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91.
Andrea Carati Giancarlo Benettin Luigi Galgani 《Communications in Mathematical Physics》1992,150(2):321-336
For classical Hamiltonian systems containing an harmonic oscillator of high frequency, one has the problem of controlling the energy exchange between the oscillator and the remaining slow degrees of freedom; under very general conditions, such an exchange turns out to be exponentially small with the frequency of the oscillator. In the Jeans-Landau-Teller method, one aims to prove the exponential dependence, and to estimate the coefficient of the exponential, by exploiting the analyticity properties of the solution of the differential equations describing the motion of the system. However, in practice, since the exact solution is not known, such properties are inferred from those of an approximate solution, with no control of the difference; this fact might a priori even invalidate the exponential dependence itself. In the present paper a rigorous treatment is given, for a particular model of interest in the domain of atomic collisions, by keeping control of the difference between the exact and the approximate solution. 相似文献
92.
The preparations of the binuclear hydrido-bridged cations [(terdentate ligand)Pd(μ-H)Pd(terdentate ligand)]+ from [(terdentate ligand)Pd(acetone)]+ and NaO2CH and [(terdentate ligand)Pd(μ-H)Pt(terdentate ligand)]+ from [(terdentate ligand)Pd(acetone)]+ and [(terdentate ligand)PtH] (terdentate ligand = 2,6-(Ph2PCH2)2C6H3) are reported. The preparation of the cation [(terdentate ligand)Pt(μ-H)Pt(terdentate ligand)]+ is also reported. 相似文献
93.
Giuseppe Mascolo Mauro Giustini Pier Luigi Luisi Jacques Lang 《Journal of colloid and interface science》1990,140(2)
The coupling reaction between cetylbromide (CB) and trimethylamine (TMA) to yield the surfactant cetyltrimethylammonium bromide (CTAB) is studied in the system chloroform/isooctane (2/1,v/v)/water in which CTAB forms reverse micelles. This system affords an endogenous micelle population growth, i.e., an increase of the concentration of the micelles due to appearance of the surfactant in situ. The reaction is studied in the presence of preexisting CTAB reverse micelles. The rate of CTAB formation is measured by NMR spectroscopy, and the endogenous micelle population growth is directly monitored by time-resolved fluorescence quenching analysis. Under our experimental conditions, a 100% yield of the chemical reaction brings about a fourfold increase in the population of the reverse micelles. Since the water concentration is constant during chemical reaction, the newly formed water pools are formed at the expense of the initial ones, which brings about a decrease of the average water pool radius during micellar growth. The implication of the endogenous micelle population growth as a model for biological systems is briefly discussed. 相似文献
94.
Gian Luigi Forti 《Aequationes Mathematicae》1982,24(1):195-206
We consider the following problem: Let (G, +) be an abelian group,B a complex Banach space,a, bB,b0,M a positive integer; find all functionsf:G B such that for every (x, y) G ×G the Cauchy differencef(x+y)–f(x)–f(y) belongs to the set {a, a+b, a+2b, ...,a+Mb}. We prove that all solutions of the above problem can be obtained by means of the injective homomorphisms fromG/H intoR/Z, whereH is a suitable proper subgroup ofG. 相似文献
95.
Gian Luigi Casalone Carla Mariani Angelo Mugnoli Massimo Simonetta 《Theoretical chemistry accounts》1967,8(3):228-235
On the basis of semiempirical calculations, the conformation of the isolated molecule of 2-bromo-1,1-diphenylprop-1-ene corresponding to the minimum of total energy was determined. Assuming some information on the localization of the molecules in the crystal, also the conformation in a theoretical crystal was studied. The results have been compared with the crystal structure of 2-bromo-1,1-diphenylprop-1-ene, as obtained by X-ray diffraction. From the comparison a slight displacement of the C2 atom was suggested.
This work was supported by a grant from the Italian Consiglio Nazionale delle Ricerche. 相似文献
Zusammenfassung Die dem Minimum der Gesamtenergie entsprechende Konformation des isolierten Moleküls von 2-Brom-1,1-diphenylprop-1-en wurde durch halb-empirische Methoden bestimmt. Gewisse Ergebnisse über die Anordnung der Moleküle im Kristall machten es möglich, die Konformation in einem theoretischen Kristall zu untersuchen. Nach Vergleich der Resultate mit der durch Röntgen-Analyse bestimmten Kristallstruktur des 2-Brom-1,1-diphenylprop-1-en wurde eine kleine Verschiebung des C2-Atoms vorgeschlagen.
Résumé Par le moyen de calculs semiempiriques on a déterminé la conformation de la molécule isolée de 2-bromo-1, 1-diphénilprop-1-ène, correspondant au minimum d'énergie totale. On a aussi étudié la conformation dans le cristal théorique en se basant sur des informations concernant la localisation des molécules dans le cristal. On a comparé ces résultats avec ceux que nous avons obtenus par la détermination de la structure cristalline du 2-bromo-1, 1-diphénilprop-1-ène avec la diffraction des rayons X: cette comparaison nous a porté à déplacer un petit peu l'atome C 2.
