全文获取类型
收费全文 | 5781篇 |
免费 | 202篇 |
国内免费 | 43篇 |
专业分类
化学 | 4051篇 |
晶体学 | 35篇 |
力学 | 136篇 |
数学 | 1067篇 |
物理学 | 737篇 |
出版年
2024年 | 10篇 |
2023年 | 44篇 |
2022年 | 132篇 |
2021年 | 164篇 |
2020年 | 105篇 |
2019年 | 128篇 |
2018年 | 106篇 |
2017年 | 82篇 |
2016年 | 194篇 |
2015年 | 175篇 |
2014年 | 203篇 |
2013年 | 348篇 |
2012年 | 398篇 |
2011年 | 442篇 |
2010年 | 285篇 |
2009年 | 288篇 |
2008年 | 355篇 |
2007年 | 371篇 |
2006年 | 341篇 |
2005年 | 329篇 |
2004年 | 241篇 |
2003年 | 178篇 |
2002年 | 181篇 |
2001年 | 83篇 |
2000年 | 66篇 |
1999年 | 55篇 |
1998年 | 42篇 |
1997年 | 46篇 |
1996年 | 71篇 |
1995年 | 40篇 |
1994年 | 38篇 |
1993年 | 37篇 |
1992年 | 45篇 |
1991年 | 33篇 |
1990年 | 20篇 |
1989年 | 29篇 |
1988年 | 23篇 |
1987年 | 21篇 |
1986年 | 25篇 |
1985年 | 37篇 |
1984年 | 31篇 |
1983年 | 22篇 |
1982年 | 29篇 |
1981年 | 17篇 |
1980年 | 20篇 |
1979年 | 16篇 |
1978年 | 13篇 |
1977年 | 7篇 |
1975年 | 8篇 |
1974年 | 7篇 |
排序方式: 共有6026条查询结果,搜索用时 15 毫秒
21.
Inés CarrancoJosé Luis D?&#x;az Oscar JiménezRodolfo Lavilla 《Tetrahedron letters》2003,44(46):8449-8452
The Lewis acid-catalyzed interaction of dihydropyridines with ethyl glyoxalate and primary aliphatic amines yields, depending on the reaction conditions, bicyclic aminals or rearranged tetrahydropyridines in one-pot multicomponent reactions. 相似文献
22.
Jos Luis Rodrigo 《纯数学与应用数学通讯》2005,58(6):821-866
We consider the problem of the evolution of sharp fronts for the surface quasi‐geostrophic (QG) equation. This problem is the analogue to the vortex patch problem for the two‐dimensional Euler equation. The special interest of the quasi‐geostrophic equation lies in its strong similarities with the three‐dimensional Euler equation, while being a two‐dimen‐sional model. In particular, an analogue of the problem considered here, the evolution of sharp fronts for QG, is the evolution of a vortex line for the three‐dimensional Euler equation. The rigorous derivation of an equation for the evolution of a vortex line is still an open problem. The influence of the singularity appearing in the velocity when using the Biot‐Savart law still needs to be understood. We present two derivations for the evolution of a periodic sharp front. The first one, heuristic, shows the presence of a logarithmic singularity in the velocity, while the second, making use of weak solutions, obtains a rigorous equation for the evolution explaining the influence of that term in the evolution of the curve. Finally, using a Nash‐Moser argument as the main tool, we obtain local existence and uniqueness of a solution for the derived equation in the C∞ case. © 2004 Wiley Periodicals, Inc. 相似文献
23.
When comparing an urban system to an elasto-plastic lattice, an analogy to the solid state of matter can be exploited using the concepts of the band theory similarly. Thereafter, the population dynamics – in a region of certain stability in the state space and within appropriate energy bands – can be described in terms of Cellular Automata, with two mobile agents or pseudo particles: the inhabitant (representative of an average individual) and the recurson (representative of its multidimensional resources). As in the solid state, transition rules take the form of two coupled transport equations, comprising the terms equivalent to the generation-recombination and circulation processes. The first process can be compared to a predator–prey growth model, typical of Ecology; whereas the circulation process – composed of a drift component and a diffusion component – should be compared to the concentration-sprawl demographic balance seen in urban occupation and dynamics. Thus, it needs to be defined and determined an urban potential function, an equivalent population charge, mobility and diffusion parameters, as well as net growth factors. This analogy, discussed within the context of a case study for Great Mendoza, plausibly explains the varied growth rates of the political departments, as well as the principal urban trends for spatial occupation. 相似文献
24.
