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101.
C Ludwig H Lutz J Wochele S Stucki 《Fresenius' Journal of Analytical Chemistry》2001,371(8):1057-1062
"Thermal desorption experiments" were carried out during which heavy metal evaporation was studied by on-line monitoring. This could be achieved by the use of a tubular furnace connected to a heavy metal detector, i.e. an ICP-OES (inductively coupled plasma optical emission spectrometer), by a specially designed and patented interface. The spectrograms typically had a time resolution of four different elements per minute using a conventional (sequentially operating) ICP-OES. This study shows how thermo-desorption spectrometry (TDS) can be applied to study the evaporation of high boiling substances, such as heavy metal and alkali metal compounds. The future scope of the method is discussed. 相似文献
102.
A 'chaos expansion' of the intersection local time functional of two independent Brownian motions in R
d
is given. The expansion is in terms of normal products of white noise (corresponding to multiple Wiener integrals). As a consequence of the local structure of the normal products, the kernel functions in the expansion are explicitly given and exhibit clearly the dimension dependent singularities of the local time functional. Their L
p
-properties are discussed. An important tool for deriving the chaos expansion is a computation of the 'S-transform' of the corresponding regularized intersection local times and a control about their singular limit. 相似文献
103.
The dynamics of C and N in terrestrial ecosystems are not completely understood and the use of stable isotopes may be useful to gain further insight in the pathways of CO2 emissions and leaching of dissolved organic carbon (DOC) and nitrogen (DON) during decomposition of litter. Objectives were (i) to study the decomposition dynamics of Calamagrostis epigeios, a common grass species in forests, using 13C-depleted and 15N-enriched plants and (ii) to quantify the effect wood ash addition on the decomposition and leaching of DOC and DON. Decomposition was studied for 128 days under aerobic conditions at 8 degrees C and moisture close to field capacity in a spodic dystric Cambisol with mor-moder layer. Variants included control plots and additions of (i) Calamagrostis litter and (ii) Calamagrostis litter plus 4 kg ash m-2. (i) Decomposition of Calamagrostis resulted in a CO2 production of 76.2 g CO2-C m-2 (10% of added C) after 128 days and cumulative DOC production was 14.0 g C m-2 out of which 0.9 g C m-2 was Calamagrostis-derived (0.1% of added C). The specific CO2 formation and specific DOC production from Calamagrostis were 6 times higher (CO2) and 4 times smaller (DOC) than those from the organic layer. The amount of Calamagrostis-derived total N (NH4+, NO3-, DON) leached was 0.7 g N m-2 (4.8% of added N). Cumulative DON production was 0.8 g N m-2 which was slightly higher than for the control. During soil passage, much of the DOC and DON was removed due to sorption or decomposition. DOC and DON releases from the mineral soil (17 cm depth) were 6.3 g C m-2 and 0.5 g N m-2. (ii) Addition of ash resulted in a complete fixing of CO2 for 40 days due to carbonatisation. Afterwards, the CO2 production rates were similar to the variant without ash addition. Production of DOC (98.6 g C m-2) and DON (2.5 g N m-2) was marked, mainly owing to humus decay. However, Calamagrostis-derived DOC and Calamagrostis-derived total N were only 3.9 g C m-2 (0.5% of added C) and 0.5 g N m-2 (3.4% of added N). The specific DOC production rate from the organic layer was 6 times higher than that from Calamagrostis. The results suggest that with increasing humification from fresh plant residues to more decomposed material (OF and OH layers) the production ratio of DOC/CO2-C increases. Addition of alkaline substances to the forest floor can lead to a manifold increase in DOC production. 相似文献
104.
M. Ludwig P. Abell 《The European Physical Journal B - Condensed Matter and Complex Systems》2007,58(1):97-105
Social networks in communities, markets, and societies self-organise through the interactions of many individuals. In this
paper we use a well-known
mechanism of social interactions — the balance of sentiment in triadic
relations — to describe the development of social networks. Our model
contrasts with many existing network models, in that people not only
establish but also break up relations whilst the network evolves. The
procedure generates several interesting network features such as a variety
of degree distributions and degree correlations. The resulting network
converges under certain conditions to a steady critical state where temporal
disruptions in triangles follow a power-law distribution. 相似文献
105.
106.
Ludwig Staudenmaier und M. Chikashige 《Fresenius' Journal of Analytical Chemistry》1897,36(1):281-284
Ohne Zusammenfassung 相似文献
107.
Ludwig J. Belenky 《Colloid and polymer science》1934,67(1):79-87
Ohne Zusammenfassung
Zum Schlu? m?chte der Author Prof. N. P. Peskow und Prof. A. I. Rabinowitsch für ihre wertvollen Ratschl?ge seinen herzlichen
Dank aussprechen. 相似文献
108.
109.
Carl Friedheim und Ludwig Jacobius 《Fresenius' Journal of Analytical Chemistry》1905,44(8-9):465-491
Ohne Zusammenfassung 相似文献
110.