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81.
Aubert B Barate R Boutigny D Gaillard JM Hicheur A Karyotakis Y Lees JP Robbe P Tisserand V Zghiche A Palano A Pompili A Chen JC Qi ND Rong G Wang P Zhu YS Eigen G Ofte I Stugu B Abrams GS Borgland AW Breon AB Brown DN Button-Shafer J Cahn RN Charles E Day CT Gill MS Gritsan AV Groysman Y Jacobsen RG Kadel RW Kadyk J Kerth LT Kolomensky YG Kral JF Kukartsev G LeClerc C Levi ME Lynch G Mir LM Oddone PJ Orimoto TJ Pripstein M Roe NA Romosan A Ronan MT Shelkov VG Telnov AV Wenzel WA Harrison TJ 《Physical review letters》2003,91(17):171801
We present results of a search for D0-D(-)0 mixing and a measurement of R(D), the ratio of doubly Cabibbo-suppressed decays to Cabibbo-favored decays, using D0-->K+pi- decays from 57.1 fb(-1) of data collected near sqrt[s]=10.6 GeV with the BABAR detector at the PEP-II collider. At the 95% confidence level, allowing for CP violation, we find the mixing parameters x('2)<0.0022 and -0.056相似文献
82.
Lee CH Na HK Yoon DW Won DH Cho WS Lynch VM Shevchuk SV Sessler JL 《Journal of the American Chemical Society》2003,125(24):7301-7306
Three calix[4]pyrroles bearing m-orcinol-derived diether straps of different lengths on one side of the tetrapyrrolic core have been synthesized and characterized. Structural information for an analogous diester bridged strapped system reported previously (Yoon, D. W.; Hwang, H.; Lee, C. H. Angew. Chem., Int. Ed. Engl. 2002, 41, 1757-1759) is also provided as are bromide and chloride anion affinities for all four systems determined by Isothermal Titration Calorimetry (ITC) in acetonitrile. Although both sets of the strapped calix[4]pyrroles displayed enhanced affinities for chloride and bromide anion, differences were seen among the various receptors that support the conclusion that the anion binding ability of calixpyrrole-type systems can be effectively tuned by modifying the length and nature of the bridging straps. In the specific case of the diether systems, the largest chloride affinity was seen with the shortest strap, whereas the largest affinity for bromide anion was recorded in the case of the longest strap. On the basis of these findings, as well as supporting (1)H NMR spectroscopic studies, it is postulated that not only cavity size per se, but also the ability of the aryl portion of the strap to serve as a CH hydrogen bond donor site are important in regulating the observed anion affinities. 相似文献
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Wiskur SL Lavigne JJ Ait-Haddou H Lynch V Chiu YH Canary JW Anslyn EV 《Organic letters》2001,3(9):1311-1314
[structure in text] The pK(a) values and the geometries of secondary and tertiary amines adjacent to boronic acids were determined using potentiometric and (11)B NMR titrations. The studies showed that the secondary ammonium ion has a pK(a) similar to that of the tertiary ammonium species, which leads to the formation of tetrahedral boron centers at pH values above approximately 5.5. Therefore, secondary amines as well as tertiary amines, when placed proximal to boron centers, can be used to create tetrahedral boronic acids at neutral pH for diol complexation. 相似文献
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Michael J. Quast Gary E. Martin Vincent M. Lynch Stanley H. Simonsen John G. Stuart Marvin L. Tedjamulia Raymond N. Castle Milton L. Lee 《Journal of heterocyclic chemistry》1986,23(4):1115-1118
The crystal structure of 9-methylphenanthro[4,3-a]dibenzothiophene, C25H16S, Mr = 348.47, has been determined. Monoclinic, P21/c, a = 11.364(3), b, = 14.257(3), c = 11.575(2)Å, β = 116.26(2)°, V = 1681.9(7)Å3, Z = 4, Dx = 1.38 g/cc, MoKα radiation λ = .71069 Å, F(000) = 728, T = 163K, R = .0458 for 2330 reflections. The structure compares favorably with that of hexahelicene and methylated derivatives. The thiophene moiety increases the helical core radius and decreases the pitch with respect to hexahelicene and its derivatives. 相似文献
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Summary The method of iterative target transformation factor analysis (ITTFA) used in conjunction with second derivative peak finding
has shown to be a practical method for the peak deconvolution and reconstruction of HPLC chromatograms and spectra. The second
derivative method of peak finding is acceptable for resolutions above 0.5 for peaks of similar heights. Above 0.5 resolution
the labelling gives correct results where the spectra are substantially different and also when reasonably similar. Below
this value the peak labelling was still accurate where the spectra were different. Solvent effects on the spectra of the compounds
studied are small and do not hinder the peak labelling process. Thus small “local” libraries are feasible.
Presented at the 17th International Symposium on Chromatography, September 25–30, 1988. Vienna, Austria. 相似文献