Yang-baxter operators arising from (co)algebra structures

We construct parametrized Yang-Baxter operators from algebra struc-tures, transfer the theory to coalgebras, and find the cases where such operators arising from (co) algebras are isomorphic. We give examples in dimension 2.     

Machine scheme of additive calculation of physicochemical properties of paraffin hydrocarbons

Summary A machine scheme has been developed for the additive calculation of the physicochemical properties of alkanes necessary for mass calculation of the constants and as a supplementation to the automatic chemical information retrieval system.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya No. 11, pp. 1985–1988, November, 1964     

A recognition algorithm for the intersection graphs of directed paths in directed trees

Consider a finite family of non-empty sets. The intersection graph of this family is obtained by representing each set by a vertex, two vertices being connected by an edge if and only if the corresponding sets intersect. The intersection graph of a family of directed paths in a directed tree is called a directed path graph. In this paper we present an efficient algorithm which constructs to a given graph a representation by a family of directed paths on a directed tree, if one exists. Also, we prove that a graph is a proper directed path graph if and only if it is a directed path graph.     

PAN composite membrane with different solvent affinities controlled by surface modification methods

Polyacrylonitrile (PAN) composite membranes with surface properties designed by either a chemical modification with ethylenediamine (EDA), or layer‐by‐layer (LbL) polyelectrolyte adsorption were investigated in this paper. Fourier‐transformed infrared (FTIR) spectroscopy and streaming potential measurements showed that the first step of the reaction with EDA in gas phase was the formation of ammonium salts with the reactive carboxylic groups present on the surface of the starting membrane. Part of the ammonium carboxylate groups was transformed in secondary amide linkages by a heat‐induced reaction. Poly(sodium styrenesulfonate) (NaPSS) and a polycation containing about 95 mol % of N,N‐dimethyl‐2‐hydroxypropyleneammonium chloride units in the backbone (PCA₅) were used as opposite polyions in the LbL film construction. The adsorbed polyion amount per every layer was controlled by the nature and concentration of the supporting electrolyte in polyelectrolyte deposition solution (NaBr and KBr). An almost linear increase of the adsorbed polyion amount versus the layer pair number was observed. The swelling degree (SD) in pure alcohols of the LbL‐modified PAN composite membrane decreased with the increase of the solvent polarity and with the decrease of the pore volume by pore filling with polyelectrolyte complex multilayer. © 2005 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 43: 4161–4171, 2005     

Nonlinear instability during the isothermal draw of optical fibers

The nonlinear instability of the isothermal draw of optical fibers from cylindric preforms is studied. The unsteady model of the process is solved numerically, accounting for the effects of inertia, gravity and surface forces. The effect of viscosity and gravity on the nonlinear stability of the process is studied. The possibility of draw resonance occurring is shown for a rate ratio much lower than the critical one, obtained when solving the simplified model. The proposed solution can be used to study technological stability and to model the draw of fibers of other materials which behave as Newtonian fluids.     

From realistic to simple models of fluids. III. Primitive models of carbon dioxide,hydrogen sulphide and acetone,and their properties

Recently developed methodology to construct primitive models of associating fluids as direct descendants of complex realistic intermolecular potential functions [L. Vl?ek, I. Nezbeda. Molec. Phys., 102, 485 (2004).] is extended to polar fluids and applied to three substances of practical importance: quadrupolar carbon dioxide, and dipolar hydrogen sulphide and acetone. It is shown that the structural properties (in terms of the site–site correlation functions) of the primitive models of polar fluids reproduce very well those of their parent realistic models but, nonetheless, they perform worse than in the case of associating fluids. A number of thermodynamic properties of the developed models obtained by computer simulations is also reported (for their later use in theoretical investigation) and discussed.