Deviation of the plane-wave approximation for optical fields in thin metallic films at various frequencies and temperatures

The frequency and temperature dependence of the size effect on the profile distribution of electromagnetic fields inside thin metallic films within the anomalous skin-effect region is theoretically studied. The relaxation time of conduction electrons is stated as (aT +b ²)^–1 in accord with Matthiessen's rule for current conduction. The errors of using the plane wave solution e^–uWz turns out to be as large as 5.5% compared to the total field including the higher-order terms for silver films with a thickness of 30 nm. However, the imaginary parts of the electric field for thinner metal films at lower temperatures are less affected by higher-order terms.     

Electronic structure and optical spectra of YBa2Cu3O7−δ thin films in the infrared and UV region

Optical reflectance of YBa₂Cu₃O_7- thin films grown by laser ablation is measured within photon energies of 0.1 eV to 3.5 eV at room temperature. The spectra can be fit congruently with the anisotropic dielectric constants which take account of the intraband free carrier transition and interband transition. The anisotropic plasma frequencies are simulated to be _pl=2.18 eV and _ch=2.80 eV contributed from free carriers on the plane and in the chain, respectively. The interband transition occurs near 2.5 eV and is pertinent to a rather broad line width.     

Properties and Bioapplications of Blended Cellulose and Corn Protein Films

A series of blend films have been prepared from cellulose and corn protein in a NaOH/urea solution by a simple, low cost, and ‘green’ pathway. Their structure and properties are characterized by amino acid analysis, X‐ray diffraction, scanning electron microscopy, thermogravimetry, and tensile testing. The results reveal that a certain miscibility exists between cellulose and corn protein and their thermal stability and mechanical properties are improved significantly, compared with the protein materials, when the protein content is less than 18 wt.‐%. The protein, which contains tyrosine and histidine, could remain in the blend films after being washed for ten days, which indicates the strong hydrogen bonding between the hydroxy groups of cellulose and the hydroxyphenyl of tyrosine and imidazolyl of histidine in the protein. Furthermore, they exhibit good biocompatibility capable of supporting cell adhesion and proliferation.

     

Helical structures from an isotropic homopolymer model

We present Monte Carlo simulation results for square-well homopolymers at a series of bond lengths. Although the model contains only isotropic pairwise interactions, under appropriate conditions this system shows spontaneous chiral symmetry breaking, where the chain exists in either a left- or a right-handed helical structure. We investigate how this behavior depends upon the ratio between bond length and monomer radius.     

Sound field prediction of ultrasonic lithotripsy in water with spheroidal beam equations

With converged shock wave,extracorporeal shock wave lithotripsy(ESWL)has become a preferable way to crush human calculi because of its advantages of efficiency and non-intrusion.Nonlinear spheroidal beam equations(SBE)are employed to illustrate the acoustic wave propagation for transducers with a wide aperture angle.To predict the acoustic field distribution precisely,boundary conditions are obtained for the SBE model of the monochromatic wave when the source is located on the focus of an ESWL transducer.Numerical results of the monochromatic wave propagation in water are analyzed and the influences of half-angle,fundamental frequency,and initial pressure are investigated.According to our results,with optimization of these factors,the pressure focal gain of ESWL can be enhanced and the effectiveness of treatment can be improved.     

Theoretical study of spectroscopic and molecular properties of several low‐lying electronic states of CO molecule

The potential energy curves (PECs) of eight low‐lying electronic states (X¹Σ⁺, a³Π, a′³Σ⁺, d³Δ, e³Σ^?, A¹Π, I¹Σ^?, and D¹Δ) of the carbon monoxide molecule have been studied by an ab initio quantum chemical method. The calculations have been performed using the complete active space self‐consistent field method, which is followed by the valence internally contracted multireference configuration interaction (MRCI) approach in combination with the correlation‐consistent aug‐cc‐pV5Z basis set. The effects on the PECs by the core‐valence correlation and relativistic corrections are included. The way to consider the relativistic corrections is to use the third‐order Douglas–Kroll Hamiltonian approximation at the level of a cc‐pV5Z basis set. Core‐valence correlation corrections are performed using the cc‐pCVQZ basis set. To obtain more reliable results, the PECs determined by the MRCI calculations are corrected for size‐extensivity errors by means of the Davidson modification (MRCI+Q). The spectroscopic parameters (D_e, T_e, R_e, ω_e, ω_ex_e, ω_ey_e, B_e, α_e, and γ_e) of these electronic states are calculated using these PECs. The spectroscopic parameters are compared with those reported in the literature. Using the Breit–Pauli operator, the spin–orbit coupling effect on the spectroscopic parameters is discussed for the a³Π electronic state. With the PECs obtained by the MRCI+Q/aug‐cc‐pV5Z+CV+DK calculations, the complete vibrational states of each electronic state have been determined. The vibrational manifolds have been calculated for each vibrational state of each electronic state. The vibrational level G(ν), inertial rotation constant B_ν, and centrifugal distortion constant D_ν of the first 20 vibrational states when the rotational quantum number J equals zero are reported and compared with the experimental data. Comparison with the measurements demonstrates that the present spectroscopic parameters and molecular constants determined by the MRCI+Q/aug‐cc‐pV5Z+CV+DK calculations are both reliable and accurate. © 2012 Wiley Periodicals, Inc.     

用结构方程辩识西部企业物流绩效与影响因素的关系

本文以我国西部某重要经济地区(重庆市)为研究对象,针对建设中的物流绩效评价工作展开,重点对影响物流绩效水平的影响因素进行调查,利用结构方程模型分析法找出它们之间可能存在的因果关系及关系的强弱,并进行了定性分析,使企业能够认识到可以从哪些方面入手以达到提高自身物流绩效水平的目的,进而能够为有效地提高西部地区物流水平提供依据。     

Particle Sizing by Photon Correlation Spectroscopy. Part IV: Resolution of bimodals and comparison with other particle sizing methods

The practical performances of single and multi-angle photon correlation spectroscopy (PCS) for resolving bimodal distributions of industrial poly (methyl methacrylate) samples was investigated in a comparative study by several users affiliated to academic and industrial groups and by two suppliers of commercial equipment. The results for the harmonic intensity averaged diameters obtained by cumulants analysis reported by the different laboratories are in agreement, in addition to the results for the normalized second cumulants. The uncertainty on the latter quantities is large, however. For the bimodal samples with two populations with average diameters in a ratio of about 2.5 : 1, not all users were able to resolve the distribution in its components by single-angle PCS. Some slight improvement was obtained by multi-angle PCS. Other indirect techniques (polarization intensity differential scattering, static light scattering data and disc photosedimentometer) appeared to be superior for resolving the bimodal distributions.