This work was supported by a grant from the Italian Consiglio Nazionale delle Ricerche. 相似文献
96.
Giorgio Pifferi Luigi Fontanella Emilia Occelli Riccardo Monguzzi 《Journal of heterocyclic chemistry》1972,9(6):1209-1214
o- Aminomethylbeiizyl alcohols (X) easily cyclize with phosgene in an aqueous alkaline medium to form 4,5-dihydro-2,4-benzoxazepin-3(1H)ones (IV) and with aldehydes in acidic conditions to yield 1,3,4,5-tetrahydro-2,4-benzoxazepines (V). The characteristics and chemical behaviour of these new heterocyclic ring systems are reported. 相似文献
97.
Migani A Gentili PL Negri F Olivucci M Romani A Favaro G Becker RS 《The journal of physical chemistry. A》2005,109(39):8684-8692
The efficiency of the photochemical ring-opening of chromenes (or benzopyrans) depends on the vibronic transition selected by the chosen excitation wavelength. In the present work, ab initio CASPT2//CASSCF calculations are used to determine the excited-state ring-opening reaction coordinate for 2H-chromene (C) and 2,2-diethyl-2H-chromene (DEC) and provide an explanation for such an unusual mode-dependent behavior. It is shown that excited-state relaxation and decay occur via a multimodal and barrierless (or nearly barrierless) reaction coordinate. In particular, the relaxation out of the Franck-Condon involves a combination of in-plane skeletal stretching and out-of-plane modes, while the second part of the reaction coordinate is dominated exclusively by a different out-of-plane mode. Population of this last mode is shown to be preparatory with respect to both C-O bond breaking and decay via an S(1)/S(0) conical intersection. The observed mode-dependent ring-opening efficiency is explained by showing that the vibrational mode corresponding to the most efficient vibronic transition has the largest projection onto the out-of-plane mode of the reaction coordinate. To support the computationally derived mechanism, we provide experimental evidence that the photochemical ring-opening reaction of 2,2-dimethyl-7,8-benzo(2H)chromene, that similarly to DEC exhibits a mode-dependent photoreaction, has a low ( approximately 1 kcal mol(-1)) activation energy barrier. 相似文献
98.
Giuseppe BifulcoTeresa Caserta Luigi Gomez-Paloma Vincenzo Piccialli 《Tetrahedron letters》2003,44(29):5499-5503
Further studies on the RuO4-catalyzed oxidative polycyclization of isoprenoid polyenes have been carried out. The configuration of the tris-THF product from the oxidation of geranylgeranyl acetate has been determined by a combination of spectral and chemical correlation methods. The oxidation of (E,Z)-farnesyl acetate, synthesized from nerol, has been carried out. This process stops at the first cyclization indicating that an E configuration of the Δ6 double bond is needed for the second cyclization to occur. The results are discussed in comparison with previous knowledge on the related Re(VII) polycyclization of polyenic bis-homoallylic alcohols. 相似文献
99.
Sunto In questa Nota è descritto wn metodo per la determinazione delle soluzioni della seguente equazione condizionale f(x+y) f(x) + f(y) + a implica f(x + y)=f(x) + f(y) dove f:GH, a H e G ed H sono gruppi abeliani qualsiasi. Sono poi determinate esplicitamente le soluzioni nei casi G=(r), G= e G=(p).
Lavoro svolto nell'ambito del G.N.A.F.A.-C.N.R. 相似文献
Lavoro svolto nell'ambito del G.N.A.F.A.-C.N.R. 相似文献
100.
Valentina Noemi Madia Walter Toscanelli Daniela De Vita Marta De Angelis Antonella Messore Davide Ialongo Luigi Scipione Valeria Tudino Felicia Diodata DAuria Roberto Di Santo Stefania Garzoli Annarita Stringaro Marisa Colone Magda Marchetti Fabiana Superti Lucia Nencioni Roberta Costi 《Molecules (Basel, Switzerland)》2022,27(12)
Influenza viruses are transmitted from human to human via airborne droplets and can be transferred through contaminated environmental surfaces. Some works have demonstrated the efficacy of essential oils (EOs) as antimicrobial and antiviral agents, but most of them examined the liquid phases, which are generally toxic for oral applications. In our study, we describe the antiviral activity of Citrus bergamia, Melaleuca alternifolia, Illicium verum and Eucalyptus globulus vapor EOs against influenza virus type A. In the vapor phase, C. bergamia and M. alternifolia strongly reduced viral cytopathic effect without exerting any cytotoxicity. The E. globulus vapor EO reduced viral infection by 78% with no cytotoxicity, while I. verum was not effective. Furthermore, we characterized the EOs and their vapor phase by the head-space gas chromatography–mass spectrometry technique, observing that the major component found in each liquid EO is the same one of the corresponding vapor phases, with the exception of M. alternifolia. To deepen the mechanism of action, the morphological integrity of virus particles was checked by negative staining transmission electron microscopy, showing that they interfere with the lipid bilayer of the viral envelope, leading to the decomposition of membranes. We speculated that the most abundant components of the vapor EOs might directly interfere with influenza virus envelope structures or mask viral structures important for early steps of viral infection. 相似文献