Tunable Surface‐Enhanced Raman Scattering from High‐Density Gold Semishell Arrays with Controllable Dimensions

A convenient reproducible technique is reported for the fabrication of large‐area gold semishell arrays by mechanically pressing porous anodic alumina (PAA) stamps into gold/polymer bilayer structures that serve as robust and cost‐efficient surface‐enhanced Raman‐scattering (SERS) substrates. The surface structure can be tuned further to optimize the enhancement factor according to optional PAA fabrication parameters and imprinting pressures. Finite‐difference time‐domain calculations indicate that the structure may possess excellent SERS characteristics due to the high density and abundance of hot spots.     

铬(Ⅲ)含β一二酮混合配体配合物的合成和表征

首次合了五种Cr(β-dik)Cl_2py_2型(其中β-dik分别为乙酰丙酮、苯甲酰丙酮、三氟乙酰丙酮、2—噻吩甲酰三氟丙酮、二苯甲酰甲烷)和一种Cr(pmbp)Cl_2(thf)混合配体配合物、一种Cr(pmbp)_3配合物。并对上述化合物进行了电子光谱、红外光谱等的表征工作。     

Two new coumarins from Micromelum falcatum with cytotoxicity and brine shrimp larvae toxicity

Two new coumarins, 7-methoxy-8-(2-hydroxmethyl-1-O-isovaleryl-4-butenyl)-coumarin (1) and 7-methoxy-8-(1-hydroxy-2-O-β-glucopyranosyl-3-methyl-4-butene-1-yl)coumarin (2), and twelve known coumarins 3-14 were isolated from the stem bark of Micromelum falcatum. The structures of compounds 1-14 were elucidated by extensive spectroscopic data analyses. The toxicity of compounds 1-14 was tested using a brine shrimp assay and in vitro antiproliferative assay against mammary cancer (F10) and lung cancer (HvEvc) cell lines by the MTT method. Some compounds had moderate activities. All compounds were also tested against the microorganisms Bacillus subtilis, Bacillus thuringiensis and Escherichia coli, but no activity was observed.     

激光打孔对氮化铝绝缘性能的影响

氮化铝陶瓷具有优良的绝缘和导热性能,是传导冷却超导电力装置绝缘与导热连接件的首选,激光切割是对其进行加工的最有效方法,但激光切割可能对其绝缘性能产生影响,进而影响超导电力装置的安全运行。基于此,通过对激光打孔前后氮化铝基片孔周区域绝缘电阻的测量、金相结构和扫描电镜成分的比较,分析了激光打孔对氮化铝绝缘性能的影响,并总结了选用氮化铝基片作为超导电力装置电流引线的绝缘与导热垫片应注意的问题。     

一种分数阶非线性系统稳定性判定定理的问题及分析

分数阶非线性系统稳定性理论的研究对于分数阶混沌系统同步控制的应用具有重要价值,将分数阶非线性系统稳定性判断转化为相应整数阶非线性系统稳定性判断的探讨很有意义.通过实例表明了:对于时变系数矩阵,如果整数阶系统稳定,其对应的阶次小于1的分数阶系统也稳定的判定定理是错误的,并分析了问题产生的原因.     

Improvement on peak-to-trough ratio of sampled fiber Bragg gratings with multiple phase shifts

Via a cascaded structure, the peak-to-trough ratio is considerably improved for sampled fiber Bragg gratings （SFBGs） based on multiple-phase-shift （MPS） technique. This cascaded filter is composed of two identical SFBGs which are inserted with the increasing or decreasing arrangement of phase shifts. With this inverse arrangement of MPS in grating design, the phase fluctuation of individual SFBG can be compensated, and as a result an excellent phase matching condition is realized. In this way, the peak-to- trough ratio in reflection spectra is improved from 6 to 12 dB when multiplication factor m = 4, and from 5dBto 10dBwhenm=8.     

从培养能力的角度看设计性实验

针对传统实验那种安排过死、刻板机械的特点，把设计性实验运用于教具设计与制作课程之中，充分地培养了学生动手、动脑的综合能力。     

环境科学与工程专业物理化学课程教与学的探讨

物理化学的学习前提是具有良好的高等数学知识基础及较强的逻辑推理能力,因此物理化学普遍被视为最难学的化学学科。本文紧扣金课标准,以环境科学与工程类专业学生为授课对象,基于近年来作者在物理化学教学内容和方法方面的探索,分析物理化学中的教与学中存在的问题及解决方法。     

Ka波段8路径向波导空间功率分配（合成）器

通过理论研究以及高频仿真相结合的方法分析设计了一款新型Ka波段8路径向波导空间功率分配（合成）器。研发的新结构输入输出段为标准矩形波导结构,代替了传统功率分配（合成）器输入输出段的同轴结构,这种新型全金属结构更加简单紧凑,更易于加工。仿真结果表明：功率分配（合成）器工作带宽达到了34%（12 GHz）,基本覆盖整个Ka波段;全频带内反射系数S11低于-20 dB,各支路的相位差均小于5。通过在同轴波导渐变段引入切比雪夫渐变结构,在减小了器件尺寸的同时,在整个频带内的网络S参数也不错。这款新型Ka波段8路径向波导功率分配（合成）器将应用于前级固态功率放大器,推动回旋行波管项目研发。     

基于光频调节的干涉型光纤水听器相位补偿检测方法

提出了一种基于光源频率调节的干涉型光纤水听器主动相位补偿的信号检测方法。详细介绍了该方法的基本检测原理,对信号解调误差进行了理论分析与仿真。为了验证该方法的可行性,搭建了实验系统,并编写了实时的信号采集、处理程序,对某一干涉型光纤水听器的声压灵敏度进行了测试。在频带20 Hz-1.3 kHz上,平均声压灵敏度为-162.2 dB(0 dB=1 rad/μPa),波动小于±0.8 dB,与采用相位载波调制解调方法测量的结果基本吻合。实验结果证明该方法是有效的。由于传感部分不含有源器件,便于实现全光纤化,且解调算法简单、检测频带宽,该方法能被广泛应用到各种干涉型光纤传感器的信号检测当中。