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61.
We study the interaction between two like charged surfaces embedded in a solution of oppositely charged multivalent rod-like counterions.The counterions consist of two rigidly bonded point charges,each of valency Z.The strength of the electrostatic coupling increases with increasing surface charge density or valency of the charges.The system is analyzed by employing a self-consistent field theory,which treats the short and long range interactions of the counterions within different approximations.We find that in the weak coupling limit,the interactions are only repulsive.In the intermediate coupling regime,the multivalent rod-like counterions can mediate attractive interactions between the surfaces. For sufficiently long rods,bridging contributes to the attractive interaction.In the strong coupling limit,the charge correlations can contribute to the attractive interactions at short separations between the charged surfaces.Two minima can then appear in the force curve between surfaces. 相似文献
62.
在Visual C++环境下,设计了一种基于OpenGL的三维电场线模拟软件。该软件采用微分方程法来生成电场线,可以准确地模拟不同观察视角下,静止点电荷的三维电场线。用户可以拖动鼠标随意转动观察视角,并可随意设置电荷个数、分布以及大小。 相似文献
63.
Shingjiang Jessie Lue Chi-Hwa Chen Chao-Ming Shih 《Journal of Macromolecular Science: Physics》2013,52(3):563-579
Temperature-responsive hydrogel with a lower critical solution temperature (LCST) close to human body temperature was prepared. Crosslinked N-isopropylacrylamide (NIPAAm) and acrylic acid (AAc) copolymer networks were synthesized at various monomer ratios in the presence of ammonium persulfate (APS), N,N′-methylenebisacrylamide (NMBA) and N,N,N′,N′-tetramethylethylenediamine (TEMED) via a redox polymerization method. The resulting hydrogels possessed thermo- and pH-responsive characteristics. They were characterized in terms of swelling ratio, volume change, water uptake and diffusivity, water vapor uptake and diffusivity, and phase transition temperature. The water liquid and vapor diffusion coefficients for all the synthesized hydrogels were higher than the literature data, implying higher rates for drug release. The LCST of the hydrogel increased with higher AAc content in the copolymer. The gel containing 1.8% AAc exhibited an LCST similar to human body temperature, demonstrating a potential use in drug controlled release and biomedical applications. 相似文献
64.
Yi-Chen Yeh Chun-Han Chiu Juh Tzeng Lue 《Applied Physics A: Materials Science & Processing》2009,94(4):923-926
We have observed an abnormal electron transport characteristic from the Ni–Mn–Ni triple-layered magnetic thin-films. Due to
the intercalated Mn ultra-thin interlayer, the magnetic domain structure and the electron transport characteristic differ
a lot from their original magnetic (Fe, Co, and Ni) films. As inspected by a magnetic force microscopy (MFM), we observed
the variation of the domain configuration with Mn interlayer thicknesses (for 1, 5, and 10 nm). Moreover, we also examined
and found that the direct current (DC) resistivity have no significant change as the current conducts from the current-in-wall
(CIW) to the current- perpendicular-to-wall (CPW), which are opposite to the results of single layered films. 相似文献
65.
66.
The frequency dependence on the reflectance of a one-dimensional (1D) photonic crystal composed of repetitive metallic and
dielectric layers was simulated by the finite difference in the time domain (FDTD) method, and with results compared to the
conventional transfer matrix (TM) method. The simulation from the FDTD method with an impedance-matched boundary of finite
dimensions yields results similar to the calculation from the TM method with unbounded planes. The FDTD method is prominent
in dealing with films of finite area including defects at some locations. The reflectivity increases and the rejection bandwidth
decreases as the number of layers increases.
PACS 42.70.Qs; 47.11.Bc; 78.20.-e; 78.67.-n 相似文献
67.
Lue‐Yung Chow Chiu Mohammad Moharerrzadeh 《International journal of quantum chemistry》1999,73(3):265-273
The Fourier transform of the spherical Laguerre Gaussian‐type function (LGTF), L (αr2)rlYlm( r̂ )e, was derived. Applying the Fourier transform convolution theorem, the basic two‐center integrals over the general two‐electron irregular solid harmonic operator, YLM( r̂ 12)/r (which becomes Coulomb repulsion, spin–other‐orbit interaction or spin–spin interaction when L=0, 1, or 2, respectively) as well as the overlap were evaluated analytically. These basic integral results generate the two‐electron integrals of the Coulomb type, hybrid type, and exchange type as well as that of three‐ and four‐center. The formulas obtained, which are general for electronic wave functions of unrestricted quantum numbers n, l, and m, are expressed explicitly in terms of nuclear spherical LGTFs of internuclear geometrical variables. ©1999 John Wiley & Sons, Inc. Int J Quant Chem 73: 265–273, 1999 相似文献
68.
By using the Moreau-Yosida regularization and proximal method, a new trust region algorithm is proposed for nonsmooth convex
minimization. A cubic subproblem with adaptive parameter is solved at each iteration. The global convergence and Q-superlinear
convergence are established under some suitable conditions. The overall iteration bound of the proposed algorithm is discussed.
Preliminary numerical experience is reported. 相似文献
69.
Cosmologists today are confronted with the perplexing reality that the universe is currently accelerating in its expansion. Nevertheless, the nature of the fuel that drives today's cosmic acceleration is an open and tantalizing mystery. There exists the intriguing possibility that the acceleration is not the manifestation of yet another mysterious ingredient in the cosmic gas tank (dark energy), but rather our first real lack of understanding of gravity itself, and even possibly a signal that there might exist dimensions beyond that which we can currently observe. The braneworld model of Dvali, Gabadadze and Porrati (DGP) is a theory where gravity is altered at immense distances by the excruciatingly slow leakage of gravity off our three-dimensional Universe and, as a modified-gravity theory, has pioneered this line of investigation. I review the underlying structure of DGP gravity and those phenomenological developments relevant to cosmologists interested in a pedagogical treatment of this intriguing model. 相似文献
70.