全文获取类型
收费全文 | 5578篇 |
免费 | 852篇 |
国内免费 | 617篇 |
专业分类
化学 | 4314篇 |
晶体学 | 70篇 |
力学 | 265篇 |
综合类 | 22篇 |
数学 | 579篇 |
物理学 | 1797篇 |
出版年
2024年 | 24篇 |
2023年 | 152篇 |
2022年 | 305篇 |
2021年 | 277篇 |
2020年 | 308篇 |
2019年 | 311篇 |
2018年 | 272篇 |
2017年 | 238篇 |
2016年 | 351篇 |
2015年 | 342篇 |
2014年 | 377篇 |
2013年 | 499篇 |
2012年 | 521篇 |
2011年 | 486篇 |
2010年 | 382篇 |
2009年 | 290篇 |
2008年 | 330篇 |
2007年 | 257篇 |
2006年 | 212篇 |
2005年 | 194篇 |
2004年 | 148篇 |
2003年 | 100篇 |
2002年 | 119篇 |
2001年 | 122篇 |
2000年 | 80篇 |
1999年 | 70篇 |
1998年 | 43篇 |
1997年 | 30篇 |
1996年 | 26篇 |
1995年 | 25篇 |
1994年 | 22篇 |
1993年 | 19篇 |
1992年 | 16篇 |
1991年 | 15篇 |
1990年 | 26篇 |
1989年 | 8篇 |
1988年 | 5篇 |
1987年 | 8篇 |
1986年 | 13篇 |
1985年 | 10篇 |
1984年 | 4篇 |
1983年 | 2篇 |
1982年 | 3篇 |
1981年 | 2篇 |
1980年 | 1篇 |
1979年 | 2篇 |
排序方式: 共有7047条查询结果,搜索用时 15 毫秒
11.
12.
On the Rank of the Semigroup TE(X) 总被引:1,自引:0,他引:1
Pei Huisheng 《Semigroup Forum》2005,70(1):107-117
${\cal T}_X $ denotes the full transformation semigroup on a set $ X $. For a
nontrivial equivalence $E$ on $X$, let
\[
T_E (X) =\{ f\in {\cal T}_X : \forall \, (a,b)\in E,\, (af,bf)\in E \} .
\]
Then $T_E (X) $ is exactly the semigroup of continuous selfmaps of
the topological space $X$ for which the collection of all
$E$-classes is a basis. In this paper, we first discuss the rank
of the homeomorphism group $G$, and then consider the rank of $T_E
(X)$ for a special case that the set $X$ is finite and that each
class of the equivalence $E$ has the same cardinality. Finally,
the rank of the closed selfmap semigroup $\Gamma(X)$ of the space
$X$ is observed. We conclude that the rank of $G$ is no more than
4, the rank of $T_E (X)$ is no more than 6 and the rank of
$\Gamma(X)$ is no more than 5. 相似文献
13.
The terminology ‘ID frequency’(w ID) is proposed after analyzing the 1D active photonic crystal based on the transfer matrix method. The relationship between wID and the structure parameters of the photonic crystal is investigated. 相似文献
14.
Chongyi Wan Shiming Liu Rongqing Tan Jin Wu Jinwen Zhou Yan Lv Yanning Yu Hua Yang 《Optics & Laser Technology》2004,36(8):2389-649
A high average power, high-repetition-rate TEA CO2 laser employing printed-circuit-board preionizer is described. The power scaling of this preionization configuration has been demonstrated. The average output power reaches 3.6 kW at pulse repetition rate of 180 pps. Furthermore, the scaling-up ability of the rotating spark gap as high-voltage switch for high-average-power gas laser has been validated. 相似文献
15.
The problem on the set-theoretical solutions to the quantum Yang-Baxter equation was presented byDrinfel'd as a main unsolved problem in quantum group theory. The set-theoretical solutions are a natural extensionof the usual (linear) solutions. In this paper, we not only give a further study on some known set-theoretical solutions(the Venkov's solutions), but also find a new kind of set-theoretical solutions which have a geometric interpretation.Moreover, the new solutions lead to the metahomomorphisms in group theory. 相似文献
16.
