiconductors. It is applied to the biexciton ground state in CdS (Ebiex = 5.0983 eV, symmetry Γ1) and to an excited biexciton state in ZnO (6.7407 eV, symmetry Γ5). 相似文献
135.
136.
T. A. Bazhenova A. F. Shestakov A. E. Shilov M. Yu. Antipin K. A. Lyssenko Yu. T. Struchkov 《Journal of organometallic chemistry》1995,490(1-2):71-73
The crystal structure of 1,4-dilithiumbutadiene 2 obtained in the reaction of tolane with an iron(II) hydridolithium complex shows that 2 is a dimer with four lithium atoms, forming a distorted tetrahedron with short Li---Li and Li---C distances. Implication for the reaction of the iron-lithium complex with dinitrogen is discussed. 相似文献
137.
S. A. Pisareva P. V. Petrovskii K. A. Lyssenko M. Yu. Antipin E. E. Nifant’ev 《Russian Chemical Bulletin》2004,53(9):2008-2012
The reaction of 1,1,1-tris(chloromethyl)propane with diphenylphosphine under phase-transfer conditions afforded 1,1,1-tris(diphenylphosphinomethyl)propane, whose oxidation gave a previously unknown representative of trigonal tris(phosphine oxides), viz., stable 1,1,1-tris(diphenylphosphorylmethyl)propane. Its analogs, viz., bis(diphenylphosphoryl)diphenylphosphinomethane and tris(diphenylphosphoryl)methane, are unstable in air and decompose with the cleavage of the P-C bond.Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 1926–1929, September, 2004. 相似文献
138.
A. V. Manaev T. A. Chibisova K. A. Lyssenko M. Yu. Antipin V. F. Traven’ 《Russian Chemical Bulletin》2006,55(11):2091-2094
New boron chelates were synthesized by the reactions of 3-acetyl-4-hydroxycoumarin and 8-acyl-7-hydroxy-4-methylcoumarins
with boron trifluoride etherate and hydroxybenzodioxaborole. The structure of 3-acetyl-4-difluoroboryloxycoumarin containing
an intramolecular C=O...B coordination bond was established by X-ray diffraction.
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 11, pp. 2012–2015, November, 2006. 相似文献
139.
Griffith D Lyssenko K Jensen P Kruger PE Marmion CJ 《Dalton transactions (Cambridge, England : 2003)》2005,(5):956-961
The 2-pyridinecarboxylate (2-pyca) platinum(IV) complex [2-pycaH2][PtCl4(2-pyca)].H2O, 1, has been synthesised from K2[PtCl4] following the hydrolysis of 2-pyridinehydroxamic acid (2-pyhaH) in the presence of H2O2, and directly from K2[PtCl6] and picolinic acid. Structural characterisation of 1 reveals octahedral geometry about platinum(IV) consisting of a (N,O)-bidentate pyridinecarboxylate ligand and four chloride ligands. A mechanism for the hydrolysis of 2-pyridinehydroxamic acid to 2-pyridinecarboxylic acid is proposed. Two novel coordination modes of hydroxamic acids to platinum(II) are also reported. The dinuclear platinum ammine hydroximato complex, [{cis-Pt(NH3)2}2(mu-2-pyhaH(-1))](ClO4)2.H2O, 3, has been synthesised where the two platinum(II) centres are bridged via(O,O) and (N,N) coordination. The latter coordination mode is via the hydroximate nitrogen and the pyridine nitrogen. The corresponding mononuclear platinum(II) pyridinehydroxamate complex, [cis-Pt(NH3)2(2-pyha)]ClO4, 4, has been synthesised. Spectroscopic studies indicate that the coordination mode is through the pyridine nitrogen and hydroxamate oxygen atoms (N,O). 相似文献
140.
The review concerns the results of systematic X-ray diffraction studies of the electron density distribution in the crystals
of compounds with strong intramolecular hydrogen bonds N-H...O, O-H...O, O-H...N, and N-H...S. The advantages of the topological
analysis of the electron density distribution function in the analysis of the nature and estimation of the H-bond energies
directly from experimental data are discussed.
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 1, pp. 1–14, January, 2006. 相似文献