全文获取类型
收费全文 | 2079篇 |
免费 | 103篇 |
国内免费 | 11篇 |
专业分类
化学 | 1517篇 |
晶体学 | 17篇 |
力学 | 29篇 |
数学 | 297篇 |
物理学 | 333篇 |
出版年
2023年 | 16篇 |
2022年 | 22篇 |
2021年 | 26篇 |
2020年 | 72篇 |
2019年 | 48篇 |
2018年 | 29篇 |
2017年 | 13篇 |
2016年 | 42篇 |
2015年 | 57篇 |
2014年 | 60篇 |
2013年 | 83篇 |
2012年 | 79篇 |
2011年 | 117篇 |
2010年 | 51篇 |
2009年 | 64篇 |
2008年 | 96篇 |
2007年 | 89篇 |
2006年 | 72篇 |
2005年 | 105篇 |
2004年 | 98篇 |
2003年 | 72篇 |
2002年 | 58篇 |
2001年 | 56篇 |
2000年 | 39篇 |
1999年 | 36篇 |
1998年 | 35篇 |
1997年 | 37篇 |
1996年 | 36篇 |
1995年 | 30篇 |
1994年 | 28篇 |
1993年 | 34篇 |
1992年 | 27篇 |
1991年 | 32篇 |
1990年 | 38篇 |
1989年 | 24篇 |
1988年 | 23篇 |
1987年 | 27篇 |
1986年 | 23篇 |
1985年 | 24篇 |
1984年 | 23篇 |
1983年 | 13篇 |
1982年 | 15篇 |
1981年 | 23篇 |
1980年 | 14篇 |
1979年 | 16篇 |
1978年 | 21篇 |
1977年 | 19篇 |
1976年 | 19篇 |
1974年 | 16篇 |
1973年 | 15篇 |
排序方式: 共有2193条查询结果,搜索用时 17 毫秒
161.
162.
C Ludwig H Lutz J Wochele S Stucki 《Fresenius' Journal of Analytical Chemistry》2001,371(8):1057-1062
"Thermal desorption experiments" were carried out during which heavy metal evaporation was studied by on-line monitoring. This could be achieved by the use of a tubular furnace connected to a heavy metal detector, i.e. an ICP-OES (inductively coupled plasma optical emission spectrometer), by a specially designed and patented interface. The spectrograms typically had a time resolution of four different elements per minute using a conventional (sequentially operating) ICP-OES. This study shows how thermo-desorption spectrometry (TDS) can be applied to study the evaporation of high boiling substances, such as heavy metal and alkali metal compounds. The future scope of the method is discussed. 相似文献
163.
Agnes T. Paras Lutz Strü ngmann 《Proceedings of the American Mathematical Society》2003,131(2):371-377
An abelian -group is called (fully) transitive if for all with ( ) there exists an automorphism (endomorphism) of which maps onto . It is a long-standing problem of A. L. S. Corner whether there exist non-transitive but fully transitive -groups with finite first Ulm subgroup. In this paper we restrict ourselves to -groups of type , this is to say -groups satisfying . We show that the answer to Corner's question is no if is finite and is of type .
164.
When the streamlinediffusion finite element method isapplied to convectiondiffusion problems using nonconformingtrial spaces, it has previously been observed that stabilityand convergence problems may occur. It has consequently beenproposed that certain jump terms should be added to the bilinearform to obtain the same stability and convergence behaviouras in the conforming case. The analysis in this paper showsthat for the Qrot1 1 element on rectangular shape-regular tensor-productmeshes, no jump terms are needed to stabilize the method. Inthis case moreover, for smooth solutions we derive in the streamlinediffusionnorm convergence of order h3/2 (uniformly in the diffusion coefficientof the problem), where h is the mesh diameter. (This estimateis already known for the conforming case.) Our analysis alsoshows that similar stability and convergence results fail tohold true for analogous piecewise linear nonconforming elements. 相似文献
165.
Fiete GA Hersch JS Heller EJ Manoharan HC Lutz CP Eigler DM 《Physical review letters》2001,86(11):2392-2395
We explain the origin of the Kondo mirage seen in recent quantum corral scanning tunneling microscope experiments with a scattering theory of electrons on the surfaces of metals. Our theory, combined with experimental data, provides a direct observation of a single Kondo atom phase shift. The Kondo mirage observed at the empty focus of an elliptical quantum corral is shown to arise from multiple electron bounces off the corral wall adatoms. We demonstrate our theory with direct quantitive comparison to experimental data. 相似文献
166.