Three novel zinc complexes [Zn(dbsf)(H2O)2] ( 1 ), [Zn(dbsf)(2,2′‐bpy)(H2O)]·(i‐C3H7OH) ( 2 ) and [Zn(dbsf)(DMF)] ( 3 ) (H2dbsf = 4,4′‐dicarboxybiphenyl sulfone, 2,2′‐bpy = 2,2′‐bipyridine, i‐C3H7OH = iso‐propanol, DMF = N,N‐dimethylformamide) were first obtained and characterized by single crystal X‐ray crystallography. Although the results show that all the complexes 1–3 have one‐dimensional chains formed via coordination bonds, unique three‐dimensional supramolecular structures are formed due to different coordination modes and configuration of the dbsf2? ligand, hydrogen bonds and π–π interactions. Iso‐propanol molecules are in open channels of 2 while larger empty channels are formed in 3 . As compared with emission band of the free H2dbsf ligand, emission peaks of the complexes 1–3 are red‐shifted, and they show blue emission, which originates from enlarging conjugation upon coordination. Copyright © 2006 John Wiley & Sons, Ltd. 相似文献
17.
18.
Peng Xu Haitao Wang Rui Lv Qiangguo Du Wei Zhong Yuliang Yang 《Journal of polymer science. Part A, Polymer chemistry》2006,44(12):3911-3920
A novel microphase‐inversion method was proposed for the preparation of TiO2–SiO2/poly(methyl methacrylate) core–shell nanocomposite particles. The inorganic–polymer nanocomposites were first synthesized via a free‐radical copolymerization in a tetrahydrofuran solution, and the poor solvent was added slowly to induce the microphase separation of the nanocomposite and result in the formation of nanoparticles. The average particle sizes of the microspheres ranged from 70 to 1000 nm, depending on the reaction conditions. Transmission electron microscopy and scanning electron microscopy indicated a core–shell morphology for the obtained microspheres. Thermogravimetric analysis and X‐ray photoelectron spectroscopy measurements confirmed that the surface of the nanocomposite microspheres was polymer‐rich, and this was consistent with the core–shell morphology. The influence of the synthetic conditions, such as the inorganic composition and the content of the crosslinking monomer, on the particle properties was studied in detail. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 3911–3920, 2006 相似文献
19.
近年来,毛细管电泳已成为一种高效快速的微化学分离分析新技术,在无机、有机及生物化学分析中得到了广泛的应用.但毛细管的内径小,进样量在pg~ng级,给样品的检测带来新的困难.因此,发展高灵敏度的显微在线检测器,已成为毛细管电泳技术发展中的重要环节.基于各种原理的检测器研究已有报道~[1].Dovichi等曾用热透镜技术在线检测了乙腈/ 相似文献
20.
Zhu Hai-Liang Huang Pei Duan Chun-Ying Zheng Li-Min Liu Yong-Jiang Wu Mei-Fang Tang Wen-Xia 《Transition Metal Chemistry》1999,24(4):380-383
An azide-bridged polymeric cationic chain complex, [LCu2(N3)2]n(ClO4)2n
·n(H2O)**, where L=the dinucleating macrocyclic ligand bis-p-xylylBISDIEN, has been prepared and characterized by x-ray crystallography, u.v.-vis and i.r. spectra, and by magnetic measurements. The structure consists of cationic azide-bridged [LCu2(N3)2]2+ (unit) chains, non-coordinated perchlorate anions and crystallized water molecules. The azide anion is bound to two copper atoms in neighboring units with an end-to-end bridging mode. In each unit, the copper atoms have a different coordination geometry; Cu(1) is a four-coordinated, distorted square-planar geometry, whereas Cu(2) is a five-coordinated, distorted square-pyramid. The electronic spectra of the title complex differ in anhydrous and in aqueous MeCN solutions, indicating that dissociation and solvation occur in aqueous solutions. The characteristic i.r. absorptions of azides and perchlorates are described. Magnetic moments vary from 2.05 (B.M.) at 300K to2.01 (B.M.) at 80K, which suggests that very weak interactions exist between the metals. 相似文献