Carmen Izquierdo María Luisa Moyá Jose Luis Usero Julio Casado 《Monatshefte für Chemie / Chemical Monthly》1992,123(5):383-389
Summary A simple working method for the estimation of the aggregation numbers and core radii from weight measurements of sodium bis-2-ethylhexylsulphosuccinate (aerosol-OT orAOT)/decane/water microemulsions of several compositions is proposed.Starting out from the hypotheses that (i) the density of the water inside the droplets is the same as that of free water, (ii) all the surfactant is localized as interface, and (iii) the penetration of the organic phase into the interface is negligible, values for the aggregation number and core radii comparable to those determined using more sophisticated methods were obtained.The results/methodological simplicity ratio may be of great advantage in kinetic work on reaction mechanisms in microemulsions.
Abschätzung von Aggregationszahl und Radius von Mikroemulsionen
Zusammenfassung Es wird eine einfache Methode zur Abschätzung von Aggregationszahl und Core-Radius von Mikroemulsionen aus Gewichtsmessungen von Natriumbis-2-ethylhexylsulphosuccinat (aerosol-OT oderAOT)/Decan/Wasser-Mikroemulsionen verschiedener Zusammensetzung vorgeschlagen. Unter den Annahmen, daß (i) die Dichte von Wasser innerhalb der Aggregationen die gleiche als bei freiem Wasser ist, (ii) das ganze Emulsionsmittel in der Grenzfläche vorliegt und (iii) das Eindringen der organischen Phase in die Grenzfläche vernachlässigbar ist, können Werte für Aggregationszahlen und Core-Radien erhalten werden, die durchaus mit entsprechenden Werten aus aufwendigeren Methoden vergleichbar sind. Das Leistungsverhältnis (Ergebnisse/geringer Aufwand) ist sehr vorteilhaft und macht die Methode für kinetische Arbeiten zur Bestimmung von Reaktionsmechanismen in Mikroemulsionen interessant.相似文献
25.
26.
Rodrigo París Jos Luis de la Fuente 《Journal of polymer science. Part A, Polymer chemistry》2006,44(18):5304-5315
Functional spontaneous gradient copolymers of allyl methacrylate (A) and butyl acrylate (B) were synthesized via atom transfer radical polymerization. The copolymerization reactions were carried out in toluene solutions at 100 °C with methyl 2‐bromopropionate as the initiator and copper bromide with N,N,N′,N″,N″‐pentamethyldiethylenetriamine as the catalyst system. Different aspects of the statistical reaction copolymerizations, such as the kinetic behavior, crosslinking density, and gel fraction, were studied. The gel data were compared with Flory's gelation theory, and the sol fractions of the synthesized copolymers were characterized by size exclusion chromatography and nuclear magnetic resonance spectroscopy. The copolymer composition, demonstrating the gradient character of the copolymers, and the microstructure were analyzed. The experimental data agreed well with data calculated with the Mayo–Lewis terminal model and Bernoullian statistics, with monomer reactivity ratios of 2.58 ± 0.37 and 0.51 ± 0.05 for A and B, respectively, an isotacticity parameter for A of 0.24, and a coisotacticity parameter of 0.33. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 5304–5315, 2006 相似文献
27.
28.
29.
30.
Mikhael Balabane Thierry Cazenave Luis Vázquez 《Communications in Mathematical Physics》1990,133(1):53-74
We prove the existence of stationary states for nonlinear Dirac equations of the form (E) $$i\sum\limits_{\mu = 0}^3 {\gamma ^\mu \partial _\mu \psi - M\psi + F\left( {\bar \psi \psi } \right)\psi = 0,} $$ whereM>0 andF is a singular self-interaction. In particular, in the model case whereF(s)=?s ?α, for some 0<α<1, and for every ω>M, there exists a solution of (E) of the form ψ(t, x)=e iωt?(x), wherex 0=t andx=(x 1,x 2,x 3), such that ? has compact support. IF 0<α<1/3, then ? is of classC 1. If 1/3<α<1, then ? is continuously differentiable, except on some sphere {|x|=R}, where |??| is infinite. 相似文献