Jung WI Bunse M Lutz O 《Journal of magnetic resonance (San Diego, Calif. : 1997)》2001,152(2):203-213
Localized (1)H NMR spectroscopy using the 90 degrees -t(1)-180 degrees -t(1)+t(2)-180 degrees -t(2)-Acq. PRESS sequence can lead to a signal loss for the lactate doublet compared with signals from uncoupled nuclei which is dependent on the choice of t(1) and t(2). The most striking signal loss of up to 78% of the total signal occurs with the symmetrical PRESS sequence (t(1)=t(2)) at an echo time of 2/J (approximately 290 ms). Calculations have shown that this signal loss is related to the pulse angle distributions produced by the two refocusing pulses which leads to the creation of single quantum polarization transfer (PT) as well as to not directly observable states (NDOS) of the lactate AX(3) spin system: zero- and multiple-quantum coherences, and longitudinal spin orders. In addition, the chemical shift dependent voxel displacement (VOD) leads to further signal loss. By calculating the density operator for various of the echo times TE=n/J, n=1, 2, 3,..., we calculated quantitatively the contributions of these effects to the signal loss as well as their spatial distribution. A maximum signal loss of 75% can be expected from theory for the symmetrical PRESS sequence and TE=2/J for Hamming filtered sinc pulses, whereby 47% are due to the creation of NDOS and up to 28% arise from PT. Taking also the VOD effect into account (2 mT/m slice selection gradients, 20-mm slices) leads to 54% signal loss from NDOS and up to 24% from PT, leading to a maximum signal loss of 78%. Using RE-BURP pulses with their more rectangular pulse angle distributions reduces the maximum signal loss to 44%. Experiments at 1.5 T using a lactate solution demonstrated a maximum lactate signal loss for sinc pulses of 82% (52% NDOS, 30% PT) at TE=290 ms using the symmetrical PRESS sequence. The great signal loss and its spatial distribution is of importance for investigations using a symmetrical PRESS sequence at TE=2/J. 相似文献
167.
We study the convergence properties of the cascadic conjugate-gradient method (CCG-method), which can be considered as a multilevel method without coarse-grid correction. Nevertheless, the CCG-method converges with a rate that is independent of the number of unknowns and the number of grid levels. We prove this property for two-dimensional elliptic second-order Dirichlet problems in a polygonal domain with an interior angle greater than . For piecewise linear finite elements we construct special nested triangulations that satisfy the conditions of a ``triangulation of type ' in the sense of I. Babuska, R. B. Kellogg and J. Pitkäranta. In this way we can guarantee both the same order of accuracy in the energy norm of the discrete solution and the same convergence rate of the CCG-method as in the case of quasiuniform triangulations of a convex polygonal domain.
168.
An interleaved sampling strategy for MR spectroscopy in vivo: applications on human calf musculature
Assessment of relaxation times, magnetization transfer rates, or apparent diffusion coefficients by volume selective (1)H MR spectroscopy requires data from several single spectra with variable sequence parameters. Unintentional movements during the examination lead to inaccuracies, especially if the spatial distribution of concentrations is inhomogeneous. Improved comparability of the single spectra in a series recorded in vivo were obtained using a modified spectroscopic technique with INTerleaved ACquisiTion of multiple SPECtra (INTACTSPEC). INTACTSPEC series of spectra from the tibialis anterior muscle (m. tib. ant.), soleus muscle (m. soleus), and tibial bone marrow of 20 healthy volunteers were analyzed. Transverse relaxation times T(2) of methylene signals in muscular lipid stores ranged from 77 ms (intramyocellular methylene component in m. tib. ant.) to 88 ms (intramyocellular methylene component in m. soleus) and were similar to those from yellow tibial bone marrow (T(2) = 84 ms). Echo time-dependent signal intensities of choline and creatine deviated markedly from a monoexponential behavior in m. tib. ant., but were nearly exponential in m. soleus. Results from water diffusion measurements parallel and perpendicular to the axis of the lower leg showed significant differences between m. tib. ant. and m. soleus, probably due to the spatial orientation of the muscle fibers. Apparent diffusion coefficients along the leg axis were found to be higher in m. tib. ant. (2.10 +/- 0.08 x 10(-3) mm(2)/s) compared to m. soleus (1.78 +/- 0.11 x 10(-3) mm(2)/s), but m. soleus showed less restricted diffusion in perpendicular orientation (1.59 +/- 0.19 x 10(-3) mm(2)/s versus 1.20 +/- 0.08 x 10(-3) mm(2)/s in m. tib. ant.). Magnetization transfer experiments with various RF preparation pulse amplitudes led to very similar results for m. tib. ant. and m. soleus. 相似文献
169.
170.