ENVIRONMENTAL CHANGE AND THE CONTRIBUTION OF BIODIVERSITY TO ECOSYSTEM ADAPTATION

Abstract This paper develops a measure of the contribution of biodiversity in enhancing ecosystem performance that is subject to environmental fluctuation. The analysis draws from an ecological model that relates high phenotypic variance with lower short‐term productivity (due to the presence of suboptimal species) and higher long‐term productivity (due to better ability to respond to environmental fluctuations). This feature, which is a notable extension to existing economic‐ecological models of biodiversity, enables assessment of the interactions between diversity and a range of environmental fluctuations to highlight that biodiversity could be rendered economically disadvantageous when environmental fluctuation is insufficient. The resulting economic‐ecological model generates discounted present value of harvests for an ecosystem with diverse set of species. This value is compared with the harvest value of a similar economic‐ecological model with no diversity and that of an ecosystem where the dynamics of phenotypes in response to environmental fluctuations is disregarded. The results show that diversity positively contributes to the performance of ecosystems subject to sufficiently large environmental fluctuation. In addition, neglecting an ecosystem's increasing ability to adapt to match environmental conditions is also shown to be more costly than having no diversity in an otherwise identical ecosystem.     

Application of the real space dynamic renormalization group method to the one-dimensional kinetic ising model

We apply the recently developed real space dynamic renormalization group method to the one-dimensional kinetic Ising model. We show how one can develop block spin methods that lead to recursion relations for the space and time dependent correlation functions that correspond to the observables for this system. We point out the importance of carefully choosing the appropriate parameters governing the behavior of individual blocks of spins and the necessity of worrying about the high temperature properties of the temperature recursion relations if one is to obtain the proper exponential decay of correlation functions at large distances away from the critical point at zero temperature. We systematically investigate the accuracy of our approximate recursion relations for various correlation functions by checking them against the known exact results. Our simple methods work surprisingly well over a wide range of temperatures, wavenumbers and frequencies.     

Benzo[2,1‐b;3,4‐b′]dithiophene‐based low‐bandgap polymers for photovoltaic applications

The synthesis of four alternating copolymers using benzo[2,1‐b;3,4‐b′]dithiophene (BDP) as the common donor unit is presented. Before the synthesis, theoretical calculations that we performed predicted that the incorporation of BDP, which consists of fused dithiophene units with a benzene ring, into these polymers would produce a low‐lying highest occupied molecular orbital (HOMO) energy level. Low‐lying HOMO levels are desirable to produce high open circuit voltages (V_OC) in organic bulk heterojunction (BHJ) photovoltaic devices. The polymers' structural characterization, as well as the preliminary results of their performance in BHJ devices, using (6,6)‐phenyl C₆₁‐butyric acid methyl ester as the electron acceptor, is presented. The V_OC values follow the expected trend: increasing with decreasing HOMO level of the polymer. High V_OC values of 0.81 and 0.82 V have been obtained from two polymers: PBDPBT and PBDPDPP. The initial power conversion efficiency achieved in these unoptimized devices was 1.11% because of relatively low J_SC values. The variation observed in the J_SC values between the four polymers is discussed. Device performance is expected to increase with optimization of processing conditions for the devices. © 2010 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2011     

Ligand-protein docking studies of potential HIV-1 drug compounds using the algorithm FlexX

Four compounds are docked to a pentameric bundle representing the transmembrane part of the Vpu protein from HIV-1. Employing the docking algorithm FlexX, their free energy of binding is estimated leading to the conclusion that potential drug candidates need to form H-bonds either with neighbouring or with n + 2 helices at the site of the serines within the bundle.